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ChemicalBook > Product Catalog >Organic Chemistry >Hydrocarbons and derivatives >DifluoroiodoMethyl phenyl sulfone

DifluoroiodoMethyl phenyl sulfone

DifluoroiodoMethyl phenyl sulfone Suppliers list
Company Name: LEAPCHEM CO., LTD.
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Products Intro: Product Name:(Difluoroiodomethylsulfonyl) benzene
CAS:802919-90-0
Purity:0 Package:1g; 5g; 25g; 1kg; 5kg; 25kg Remarks:0
Company Name: Aladdin Scientific
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Products Intro: Product Name:((Difluoroiodomethyl)sulfonyl)benzene
CAS:802919-90-0
Purity:98% Package:$31.9/50mg;$130.9/250mg;Bulk package Remarks:98%
Company Name: Chengdu Feibo Pharm Technology Co., Ltd  
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Products Intro: Product Name:DifluoroiodoMethyl phenyl sulfone
CAS:802919-90-0
Purity:95%+ Package:5g;50g;100g;250g;500g;1kg;5kg
Company Name: J & K SCIENTIFIC LTD.  
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Products Intro: Product Name:Difluoroiodomethyl phenyl sulfone, 98%
CAS:802919-90-0
Purity:98% Package:1G;250MG
Company Name: Daicel Chiral Technologies (China)CO.,LTD  
Tel: 021-50460086-9 15921403865
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Products Intro: Product Name:(Difluoroiodomethyl)sulfonyl]-benzene
CAS:802919-90-0
Purity:95%/98% Package:1G;100G;1KG Remarks:201207
DifluoroiodoMethyl phenyl sulfone Basic information
Product Name:DifluoroiodoMethyl phenyl sulfone
Synonyms:DifluoroiodoMethyl phenyl sulfone;(difluoroiodomethylsulfonyl)benzene;Benzene, [(difluoroiodomethyl)sulfonyl]-
CAS:802919-90-0
MF:C7H5F2IO2S
MW:318.08
EINECS:
Product Categories:
Mol File:802919-90-0.mol
DifluoroiodoMethyl phenyl sulfone Structure
DifluoroiodoMethyl phenyl sulfone Chemical Properties
Boiling point 312.4±42.0 °C(Predicted)
density 1.975±0.06 g/cm3(Predicted)
storage temp. 2-8°C(protect from light)
Safety Information
Safety Statements 24/25
HS Code 29309090
MSDS Information
DifluoroiodoMethyl phenyl sulfone Usage And Synthesis
DescriptionA visible light-catalysed direct and regioselective (phenylsulfonyl) difluoromethylation of imidazo[1,2-A]pyridines and benzo[d]-imidazo[2,1-b]thiazoles was carried out by DifluoroiodoMethyl phenyl sulfone under mild conditions. This synthetic methodology enables the introduction of a CF2SO2Ph group in an efficient and regioselective reaction through C-H bond functionalization with a broad substrate scope in good to excellent yields.
UsesIododifluoromethyl phenyl sulfone can be used for the difluoromethylation of alkenes and alkynes initiated by triethylborane/air or arenediazonium salt/titanium chloride in moderate to good yields.
Reactions(1) Difluoromethylation of terminal alkenes and alkynes.
DifluoroiodoMethyl phenyl sulfone
References[1] GUO-JIE YIN; W. F; Mei Zhu. Visible-light mediated regioselective (phenylsulfonyl)difluoromethylation of fused imidazoles with iododifluoromethyl phenyl sulfone[J]. Heterocyclic Communications, 2017. DOI:10.1515/hc-2017-0101.
[2] YA LI. Radical (Phenylsulfonyl)difluoromethylation with Iododifluoromethyl Phenyl Sulfone[J]. The Journal of Organic Chemistry, 2007. DOI:10.1021/jo070618s.
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