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ChemicalBook > Product Catalog >Organic Chemistry >Carboxylic acids and derivatives >Dibenzyl L-Tartrate

Dibenzyl L-Tartrate

Dibenzyl L-Tartrate Suppliers list
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Products Intro: Product Name:Dibenzyl L-Tartrate
CAS:622-00-4
Purity:>95% Package:25kg,1kg;250g,100g,10g
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Products Intro: Product Name:L-Tartaric Acid Dibenzyl Ester
CAS:622-00-4
Purity:98% HPLC Package:1KG;1USD
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Products Intro: Product Name:(+)-dibenzyl-L-tartrate
CAS:622-00-4
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Products Intro: Product Name:Dibenzyl L-Tartrate
CAS:622-00-4
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Products Intro: Product Name:Dibenzyl L-Tartrate
CAS:622-00-4
Purity:99 Package:5KG;1KG,25kg

Dibenzyl L-Tartrate manufacturers

Dibenzyl L-Tartrate Basic information
Product Name:Dibenzyl L-Tartrate
Synonyms:Dibenzyl L-Tartrate;Di Benzyl-L-Tartarate;L-TARTARIC AIC DIBENZYL ESTER;L-TARTARIC ACID DIBENZYL ESTER;L-DBT;(+)-DIBENZYL-L-TARTRATE;DIBENZYL L-TARTRATE;L-(+)-Dibenzyl Tartrate
CAS:622-00-4
MF:C18H18O6
MW:330.33
EINECS:
Product Categories:Chiral Building Blocks;Esters (Chiral);Synthetic Organic Chemistry;Asymmetric Synthesis;Chiral Catalysts, Ligands, and Reagents;EpoxidationChiral Building Blocks;Esters;Organic Building Blocks
Mol File:622-00-4.mol
Dibenzyl L-Tartrate Structure
Dibenzyl L-Tartrate Chemical Properties
Melting point 51-54 °C
Boiling point 427.78°C (rough estimate)
density 1.2036
refractive index -13 ° (C=1, Acetone)
form powder to crystal
pka11.38±0.20(Predicted)
color White to Almost white
optical activity[α]20/D +12.5±1°, c = 1.1% in acetone
BRN 3221733
CAS DataBase Reference622-00-4(CAS DataBase Reference)
Safety Information
Safety Statements 22-24/25
WGK Germany 3
3-10
HS Code 2918.13.5000
MSDS Information
ProviderLanguage
SigmaAldrich English
Dibenzyl L-Tartrate Usage And Synthesis
UsesPolyesters could be prepared from succinyl chloride, adipoly chloride, and telephthaloyl chloride with dibenzyl L-tartrate, polyurethanes from hexamethylene diisocyanate, tolune 2,4-diisocyanate, and methylene-bis(4-phenyl isocyanate) with dibenzyl L-tartrate[1].
SynthesisDibenzyl L-tartrate was obtained by the reaction of L-tartaric acid. Dibenzyl L-tartrate was precipitated with petroleum ether and purified by repeated recrystallization using ethyl ether-petroleum ether. (mp 50-51℃/lit. 50°C) [C, 65.28%; H, 5.46%, (calcd: c, 65.45%; H, 5.45% for C18H1806].
References[1] Noriyuki Kuramoto. “Carboxyl-containing polyesters and polyurethanes from dibenzyl L-tartrate.” Journal of Applied Polymer Science 29 3 (1984): 977–983.
Tag:Dibenzyl L-Tartrate(622-00-4) Related Product Information
L(+)-Tartaric acid (+)-Dimethyl L-tartrate BENZYL 2-HYDROXYBUTYRATE Ethyl (R)-4-benzyloxy-3-hydroxybutyrate. Benzyl lactate DIBENZYL SUCCINATE (2R,3S)-2,3-Dihydroxybutanedioic acid dimethyl ester D-LACTIC ACID-BENZYL ESTER (-)-1,4-DI-O-BENZYL-L-THREITOL (R)-3-Hydroxypiperidine hydrocloride Dibenzyl L-Tartrate (-)-Di-1,4-toluoyl-L-tartaric acid monohydrate

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