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ChemicalBook >> CAS DataBase List >> (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE price.
  • $12 - $1506.84
  • Product name: (R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
  • CAS: 138124-32-0
  • MF: C36H52ClMnN2O2
  • MW: 635.2
  • EINECS:
  • MDL Number:MFCD02101664
  • Synonyms:(R,R)-(-)-N,N'-BIS(3.5-DI-T-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINE-MANGANESE (III) CHLORIDE;(R,R)-(-)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE;(R,R)-JACOBSEN CATALYST;(R,R)-JACOBSEN'S CATALYST;(R,R)-JACOBSEN'S CATALYST MANGANESE(III) CHLORIDE COMPLEX;(1R,2R)-(-)-[1,2-CYCLOHEXANEDIAMINO-N N'-BIS(3,5-DI-T-BUTYLSALICYLIDENE)]MANGANESE(III)CHLORIDE;JACOBSEN'S CATALYST;(-)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO-
27 prices
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  • Ambeed
  • American Custom Chemicals Corporation
  • Arctom
  • Biosynth Carbosynth
  • BLDpharm
  • Chem-Impex
  • Crysdot
  • Oakwood
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
  • TRC
Package
  • 100mg
  • 250mg
  • 500mg
  • 1g
  • 2g
  • 5g
  • 25g
  • 50g
  • 250G
  • ManufacturerAmbeed
  • Product numberA489410
  • Product description(R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 98%
  • Packaging1g
  • Price$12
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA489410
  • Product description(R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 98%
  • Packaging5g
  • Price$28
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA489410
  • Product description(R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 98%
  • Packaging25g
  • Price$108
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000042
  • Product description(R,R)-(-)N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINOMANGANESE(III) CHLORIDE 95.00%
  • Packaging1G
  • Price$245.07
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000042
  • Product description(R,R)-(-)N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINOMANGANESE(III) CHLORIDE 95.00%
  • Packaging5G
  • Price$908.47
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000042
  • Product description(R,R)-(-)N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINOMANGANESE(III) CHLORIDE 95.00%
  • Packaging25G
  • Price$1506.84
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberSY007841
  • Product description(R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging5g
  • Price$115
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB30906
  • Product description(R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging100mg
  • Price$50
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB30906
  • Product description(R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging250mg
  • Price$80
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB30906
  • Product description(R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging500mg
  • Price$125
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB30906
  • Product description(R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging1g
  • Price$200
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB30906
  • Product description(R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging2g
  • Price$320
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD165036
  • Product description(R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 98%
  • Packaging1g
  • Price$12
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD165036
  • Product description(R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 98%
  • Packaging5g
  • Price$28
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD165036
  • Product description(R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 98%
  • Packaging25g
  • Price$108
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number36017
  • Product description(R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging250G
  • Price$1106.56
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Ambeed A489410 (R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 98% 1g $12 2021-12-16 Buy
Ambeed A489410 (R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 98% 5g $28 2021-12-16 Buy
Ambeed A489410 (R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 98% 25g $108 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000042 (R,R)-(-)N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINOMANGANESE(III) CHLORIDE 95.00% 1G $245.07 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000042 (R,R)-(-)N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINOMANGANESE(III) CHLORIDE 95.00% 5G $908.47 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000042 (R,R)-(-)N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINOMANGANESE(III) CHLORIDE 95.00% 25G $1506.84 2021-12-16 Buy
Arctom SY007841 (R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 5g $115 2021-12-16 Buy
Biosynth Carbosynth FB30906 (R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 100mg $50 2021-12-16 Buy
Biosynth Carbosynth FB30906 (R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 250mg $80 2021-12-16 Buy
Biosynth Carbosynth FB30906 (R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 500mg $125 2021-12-16 Buy
Biosynth Carbosynth FB30906 (R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 1g $200 2021-12-16 Buy
Biosynth Carbosynth FB30906 (R,R)-(-)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 2g $320 2021-12-16 Buy
BLDpharm BD165036 (R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 98% 1g $12 2021-12-16 Buy
BLDpharm BD165036 (R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 98% 5g $28 2021-12-16 Buy
BLDpharm BD165036 (R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 98% 25g $108 2021-12-16 Buy
Chem-Impex 36017 (R,R)-(?)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 250G $1106.56 2021-12-16 Buy

Properties

Melting point :330-332 °C(lit.)
alpha :D23 +580° (c = 0.01 in ethanol)
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :Liquid May Develop Some Turbidity or Precipitate
color :Light yellow to gold to brown
λmax :509nm(CH2Cl2)(lit.)
Merck :14,5252
InChIKey :LJVAWOSDJSQANR-OHRASPNLSA-K

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins.High enantioselectivities and yields are obtained for a variety of substrates, especiallycis-alkenes. A few applications include the synthesis of the taxol side chainandcis-1-amino-2-indanol.Jacobsen′s catalyst has also been used in the asymmetricα-hydroxylation of silyl enol ethers.Catalyst for the enantioselective epoxidation of a variety of olefins.

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