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ChemicalBook >> CAS DataBase List >> PHENYLMAGNESIUM CHLORIDE

PHENYLMAGNESIUM CHLORIDE

PHENYLMAGNESIUM CHLORIDE price.
  • $44 - $4730
  • Product name: PHENYLMAGNESIUM CHLORIDE
  • CAS: 100-59-4
  • MF: C6H5ClMg
  • MW: 136.86
  • EINECS:202-868-8
  • MDL Number:MFCD00000464
  • Synonyms:PHENYLMAGNESIUM CHLORIDE, 2.0M SOLUTION IN TETRAHYDROFURAN;Phenylmagnesium Chloride 2.0 M In Tetrahdyrofuran;PHENYLMAGNESIUM CHLORIDE 25 WT% IN THF;Phenylmagnesium chloride, 25 wt% solution in tetrahydrofuran;PHENYLMAGNESIUM CHLORIDE, 1 M in DIBUTYL ETHER;PHENYLMAGNESIUM CHLORIDE, 2 M in TETRAHYDROFURAN;Phenylmagnesiumchloride,2-3MinTHF;PHENYLMAGNESIUMCHLORIDE,25%INTETRAHYDROFURAN
14 prices
Selected condition:
Brand
  • AK Scientific
  • American Custom Chemicals Corporation
  • Matrix Scientific
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 0.25mole
  • 25g
  • 1mole
  • 50ml
  • 100ml
  • 200ml
  • 250g
  • 500ml
  • 800ml
  • 8l
  • 18L
  • ManufacturerAK Scientific
  • Product number9006AJ
  • Product descriptionPhenylmagnesiumchloride
  • Packaging250g
  • Price$214
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000521
  • Product descriptionPHENYLMAGNESIUM CHLORIDE 95.00%
  • Packaging250G
  • Price$4338.25
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number121759
  • Product descriptionPhenylmagnesiumChloride 1.0Min2-MeTHF97%
  • Packaging50ml
  • Price$232
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number121759
  • Product descriptionPhenylmagnesiumChloride 1.0Min2-MeTHF97%
  • Packaging100ml
  • Price$332
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number121759
  • Product descriptionPhenylmagnesiumChloride 1.0Min2-MeTHF97%
  • Packaging500ml
  • Price$737
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number224448
  • Product descriptionPhenylmagnesium chloride solution 2.0 M in THF
  • Packaging100ml
  • Price$84.9
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number257125
  • Product descriptionPhenylmagnesium chloride solution 2.0M in THF
  • Packaging200ml
  • Price$124.2
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number224448
  • Product descriptionPhenylmagnesium chloride solution 2.0 M in THF
  • Packaging800ml
  • Price$279
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number224448
  • Product descriptionPhenylmagnesium chloride solution 2.0 M in THF
  • Packaging8l
  • Price$2460
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number224448
  • Product descriptionPhenylmagnesium chloride solution 2.0?M in THF
  • Packaging18L
  • Price$4730
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number93-1269
  • Product descriptionPhenylmagnesium chloride, 2-3M in THF
  • Packaging0.25mole
  • Price$44
  • Updated2023-06-20
  • Buy
  • ManufacturerStrem Chemicals
  • Product number93-1269
  • Product descriptionPhenylmagnesium chloride, 2-3M in THF
  • Packaging1mole
  • Price$123
  • Updated2023-06-20
  • Buy
  • ManufacturerTCI Chemical
  • Product numberP1381
  • Product descriptionPhenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L)
  • Packaging250g
  • Price$130
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberP399213
  • Product descriptionPhenylmagnesiumChloride
  • Packaging25g
  • Price$90
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 9006AJ Phenylmagnesiumchloride 250g $214 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000521 PHENYLMAGNESIUM CHLORIDE 95.00% 250G $4338.25 2021-12-16 Buy
Matrix Scientific 121759 PhenylmagnesiumChloride 1.0Min2-MeTHF97% 50ml $232 2021-12-16 Buy
Matrix Scientific 121759 PhenylmagnesiumChloride 1.0Min2-MeTHF97% 100ml $332 2021-12-16 Buy
Matrix Scientific 121759 PhenylmagnesiumChloride 1.0Min2-MeTHF97% 500ml $737 2021-12-16 Buy
Sigma-Aldrich 224448 Phenylmagnesium chloride solution 2.0 M in THF 100ml $84.9 2024-03-01 Buy
Sigma-Aldrich 257125 Phenylmagnesium chloride solution 2.0M in THF 200ml $124.2 2024-03-01 Buy
Sigma-Aldrich 224448 Phenylmagnesium chloride solution 2.0 M in THF 800ml $279 2024-03-01 Buy
Sigma-Aldrich 224448 Phenylmagnesium chloride solution 2.0 M in THF 8l $2460 2024-03-01 Buy
Sigma-Aldrich 224448 Phenylmagnesium chloride solution 2.0?M in THF 18L $4730 2024-03-01 Buy
Strem Chemicals 93-1269 Phenylmagnesium chloride, 2-3M in THF 0.25mole $44 2023-06-20 Buy
Strem Chemicals 93-1269 Phenylmagnesium chloride, 2-3M in THF 1mole $123 2023-06-20 Buy
TCI Chemical P1381 Phenylmagnesium Chloride (27% in Tetrahydrofuran, ca. 2mol/L) 250g $130 2024-03-01 Buy
TRC P399213 PhenylmagnesiumChloride 25g $90 2021-12-16 Buy

Properties

Melting point :89-90℃
Boiling point :230℃ (8 Torr)
Density :0.98 g/mL at 20 °C
Flash point :1 °F
storage temp. :2-8°C
Water Solubility :It reacts violently with water.
Sensitive :Air & Moisture Sensitive
Merck :14,7298
BRN :3587900
InChIKey :GQONLASZRVFGHI-UHFFFAOYSA-M
CAS DataBase Reference :100-59-4(CAS DataBase Reference)
EPA Substance Registry System :Magnesium, chlorophenyl- (100-59-4)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H261 In contact with water releases flammable gas Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 2
Category 3
Danger
Warning
GHS hazard pictograms P231+P232, P280, P370+P378,P402+P404, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H312 Harmful in contact with skin Acute toxicity,dermal Category 4 Warning GHS hazard pictograms P280,P302+P352, P312, P322, P363,P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger GHS hazard pictograms P280, P305+P351+P338, P310
H333 May be harmful if inhaled Acute toxicity,inhalation Category 5 P304+P312
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
H371 May cause damage to organs Specific target organ toxicity, single exposure Category 2 Warning P260, P264, P270, P309+P311, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P233 Keep container tightly closed.
P240 Ground/bond container and receiving equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P403+P235 Store in a well-ventilated place. Keep cool.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

Phenylmagnesium chloride is used primarily to add an iso-propyl group to carbonyl groups. This reagent can also be used as a strong base in aprotic solvents. It is also used as a Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF).

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