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ChemicalBook >> CAS DataBase List >> Diphenylphosphine

Diphenylphosphine

Diphenylphosphine price.
  • $33 - $1465
  • Product name: Diphenylphosphine
  • CAS: 829-85-6
  • MF: C12H11P
  • MW: 186.19
  • EINECS:212-591-4
  • MDL Number:MFCD00003040
  • Synonyms:PHOSPHINE, DIPHENYL;Diphenyl-phosphane ;Diphenyl phospine;Diphenylphosphine,99%;Diphenylphosphine,99%(10wt%inhexane);DIPHENYLPHOSPHINE;AURORA KA-1107;DIPHENYLPHOSPHINE OR PHOSPHINE, DIPHENYL
19 prices
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  • Acrotein
  • Alfa Aesar
  • Chemenu
  • Oakwood
  • Sigma-Aldrich
  • Strem Chemicals
  • TRC
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  • ManufacturerAcrotein
  • Product numberAC-2972
  • Product descriptionDiphenylphosphine 97%
  • Packaging25mL
  • Price$73.33
  • Updated2021-12-16
  • Buy
  • ManufacturerAcrotein
  • Product numberAC-2972
  • Product descriptionDiphenylphosphine 97%
  • Packaging100mL
  • Price$234.67
  • Updated2021-12-16
  • Buy
  • ManufacturerAlfa Aesar
  • Product number056169
  • Product descriptionDiphenylphosphine
  • Packaging10g
  • Price$71.19
  • Updated2023-01-06
  • Buy
  • ManufacturerAlfa Aesar
  • Product number056169
  • Product descriptionDiphenylphosphine
  • Packaging50g
  • Price$278.25
  • Updated2023-01-06
  • Buy
  • ManufacturerChemenu
  • Product numberCM333431
  • Product descriptiondiphenylphosphane 95%+
  • Packaging1000g
  • Price$339
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number050092
  • Product descriptionDiphenylphosphine
  • Packaging25g
  • Price$33
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number050092
  • Product descriptionDiphenylphosphine
  • Packaging100g
  • Price$120
  • Updated2021-12-16
  • Buy
  • ManufacturerOakwood
  • Product number050092
  • Product descriptionDiphenylphosphine
  • Packaging1Kg
  • Price$1050
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number252964
  • Product descriptionDiphenylphosphine 98%
  • Packaging10g
  • Price$85.7
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number252964
  • Product descriptionDiphenylphosphine 98%
  • Packaging50g
  • Price$302
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number252964
  • Product descriptionDiphenylphosphine 98%
  • Packaging1kg
  • Price$1450
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-1700
  • Product descriptionDiphenylphosphine, 99%
  • Packaging10g
  • Price$68
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-1702
  • Product descriptionDiphenylphosphine, 99% (10 wt% in hexanes)
  • Packaging100g
  • Price$119
  • Updated2024-03-01
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  • ManufacturerStrem Chemicals
  • Product number15-1701
  • Product descriptionDiphenylphosphine min. 97% (30 wt% in 2-methyltetrahydrofuran) Diphenylphosphine min. 97% (30 wt% in 2-methyltetrahydrofuran)
  • Packaging25g
  • Price$141
  • Updated2021-12-16
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-1700
  • Product descriptionDiphenylphosphine, 99%
  • Packaging50g
  • Price$254
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number15-1702
  • Product descriptionDiphenylphosphine, 99% (10 wt% in hexanes)
  • Packaging500g
  • Price$310
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Acrotein AC-2972 Diphenylphosphine 97% 25mL $73.33 2021-12-16 Buy
Acrotein AC-2972 Diphenylphosphine 97% 100mL $234.67 2021-12-16 Buy
Alfa Aesar 056169 Diphenylphosphine 10g $71.19 2023-01-06 Buy
Alfa Aesar 056169 Diphenylphosphine 50g $278.25 2023-01-06 Buy
Chemenu CM333431 diphenylphosphane 95%+ 1000g $339 2021-12-16 Buy
Oakwood 050092 Diphenylphosphine 25g $33 2021-12-16 Buy
Oakwood 050092 Diphenylphosphine 100g $120 2021-12-16 Buy
Oakwood 050092 Diphenylphosphine 1Kg $1050 2021-12-16 Buy
Sigma-Aldrich 252964 Diphenylphosphine 98% 10g $85.7 2024-03-01 Buy
Sigma-Aldrich 252964 Diphenylphosphine 98% 50g $302 2024-03-01 Buy
Sigma-Aldrich 252964 Diphenylphosphine 98% 1kg $1450 2024-03-01 Buy
Strem Chemicals 15-1700 Diphenylphosphine, 99% 10g $68 2024-03-01 Buy
Strem Chemicals 15-1702 Diphenylphosphine, 99% (10 wt% in hexanes) 100g $119 2024-03-01 Buy
Strem Chemicals 15-1701 Diphenylphosphine min. 97% (30 wt% in 2-methyltetrahydrofuran) Diphenylphosphine min. 97% (30 wt% in 2-methyltetrahydrofuran) 25g $141 2021-12-16 Buy
Strem Chemicals 15-1700 Diphenylphosphine, 99% 50g $254 2024-03-01 Buy
Strem Chemicals 15-1702 Diphenylphosphine, 99% (10 wt% in hexanes) 500g $310 2024-03-01 Buy

Properties

Melting point :-14.5 °C
Boiling point :280 °C(lit.)
Density :1.07 g/mL at 25 °C(lit.)
vapor pressure :2 mm Hg ( 110 °C)
refractive index :n20/D 1.625(lit.)
Flash point :-18°C (Hexane)
storage temp. :2-8°C
solubility :Chloroform
form :liquid
pka :diphenylphosphine is weakly basic. The pKa of the protonated derivative is 0.03.
color :colorless
Specific Gravity :0.68
Water Solubility :Miscible with ethanol, ether, benzene, concentrated hydrochloric acid. Immiscible with water.
Sensitive :Air & Moisture Sensitive
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
BRN :742504
InChIKey :GPAYUJZHTULNBE-UHFFFAOYSA-N
CAS DataBase Reference :829-85-6(CAS DataBase Reference)
NIST Chemistry Reference :Phosphine, diphenyl-(829-85-6)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H250 Catches fire spontaneously if exposed to air Pyrophoric liquids; Pyrorophoric solids Category 1 Danger GHS hazard pictograms P210, P222, P280, P302+P334,P370+P378, P422
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P222 Do not allow contact with air.
P231+P232 Handle under inert gas. Protect from moisture.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.

Description

Diphenylphosphine acts as an intermediate in the preparation of diphenylphosphide derivatives, phosphonium salts, phosphine ligands and Wittig-Horner reagents. The presence of hydrogen atom bonded to phosphorus undergoes Michael-like addition to activated alkenes. It is involved in the preparation of 1,2-bis(diphenylphosphino)ethane and (phenyl-(phenylmethyl)phosphoryl)benzene. Further, it is used in the synthesis of aminophosphines and chiral palladacycles with N-heterocyclic carbene ligands as catalysts.

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