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ChemicalBook >> CAS DataBase List >> (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl

(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl price.
  • $25 - $485
  • Product name: (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl
  • CAS: 135139-00-3
  • MF: C52H48P2
  • MW: 734.89
  • EINECS:681-146-8
  • MDL Number:MFCD01630821
  • Synonyms:2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL;2,2'-BIS[BIS(3,5-DIMETHYLPHENYL)PHOSPHINO]-1,1'-BINAPHTHYL;(S)-(-)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl , ((S)-Xylyl ;(S)-(-)-2,2'-Bis[bis(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl;(S)-3,5-Xyl-BINAP;PHOSPHINE, 1,1''-[(1S)-[1,1''-BINAPHTHALENE]-2,2''-DIYL]BIS[1,1-BIS(3,5-DIMETHYLPHENYL)-;(S)-(-)-2,2'-Bis(di-(3,5-dimethylphenyl)phosphino)-1,1'-binaphthyl , 98% ((S)-Xylyl-BINAP);(S)-3,5-Xylyl-BINAP, (S)-(-)-2,2μ-Bis[di(3,5-xylyl)phoshino]-1,1μ-binaphthyl, (S)-(-)-2,2μ-Bis[bis(3,5-dimethylphenyl)phosphino]-1,1μ-binaphthyl
23 prices
Selected condition:
Brand
  • AK Scientific
  • Alfa Aesar
  • Alichem
  • Ambeed
  • Chem-Impex
  • ChemScene
  • ChemSupplyAustralia
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 100mg
  • 200mg
  • 250mg
  • 500mg
  • 1g
  • 5g
  • ManufacturerAK Scientific
  • Product number4137AL
  • Product description(S)-(-)-XylBINAP
  • Packaging200mg
  • Price$139
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product number4137AL
  • Product description(S)-(-)-XylBINAP
  • Packaging1g
  • Price$320
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH26970
  • Product description(S)-(-)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
  • Packaging100mg
  • Price$93.3
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberH26970
  • Product description(S)-(-)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98%
  • Packaging500mg
  • Price$301
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number135139003
  • Product description(R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene
  • Packaging250mg
  • Price$183.6
  • Updated2021-12-16
  • Buy
  • ManufacturerAlichem
  • Product number135139003
  • Product description(R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene
  • Packaging1g
  • Price$481.5
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA999826
  • Product description(S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98%
  • Packaging100mg
  • Price$25
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA999826
  • Product description(S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98%
  • Packaging250mg
  • Price$45
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA999826
  • Product description(S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98%
  • Packaging1g
  • Price$85
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA999826
  • Product description(S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98%
  • Packaging5g
  • Price$340
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number41165
  • Product description(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,99%(Chiralpurity) 99%(Chiralpurity)
  • Packaging200MG
  • Price$63.84
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number41165
  • Product description(S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,99%(Chiralpurity) 99%(Chiralpurity)
  • Packaging1G
  • Price$221.76
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W014408
  • Product description(S)-DM-BINAP ≥98.0%
  • Packaging500mg
  • Price$75
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W014408
  • Product description(S)-DM-BINAP ≥98.0%
  • Packaging1g
  • Price$97
  • Updated2021-12-16
  • Buy
  • ManufacturerChemScene
  • Product numberCS-W014408
  • Product description(S)-DM-BINAP ≥98.0%
  • Packaging5g
  • Price$485
  • Updated2021-12-16
  • Buy
  • ManufacturerChemSupplyAustralia
  • Product number300007
  • Product description(S)-(-)-2,2'-Bis[di-(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl , 98%
  • Packaging250mg
  • Price$48.4
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 4137AL (S)-(-)-XylBINAP 200mg $139 2021-12-16 Buy
AK Scientific 4137AL (S)-(-)-XylBINAP 1g $320 2021-12-16 Buy
Alfa Aesar H26970 (S)-(-)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98% 100mg $93.3 2021-12-16 Buy
Alfa Aesar H26970 (S)-(-)-2,2'-Bis(di-3,5-xylylphosphino)-1,1'-binaphthyl, 98% 500mg $301 2021-12-16 Buy
Alichem 135139003 (R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 250mg $183.6 2021-12-16 Buy
Alichem 135139003 (R)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 1g $481.5 2021-12-16 Buy
Ambeed A999826 (S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98% 100mg $25 2021-12-16 Buy
Ambeed A999826 (S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98% 250mg $45 2021-12-16 Buy
Ambeed A999826 (S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98% 1g $85 2021-12-16 Buy
Ambeed A999826 (S)-2,2'-Bis(bis(3,5-dimethylphenyl)phosphino)-1,1'-binaphthalene 98% 5g $340 2021-12-16 Buy
Chem-Impex 41165 (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,99%(Chiralpurity) 99%(Chiralpurity) 200MG $63.84 2021-12-16 Buy
Chem-Impex 41165 (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl,99%(Chiralpurity) 99%(Chiralpurity) 1G $221.76 2021-12-16 Buy
ChemScene CS-W014408 (S)-DM-BINAP ≥98.0% 500mg $75 2021-12-16 Buy
ChemScene CS-W014408 (S)-DM-BINAP ≥98.0% 1g $97 2021-12-16 Buy
ChemScene CS-W014408 (S)-DM-BINAP ≥98.0% 5g $485 2021-12-16 Buy
ChemSupplyAustralia 300007 (S)-(-)-2,2'-Bis[di-(3,5-dimethylphenyl)phosphino]-1,1'-binaphthyl , 98% 250mg $48.4 2021-12-16 Buy

Properties

Melting point :203-206°C
alpha :-172 º (c=1 in chloroform)
Boiling point :825.3±65.0 °C(Predicted)
storage temp. :Inert atmosphere,Room Temperature
Water Solubility :Insoluble in water
form :crystal
color :white to pale yellow

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.

Description

Catalyst for:
  • Asymmetric hydrogenation of benzophenone
  • Regio- and stereoselective preparation of axially chiral arylnaphthalene derivatives via rhodium-catalyzed [2+2+2] cycloaddition of diynes with naphthalenepropynoic acid derivatives in the presence of chiral biaryl bisphosphine ligands
  • Regiodivergent rhodium-catalyzed [(2+2)+2] carbocyclization of 1,6-enynes with Me propiolates
  • Ligand controlled regioselective and stereoselective desymmetrizing rhodium-catalyzed allylic arylation of meso cyclopentene dicarbonates with arylboronic acids to form regioisomeric arylcyclopentenols
  • Platinum(II) complex-catalyzed enantioselective aldol reaction with ketene silyl acetals in DMF at room temperature
  • Stereoselective preparation of chiral N,O-biaryls via Rh-catalyzed [2+2+2] cycloaddition of conjugate ynamides with diynes

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