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ChemicalBook >> CAS DataBase List >> (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE

(S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE price.
  • $21 - $1528.67
  • Product name: (S,S)-(+)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)-1,2-CYCLOHEXANEDIAMINO-MANGANESE(III) CHLORIDE
  • CAS: 135620-04-1
  • MF: C36H52ClMnN2O2
  • MW: 635.2
  • EINECS:
  • MDL Number:MFCD02101663
  • Synonyms:(+)-BIS(3,5-DI-T-BU-SALICYL.)-1,2-CYCLO- HEXANEDIAMINO-MN CL;(S,S)-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYL- IDENE)-1,2-CYCLOHEXANEDIAMINO-MN-CL;(1S,2S)-(+)-(1,2-Cyclohexanediamino-N,N'-bis(3,5-di-tert-butylsalicylidene))manganese(III)chloride;(S,S)-Jacobsencat.;(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]manganese(III)chloride,98%(S,S)-JacobsenCat.;(S,S)(+)N,N'-Bis(3,5-di-tbutylsalicylidene)1,2-chexanediaminomanganese(iii)chlorideco;(S,S)-(+)N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chlo;(1S,2S)-(+)-[1,2-CyclohexanediaMino-N,N'-bis(3,5-di-t-butylsalicylidene)]Manganese(III) chloride (S,S)-Jacobsen Cat.
19 prices
Selected condition：
Brand
  • AK Scientific
  • American Custom Chemicals Corporation
  • BLDpharm
  • Chemenu
  • Crysdot
  • Matrix Scientific
  • Sigma-Aldrich
  • Strem Chemicals
Package
  • 1g
  • 5G
  • 10g
  • 25G
  • 100g
  • ManufacturerAK Scientific
  • Product numberJ57362
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride
  • Packaging1g
  • Price$30
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberJ57362
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride
  • Packaging100g
  • Price$720
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000049
  • Product description(1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE 95.00%
  • Packaging25G
  • Price$1528.67
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000049
  • Product description(1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE 95.00%
  • Packaging5G
  • Price$908.47
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000049
  • Product description(1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE 95.00%
  • Packaging1G
  • Price$641.18
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD228424
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98%
  • Packaging25g
  • Price$247
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD228424
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98%
  • Packaging10g
  • Price$131
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD228424
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98%
  • Packaging5g
  • Price$73
  • Updated2021-12-16
  • Buy
  • ManufacturerBLDpharm
  • Product numberBD228424
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98%
  • Packaging1g
  • Price$21
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM282415
  • Product description(S,S)-[N,N''-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 95%
  • Packaging25g
  • Price$370
  • Updated2021-12-16
  • Buy
  • ManufacturerCrysdot
  • Product numberCD52001301
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 95+%
  • Packaging25g
  • Price$392
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number097952
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride 95+%
  • Packaging10g
  • Price$395
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number097952
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride 95+%
  • Packaging5g
  • Price$252
  • Updated2021-12-16
  • Buy
  • ManufacturerMatrix Scientific
  • Product number097952
  • Product description(S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride 95+%
  • Packaging1g
  • Price$95
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number404454
  • Product description(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging25g
  • Price$663
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number404454
  • Product description(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride
  • Packaging5g
  • Price$112.2
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific J57362 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 1g $30 2021-12-16 Buy
AK Scientific J57362 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 100g $720 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000049 (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE 95.00% 25G $1528.67 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000049 (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE 95.00% 5G $908.47 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000049 (1S,2S)-(+)-[1,2-CYCLOHEXANEDIAMINO-N,N'-BIS(3,5-DI-TERT-BUTYLSALICYLIDENE)]MANGANESE (III) CHLORIDE 95.00% 1G $641.18 2021-12-16 Buy
BLDpharm BD228424 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98% 25g $247 2021-12-16 Buy
BLDpharm BD228424 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98% 10g $131 2021-12-16 Buy
BLDpharm BD228424 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98% 5g $73 2021-12-16 Buy
BLDpharm BD228424 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 98% 1g $21 2021-12-16 Buy
Chemenu CM282415 (S,S)-[N,N''-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 95% 25g $370 2021-12-16 Buy
Crysdot CD52001301 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride 95+% 25g $392 2021-12-16 Buy
Matrix Scientific 097952 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride 95+% 10g $395 2021-12-16 Buy
Matrix Scientific 097952 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride 95+% 5g $252 2021-12-16 Buy
Matrix Scientific 097952 (S,S)-[N,N'-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III) chloride 95+% 1g $95 2021-12-16 Buy
Sigma-Aldrich 404454 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 25g $663 2024-03-01 Buy
Sigma-Aldrich 404454 (S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese(III) chloride 5g $112.2 2024-03-01 Buy

Properties

Melting point :330-332 °C(lit.)
storage temp. :Inert atmosphere,Room Temperature
form :Powder
color :brown
InChIKey :VGAJDQCIDNCJQC-JINVCYSXSA-K
CAS DataBase Reference :135620-04-1

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Salen (Mn)-catalyzed asymmetric epoxidation of unfunctionalized olefins.High enantioselectivities and yields are obtained for a variety of substrates,especiallycis-alkenes. A few applications include the synthesis of the taxol side chainandcis-1-amino-2-indanol.Jacobsen′s catalyst has also been used in the asymmetricα-hydroxylation of silyl enol ethers.Catalyst for the enantioselective epoxidation of a variety of olefins.

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