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ChemicalBook >> CAS DataBase List >> N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE

N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE

N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE price.
  • $45 - $909.44
  • Product name: N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE
  • CAS: 7688-51-9
  • MF: C9H23NSi2
  • MW: 201.46
  • EINECS:231-699-2
  • MDL Number:MFCD00545193
  • Synonyms:1,1,1-Trimethyl-N-2-propenyl-N-(trimethylsilyl)silanamine;Allylbis(trimethylsilyl)amine;α,α,α-Trimethyl-N-(2-propenyl)-N-(trimethylsilyl)silanamine;Einecs 231-699-2;N-ALLYL-N N-BIS(TRIMETHYLSILYL)AMINE;N-allyl-1,1,1-trimethyl-N-(trimethylsilyl)silylamine ;2-ALLYL-1,1,1,3,3,3-HEXAMETHYLDISILAZAN&;N,N'-bis(trimethylsilyl)allylamine
5 prices
Selected condition：
Brand
  • American Custom Chemicals Corporation
  • BroadPharm
  • Sigma-Aldrich
  • SynQuest Laboratories
Package
  • 1G
  • 5G
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberORS0000919
  • Product descriptionN-ALLYL-N,N-BIS(TRIMETHYLSILYL)AMINE 95.00%
  • Packaging1G
  • Price$163.8
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberORS0000919
  • Product descriptionN-ALLYL-N,N-BIS(TRIMETHYLSILYL)AMINE 95.00%
  • Packaging5G
  • Price$909.44
  • Updated2021-12-16
  • Buy
  • ManufacturerBroadPharm
  • Product numberBP-21138
  • Product descriptionN-ALLYL-N,N-BIS(TRIMETHYLSILYL)AMINE 95%
  • Packaging1g
  • Price$45
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number578932
  • Product descriptionN-Allyl-N,N-bis(trimethylsilyl)amine 97%
  • Packaging5g
  • Price$179
  • Updated2024-03-01
  • Buy
  • ManufacturerSynQuest Laboratories
  • Product number7387-1-03
  • Product descriptionProp-2-en-1-ylbis(trimethylsilyl)amine
  • Packaging5G
  • Price$125
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation ORS0000919 N-ALLYL-N,N-BIS(TRIMETHYLSILYL)AMINE 95.00% 1G $163.8 2021-12-16 Buy
American Custom Chemicals Corporation ORS0000919 N-ALLYL-N,N-BIS(TRIMETHYLSILYL)AMINE 95.00% 5G $909.44 2021-12-16 Buy
BroadPharm BP-21138 N-ALLYL-N,N-BIS(TRIMETHYLSILYL)AMINE 95% 1g $45 2021-12-16 Buy
Sigma-Aldrich 578932 N-Allyl-N,N-bis(trimethylsilyl)amine 97% 5g $179 2024-03-01 Buy
SynQuest Laboratories 7387-1-03 Prop-2-en-1-ylbis(trimethylsilyl)amine 5G $125 2021-12-16 Buy

Properties

Boiling point :72 °C/15 mmHg (lit.)
Density :0.816 g/mL at 25 °C (lit.)
refractive index :n20/D 1.440(lit.)
Flash point :109 °F
form :liquid
Specific Gravity :0.817
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:
  • Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.
  • Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.
  • Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.


AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.

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