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ChemicalBook >> CAS DataBase List >> 1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane

1,3-Bis(diphenylphosphino)propane price.
  • $6 - $736.65
  • Product name: 1,3-Bis(diphenylphosphino)propane
  • CAS: 6737-42-4
  • MF: C27H26P2
  • MW: 412.45
  • EINECS:229-791-2
  • MDL Number:MFCD00003050
  • Synonyms:1,3-BIS(DIPHENYLPHOSPHINO)PROPANE;TRIMETHYLENEBIS(DIPHENYLPHOSPHINE);[3-(Diphenylphosphino)propyl](diphenyl)phosphine;1,3-Propanediylbis(diphenylphosphine);Phosphine, 1,3-propanediylbis[diphenyl-;Phosphine, trimethylenebis(diphenyl-;Propane-1,3-diylbis(diphenylphosphine);PROPYLENEBIS(DIPHENYLPHOSPHINE)
41 prices
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  • Acrotein
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  • ManufacturerAcrotein
  • Product numberAC-1576
  • Product description1,3-Bis(diphenylphosphino)propane 97%
  • Packaging250g
  • Price$385
  • Updated2021-12-16
  • Buy
  • ManufacturerAHH
  • Product numberMT-26878
  • Product description1,3-Bis(diphenylphosphino)propane 98%
  • Packaging100g
  • Price$330
  • Updated2021-12-16
  • Buy
  • ManufacturerAK Scientific
  • Product numberK871
  • Product descriptionDPPP,1,3-Bis(diphenylphosphino)propane
  • Packaging500g
  • Price$267
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12931
  • Product description1,3-Bis(diphenylphosphino)propane, 97%
  • Packaging5g
  • Price$76.9
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12931
  • Product description1,3-Bis(diphenylphosphino)propane, 97%
  • Packaging25g
  • Price$218.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA12931
  • Product description1,3-Bis(diphenylphosphino)propane, 97%
  • Packaging100g
  • Price$736.65
  • Updated2024-03-01
  • Buy
  • ManufacturerAlichem
  • Product number6737424
  • Product description1,3-Bis(diphenylphosphino)propane
  • Packaging500g
  • Price$212
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA150622
  • Product description1,3-Bis(diphenylphosphino)propane 97+%
  • Packaging10g
  • Price$9
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA150622
  • Product description1,3-Bis(diphenylphosphino)propane 97+%
  • Packaging25g
  • Price$14
  • Updated2021-12-16
  • Buy
  • ManufacturerAmbeed
  • Product numberA150622
  • Product description1,3-Bis(diphenylphosphino)propane 97+%
  • Packaging500g
  • Price$189
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS453956
  • Product description1,3-Bis(diphenylphosphino)propane ≥97%
  • Packaging5g
  • Price$6
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS453956
  • Product description1,3-Bis(diphenylphosphino)propane ≥97%
  • Packaging10g
  • Price$9
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS453956
  • Product description1,3-Bis(diphenylphosphino)propane ≥97%
  • Packaging25g
  • Price$14
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS453956
  • Product description1,3-Bis(diphenylphosphino)propane ≥97%
  • Packaging100g
  • Price$44
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS453956
  • Product description1,3-Bis(diphenylphosphino)propane ≥97%
  • Packaging1kg
  • Price$285
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB30424
  • Product description1,3-Bis(diphenylphosphino)propane
  • Packaging100g
  • Price$55
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AC-1576 1,3-Bis(diphenylphosphino)propane 97% 250g $385 2021-12-16 Buy
AHH MT-26878 1,3-Bis(diphenylphosphino)propane 98% 100g $330 2021-12-16 Buy
AK Scientific K871 DPPP,1,3-Bis(diphenylphosphino)propane 500g $267 2021-12-16 Buy
Alfa Aesar A12931 1,3-Bis(diphenylphosphino)propane, 97% 5g $76.9 2024-03-01 Buy
Alfa Aesar A12931 1,3-Bis(diphenylphosphino)propane, 97% 25g $218.65 2024-03-01 Buy
Alfa Aesar A12931 1,3-Bis(diphenylphosphino)propane, 97% 100g $736.65 2024-03-01 Buy
Alichem 6737424 1,3-Bis(diphenylphosphino)propane 500g $212 2021-12-16 Buy
Ambeed A150622 1,3-Bis(diphenylphosphino)propane 97+% 10g $9 2021-12-16 Buy
Ambeed A150622 1,3-Bis(diphenylphosphino)propane 97+% 25g $14 2021-12-16 Buy
Ambeed A150622 1,3-Bis(diphenylphosphino)propane 97+% 500g $189 2021-12-16 Buy
Arctom AS453956 1,3-Bis(diphenylphosphino)propane ≥97% 5g $6 2021-12-16 Buy
Arctom AS453956 1,3-Bis(diphenylphosphino)propane ≥97% 10g $9 2021-12-16 Buy
Arctom AS453956 1,3-Bis(diphenylphosphino)propane ≥97% 25g $14 2021-12-16 Buy
Arctom AS453956 1,3-Bis(diphenylphosphino)propane ≥97% 100g $44 2021-12-16 Buy
Arctom AS453956 1,3-Bis(diphenylphosphino)propane ≥97% 1kg $285 2021-12-16 Buy
Biosynth Carbosynth FB30424 1,3-Bis(diphenylphosphino)propane 100g $55 2021-12-16 Buy

Properties

Melting point :63-65 °C (lit.)
Boiling point :529.7±33.0 °C(Predicted)
Flash point :235°C
storage temp. :Inert atmosphere,Room Temperature
form :Granules or Powder
color :White to light yellow-beige
Water Solubility :insoluble
Sensitive :Air Sensitive
BRN :2821785
InChI :InChI=1S/C27H26P2/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27/h1-12,14-21H,13,22-23H2
InChIKey :LVEYOSJUKRVCCF-UHFFFAOYSA-N
SMILES :P(C1C=CC=CC=1)(C1C=CC=CC=1)CCCP(C1C=CC=CC=1)C1C=CC=CC=1
CAS DataBase Reference :6737-42-4(CAS DataBase Reference)
NIST Chemistry Reference :1,3-Bis(diphenylphosphino)propane(6737-42-4)
EPA Substance Registry System :Phosphine, 1,3-propanediylbis[diphenyl- (6737-42-4)

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

1,3-Bis(diphenylphosphino)propane is used as a bidentate ligand in coordination chemistry and form complex dichloro(1,3-bis(diphenylphosphino)propane)nickel by reacting with nickel(II) chloride. This complex is used as a catalyst for Kumada coupling reaction. It also acts as a ligand for palladium(II) catalysts which is useful for the co-polymerization of carbon monoxide and ethylene to get polyketones. Further, it is employed in palladium-catalyzed arylation under Heck reaction and Suzuki reaction. In addition to this, it serves as a catalyst for Negishi coupling and Sonogashira coupling reactions.

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