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Heteroatom Chemistry

Heteroatom Chemistry

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New Insights into the Mechanism of Reduction of Tertiary Phosphine Oxides by Means of Phenylsilane

Published:27 July 2015 DOI: 10.1002/hc.21279
Oleg M. Demchuk, Radomir Jasiński, K. Micha? Pietrusiewicz

Abstract

The mechanism of the reduction of phosphine oxides by PhSiH3 was established on the basis of kinetic measurements and Density Functional Theory (DFT) calculations. In particular, it has been proved that the model reaction between tri-n-butylphosphine oxide and phenylsilane occurs via a nonpolar mechanism. The data presented herein allow prediction and verification of the applicability of the new reduction reagents and conditions for industrially attractive processes.

Synthesis

Tributylphosphine sulfide
Tributylphosphine

Substances (1)

Related products
Procduct Name CAS Molecular Formula Supplier Price
TRI-N-BUTYLPHOSPHINE OXIDE 814-29-9 C12H27OP 230 suppliers $11.00-$2148.30

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