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ChemicalBook >> CAS DataBase List >> 1-ACETOXY-1,3-BUTADIENE

1-ACETOXY-1,3-BUTADIENE

1-ACETOXY-1,3-BUTADIENE price.
  • $120 - $1232.15
  • Product name: 1-ACETOXY-1,3-BUTADIENE
  • CAS: 1515-76-0
  • MF: C6H8O2
  • MW: 112.13
  • EINECS:216-159-6
  • MDL Number:MFCD00008714
  • Synonyms:(1E)-1,3-Butadienyl acetate;1,3-butadien-1-ol,acetate ;1,3-Butadienylester kyseliny octove;1,3-butadienylesterkyselinyoctove ;1-acetoxy-1,3-butadiene,mixtureofisomers ;1-Acetoxybutadiene;Acetic acid, 1,3-butadienyl ester;aceticacid,1,3-butadienylester
4 prices
Selected condition：
Brand
  • American Custom Chemicals Corporation
  • Sigma-Aldrich
  • TRC
  • Usbiological
Package
  • 500mg
  • 1g
  • 10G
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberCHM0006438
  • Product description1-ACETOXY-1,3-BUTADIENE 95.00%
  • Packaging10G
  • Price$1232.15
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number220868
  • Product description1-Acetoxy-1,3-butadiene mixture of cis and trans
  • Packaging10g
  • Price$308
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberA164285
  • Product description1-Acetoxy-1,3-butadiene
  • Packaging1g
  • Price$120
  • Updated2021-12-16
  • Buy
  • ManufacturerUsbiological
  • Product number408671
  • Product description1-Acetoxy-1,3-butadiene
  • Packaging500mg
  • Price$355
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
American Custom Chemicals Corporation CHM0006438 1-ACETOXY-1,3-BUTADIENE 95.00% 10G $1232.15 2021-12-16 Buy
Sigma-Aldrich 220868 1-Acetoxy-1,3-butadiene mixture of cis and trans 10g $308 2024-03-01 Buy
TRC A164285 1-Acetoxy-1,3-butadiene 1g $120 2021-12-16 Buy
Usbiological 408671 1-Acetoxy-1,3-butadiene 500mg $355 2021-12-16 Buy

Properties

Boiling point :60-61 °C40 mm Hg(lit.)
Density :0.96 g/mL at 20 °C(lit.)
vapor pressure :40 mm Hg ( 60 °C)
refractive index :n20/D 1.47
Flash point :92 °F
storage temp. :2-8°C
form :Liquid
BRN :1743394
CAS DataBase Reference :1515-76-0(CAS DataBase Reference)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger GHS hazard pictograms P280, P302+P352, P312, P322, P361,P363, P405, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P233 Keep container tightly closed.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312 IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1-Acetoxy-1,3-butadiene was used as diene in the following reactions:Diels-Alder reaction withortho-carbazolequinones to yield benzocarbazolequinone.Diels-Alder reaction with diethyl ketovinylphosphonate, with and without Lewis acid assistance.Diels-Alder reaction with methyl acrylate to yield racemic forms of 2-hydroxy-3-cyclohexenecarboxylic acid.It was used for the reaction with dienophiles such as maleimides,a juglone,a butyne-1,4-dioneand methyl 2-(4-methylphenyl)-2H-azirine-3-carboxylate and during visible light photocatalysis.It was also used as reactant during intermolecular oxa-Pictet-Spengler cyclization.