Triclopyr
Product identifier
- Product name: Triclopyr
- CBnumber: CB4666264
- CAS: 55335-06-3
- EINECS Number: 259-597-3
- Synonyms: TRICLOPYR,TRICLOPYR ACID
Relevant identified uses of the substance or mixture and uses advised against
- Relevant identified uses: For R&D use only. Not for medicinal, household or other use.
- Uses advised against: none
Company Identification
- Company: Chemicalbook
- Address: Building 1, Huihuang International, Shangdi 10th Street, Haidian District, Beijing
- Telephone: 400-158-6606
Classification of the substance or mixture
Acute toxicity - Category 4, Oral
Skin sensitization, Category 1
Eye irritation, Category 2
Specific target organ toxicity – repeated exposure, Category 2
Hazardous to the aquatic environment, short-term (Acute) - Category Acute 1
Hazardous to the aquatic environment, long-term (Chronic) - Category Chronic 1
Label elements
Pictogram(s)
- Signal wordWarning
H302 Harmful if swallowed
H319 Causes serious eye irritation
H371 May cause damage to organs
H373 May cause damage to organs through prolonged or repeated exposure
H410 Very toxic to aquatic life with long lasting effects
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P391 Collect spillage. Hazardous to the aquatic environment
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P337+P313 IF eye irritation persists: Get medical advice/attention.
P405 Store locked up.
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P272 Contaminated work clothing should not be allowed out of the workplace.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P301+P317 IF SWALLOWED: Get medical help.
P330 Rinse mouth.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P333+P317 If skin irritation or rash occurs: Get medical help.
P321 Specific treatment (see ... on this label).
P362+P364 Take off contaminated clothing and wash it before reuse.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P319 Get medical help if you feel unwell.
P391 Collect spillage.
none
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
Other hazards
no data available
Substance
- Product name: Triclopyr
- Synonyms: TRICLOPYR,TRICLOPYR ACID
- CAS: 55335-06-3
- EC number: 259-597-3
- MF: C7H4Cl3NO3
- MW: 256.47
Description of first aid measures
If inhaledFresh air, rest.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
Rinse with plenty of water for several minutes (remove contact lenses if easily possible).
Rinse mouth.
Most important symptoms and effects, both acute and delayed
no data available
Indication of any immediate medical attention and special treatment needed
Skin decontamination. Skin contamination should be treated promptly by washing with soap and water. Contamination of the eyes should be treated immediately by prolonged flushing of the eyes with large amounts of clean water. If dermal or ocular irritation persists, medical attention should be obtained without delay. Other herbicides
Extinguishing media
In case of fire in the surroundings, use appropriate extinguishing media.
Specific Hazards Arising from the Chemical
Not combustible.
Advice for firefighters
In case of fire in the surroundings, use appropriate extinguishing media.
NFPA 704
| HEALTH | 2 | Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine) | |
| FIRE | 0 | Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. Materials that will not burn in air when exposed to a temperature of 820 °C (1,500 °F) for a period of 5 minutes.(e.g. Carbon tetrachloride) | |
| REACT | 0 | Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2) | |
| SPEC. HAZ. |
Personal precautions, protective equipment and emergency procedures
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. Wash away remainder with plenty of water.
Environmental precautions
Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into covered containers. Wash away remainder with plenty of water.
Methods and materials for containment and cleaning up
Collect and arrange disposal. Keep the chemical in suitable and closed containers for disposal. Remove all sources of ignition. Use spark-proof tools and explosion-proof equipment. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations.
Precautions for safe handling
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Conditions for safe storage, including any incompatibilities
Keep in the dark.
Control parameters
Occupational Exposure limit valuesno data available
no data available
Exposure controls
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Individual protection measures
Eye/face protectionWear safety spectacles.
Protective gloves.
Use local exhaust.
no data available
Information on basic physicochemical properties
- Physical stateLiquid
- ColourFluffy solid
- Odour
no data available
- Melting point/freezing point
148-150°C
- Boiling point or initial boiling point and boiling range
290°C
- Flammability
Not combustible.
- Lower and upper explosion limit/flammability limit
no data available
- Flash point
171°C
- Auto-ignition temperature
no data available
- Decomposition temperature
208°C
- pH
no data available
- Kinematic viscosity
no data available
- SolubilityChloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
- Partition coefficient n-octanol/water
no data available
- Vapour pressure
1.26X10-6 mm Hg @ 25 deg C
- Density and/or relative density
1.669 g/cm3
- Relative vapour density
no data available
- Particle characteristics
no data available
Reactivity
Decomposes on heating and under the influence of UV light. This produces toxic and corrosive fumes including hydrogen chloride (see ICSC 0163) and nitrogen dioxide (see ICSC 0930).
Chemical stability
no data available
Possibility of hazardous reactions
Decomposes on heating and under the influence of UV light. This produces toxic and corrosive fumes including hydrogen chloride (see ICSC 0163) and nitrogen dioxide (see ICSC 0930).
Conditions to avoid
no data available
Incompatible materials
no data available
Hazardous decomposition products
When heated to decomposition it emits toxic fumes of chloride ion and nitric oxides.
Acute toxicity
- Oral: LD50 Rat (male) oral 729 mg/kg
- Inhalation: LC50 Rat inhalation >256 ppm/4 hr
- Dermal: no data available
Skin corrosion/irritation
no data available
Serious eye damage/irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
Cancer Classification: Group D Not Classifiable as to Human Carcinogenicity
Reproductive toxicity
no data available
STOT-single exposure
May cause mechanical irritation.
STOT-repeated exposure
no data available
Aspiration hazard
A nuisance-causing concentration of airborne particles can be reached quickly when dispersed.
Toxicity
- Toxicity to fish: LC50 Rainbow trout 117 mg/l/96 hr
- Toxicity to daphnia and other aquatic invertebrates: no data available
- Toxicity to algae: no data available
- Toxicity to microorganisms: no data available
Persistence and degradability
AEROBIC: Under aerobic soil metabolism conditions, triclopyr, at 1 ppm, degraded with half-lives of 8 and 18 days in silty clay loam and silt loam soils, respectively(1). The non-volatile degradates observed during the study were 3,5,6-trichloro-2-pyridinol (TCP) and 3,5,6-trichloro-2-methoxypyridine (TMP)(1); they were not persistent (max concns of 26 and 8%, respectively, were seen after <30 days of incubation)(1). The ultimate degradate was carbon dioxide (at 300 days post-treatment, approx 70 and 80% of the applied radioactivity in the silt loam and silty clay soils, respectively)(1). Triclopyr degraded slowly (half-life = 142 days) in a silty clay soil:water system incubated aerobically for 30 days(1). The only degradate observed was 3,5,6-trichloro-2-pyridinol at <5% of the amount applied after 30 days(1). Triclopyr was applied to the top layer of a column packed with loam soil(1). Water, equivalent to 2.5 cm of precipitation was leached through the column every second day(1). After 54 days, residues of triclopyr were found in the 10-cm layers of the soil; the residues were triclopyr and the metabolites, 3,5,6-trichloro-2-pyridinol and 2-methoxy-3,5,6-trichloropyridine, accounting for 5,85, and 10%, respectively, of the total of the residues which, in turn, was equivalent to 65% of the amount applied to the top layers(1). No residues were detected in the lower soil layers(1).
Bioaccumulative potential
An estimated BCF of 3 was calculated for triclopyr(SRC), using an estimated log Kow of 2.53(1) and a regression-derived equation(2). According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC).
Mobility in soil
Koc values for triclopyr range from 1.5 to 134 at pH values of 5.0 to 7.7(1). According to a classification scheme(2), these Koc values suggest that triclopyr will have very high to high mobility in soil(SRC). Based on adsorption/desorption studies using sand, sandy loam, silt loam, and clay loam soils, unaged triclopyr was very mobile. Freundlich Kd values ranged from 0.165 to 0.975 ml/g(3); Kocs were 25-384 ml/g. Adsorption was not correlated with CEC or organic carbon content(3). Kd values for triclopyr on four soils ranged from 0.08 to 0.61 ml/g(4).
Other adverse effects
no data available
Disposal methods
ProductThe material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
UN Number
ADR/RID: no data available
IMDG: no data available
IATA: no data available
UN Proper Shipping Name
ADR/RID: no data available
IMDG: no data available
IATA: no data available
Transport hazard class(es)
ADR/RID: no data available
IMDG: no data available
IATA: no data available
Packing group, if applicable
ADR/RID: no data available
IMDG: no data available
IATA: no data available
Environmental hazards
ADR/RID: Yes
IMDG: Yes
IATA: Yes
Special precautions for user
no data available
Transport in bulk according to IMO instruments
no data available
Safety, health and environmental regulations specific for the product in question
European Inventory of Existing Commercial Chemical Substances (EINECS)Abbreviations and acronyms
- CAS: Chemical Abstracts Service
- ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road
- RID: Regulation concerning the International Carriage of Dangerous Goods by Rail
- IMDG: International Maritime Dangerous Goods
- IATA: International Air Transportation Association
- TWA: Time Weighted Average
- STEL: Short term exposure limit
- LC50: Lethal Concentration 50%
- LD50: Lethal Dose 50%
- EC50: Effective Concentration 50%
References
- IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home
- HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm
- IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/
- eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en
- CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple
- ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp
- ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg
- Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp
- ECHA - European Chemicals Agency, website: https://echa.europa.eu/
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.