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ChemicalBook >> CAS DataBase List >> (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

$74 - $3784
Product name: (R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny
CAS: 352655-61-9
MF: C74H104O6P2
MW: 1151.56
EINECS:
MDL Number:MFCD09265029
Synonyms:(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny;(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(R)-(-)-2,2''-BIS[DI(3,5-DI-T-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine];(S)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-2, (S)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine};(R)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphine];(R)-3,5-t-Bu-4-MeO-MeOBIPHEP, SL-A109-1, (R)-[6,6μ-Dimethoxy(1,1μ-biphenyl)-2,2μ-diyl]bis{bis[3,5-bis(1,1-dimethylethyl)-4-methoxyphenyl]phosphine};(R)-(-)-2,2'-Bis[di-(3,5-di-tert-butyl-4-methoxy-phenyl)phosphino]-(diphenylphosphino)-6,6'-dimethoxy-1,1'-biphenyl

Price18 Properties Safety Information Description

18 prices

Selected condition：

Brand

Ambeed
American Custom Chemicals Corporation
BLDpharm
Strem Chemicals

Package

50mg
100mg
250mg
500MG
1g
2G
5g
10g

ManufacturerAmbeed
Product numberA127511
Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
Packaging50mg
Price$80
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA127511
Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
Packaging100mg
Price$132
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA127511
Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
Packaging250mg
Price$285
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA127511
Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
Packaging1g
Price$775
Updated2021-12-16
Buy

ManufacturerAmbeed
Product numberA127511
Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
Packaging5g
Price$2553
Updated2021-12-16
Buy

ManufacturerAmerican Custom Chemicals Corporation
Product numberING0001277
Product description(R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%
Packaging100MG
Price$646.88
Updated2021-12-16
Buy

ManufacturerAmerican Custom Chemicals Corporation
Product numberING0001277
Product description(R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%
Packaging500MG
Price$914.17
Updated2021-12-16
Buy

ManufacturerAmerican Custom Chemicals Corporation
Product numberING0001277
Product description(R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%
Packaging1G
Price$1269.75
Updated2021-12-16
Buy

ManufacturerAmerican Custom Chemicals Corporation
Product numberING0001277
Product description(R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%
Packaging2G
Price$1765
Updated2021-12-16
Buy

ManufacturerBLDpharm
Product numberBD633937
Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
Packaging50mg
Price$75
Updated2021-12-16
Buy

ManufacturerBLDpharm
Product numberBD633937
Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
Packaging100mg
Price$120
Updated2021-12-16
Buy

ManufacturerBLDpharm
Product numberBD633937
Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
Packaging250mg
Price$250
Updated2021-12-16
Buy

ManufacturerBLDpharm
Product numberBD633937
Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
Packaging1g
Price$695
Updated2021-12-16
Buy

ManufacturerBLDpharm
Product numberBD633937
Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%
Packaging5g
Price$3128
Updated2021-12-16
Buy

ManufacturerStrem Chemicals
Product number15-0042
Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging100mg
Price$74
Updated2021-12-16
Buy

ManufacturerStrem Chemicals
Product number15-0042
Product description(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%
Packaging500mg
Price$278
Updated2021-12-16
Buy

Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
Ambeed	A127511	(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%	50mg	$80	2021-12-16	Buy
Ambeed	A127511	(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%	100mg	$132	2021-12-16	Buy
Ambeed	A127511	(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%	250mg	$285	2021-12-16	Buy
Ambeed	A127511	(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%	1g	$775	2021-12-16	Buy
Ambeed	A127511	(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%	5g	$2553	2021-12-16	Buy
American Custom Chemicals Corporation	ING0001277	(R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%	100MG	$646.88	2021-12-16	Buy
American Custom Chemicals Corporation	ING0001277	(R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%	500MG	$914.17	2021-12-16	Buy
American Custom Chemicals Corporation	ING0001277	(R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%	1G	$1269.75	2021-12-16	Buy
American Custom Chemicals Corporation	ING0001277	(R)-(-)-2,2'-BIS[DI(3,5-DI-TERT-BUTYL-4-METHOXYPHENYL)PHOSPHINO]-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00%	2G	$1765	2021-12-16	Buy
BLDpharm	BD633937	(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%	50mg	$75	2021-12-16	Buy
BLDpharm	BD633937	(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%	100mg	$120	2021-12-16	Buy
BLDpharm	BD633937	(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%	250mg	$250	2021-12-16	Buy
BLDpharm	BD633937	(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%	1g	$695	2021-12-16	Buy
BLDpharm	BD633937	(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl 98%	5g	$3128	2021-12-16	Buy
Strem Chemicals	15-0042	(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%	100mg	$74	2021-12-16	Buy
Strem Chemicals	15-0042	(R)-(-)-2,2'-Bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-6,6'-dimethoxy-1,1'-biphenyl, min. 97%	500mg	$278	2021-12-16	Buy

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Properties

Boiling point :951.5±65.0 °C(Predicted)
form :crystal
color :white

Safety Information

Symbol(GHS):

Signal word:

Warning

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	P-Codes
H302	Harmful if swallowed	Acute toxicity,oral	Category 4	Warning	P264, P270, P301+P312, P330, P501
H315	Causes skin irritation	Skin corrosion/irritation	Category 2	Warning	P264, P280, P302+P352, P321,P332+P313, P362
H319	Causes serious eye irritation	Serious eye damage/eye irritation	Category 2A	Warning	P264, P280, P305+P351+P338,P337+P313P
H335	May cause respiratory irritation	Specific target organ toxicity, single exposure;Respiratory tract irritation	Category 3	Warning

Precautionary statements:

P261	Avoid breathing dust/fume/gas/mist/vapours/spray.
P280	Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352	IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Atropisomeric MeOBIPHEP ligands

Asymmetrical conjugate addition of arylboronic acids to maleimides and enones catalyzed by rhodium complexes
Intramolecular ketone hydroacylation
Desymmetrization through enantioselective C-C bond activation and ring expansion of allenyl cyclobutanols
Hydroamination of bicyclic alkenes and dienes with anilines
1,4-addition/asymmetric protonation of amino acrylates

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(R)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(3,5-di-tert-butyl-4-methoxypheny

Properties

Safety Information

Description

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