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ChemicalBook >> CAS DataBase List >> Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)

Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) price.
  • $33.8 - $501.07
  • Product name: Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
  • CAS: 220114-38-5
  • MF: C66H64Cl2N2P2Ru
  • MW: 1119.17
  • EINECS:
  • MDL Number:MFCD09753028
  • Synonyms:Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II);RuCl2[(R)-DM-BINAP][(R,R)-DPEN];RuCl2[(R)-xylbinap][(R,R)-dpen];Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen];-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II),RuCl2[(;RUCL2[(R)-DM-BINAP][(R,R)-DPEN] 1G;DICHLORO{(R)-(+)-2,2'-BIS[DI(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL}[(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM(II),RUCL2[(;Dichloro[(R)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl][(R,R)-1,2-diphenylethylenediamine]ruthenium(II)
13 prices
Selected condition：
Brand
  • AK Scientific
  • American Custom Chemicals Corporation
  • Arctom
  • Chemenu
  • Chem-Impex
  • Sigma-Aldrich
  • Strem Chemicals
  • TCI Chemical
Package
  • 5MG
  • 50mg
  • 100mg
  • 200mg
  • 250mg
  • 1g
  • 5g
  • ManufacturerAK Scientific
  • Product number8932AL
  • Product descriptionRuCl2[(R)-xylbinap][(R,R)-dpen]
  • Packaging200mg
  • Price$147
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberING0013141
  • Product descriptionDICHLORO-[(R)-(+)-2,2'-BIS-[DI-(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL]-[(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM-(II) 95.00%
  • Packaging5MG
  • Price$501.07
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS626980
  • Product descriptionRuCl2[(R)-xylbinap][(R,R)-dpen] 98%
  • Packaging250mg
  • Price$92
  • Updated2021-12-16
  • Buy
  • ManufacturerArctom
  • Product numberAS626980
  • Product descriptionRuCl2[(R)-xylbinap][(R,R)-dpen] 98%
  • Packaging1g
  • Price$229
  • Updated2021-12-16
  • Buy
  • ManufacturerChemenu
  • Product numberCM102989
  • Product descriptionDichloro{(R)-(+)-2,2''-bis[di(3,5-xylyl)phosphino]-1,1''-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) 98%
  • Packaging1g
  • Price$320
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number40798
  • Product descriptionRuCl2[(R)-xylbinap][(R,R)-dpen]
  • Packaging200MG
  • Price$74.55
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number692301
  • Product descriptionRuCl2[(R)?DM?BINAP][(R,R)?DPEN]
  • Packaging50mg
  • Price$33.8
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number692301
  • Product descriptionRuCl2[(R)?DM?BINAP][(R,R)?DPEN]
  • Packaging100mg
  • Price$48.6
  • Updated2023-06-20
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0226
  • Product descriptionDichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen]
  • Packaging250mg
  • Price$64
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0226
  • Product descriptionDichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen]
  • Packaging1g
  • Price$190
  • Updated2024-03-01
  • Buy
  • ManufacturerStrem Chemicals
  • Product number44-0226
  • Product descriptionDichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen]
  • Packaging5g
  • Price$474
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberR0135
  • Product descriptionRuCl2[(R)-xylbinap][(R,R)-dpen]
  • Packaging200mg
  • Price$75
  • Updated2024-03-01
  • Buy
  • ManufacturerTCI Chemical
  • Product numberR0135
  • Product descriptionRuCl2[(R)-xylbinap][(R,R)-dpen]
  • Packaging1g
  • Price$253
  • Updated2024-03-01
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 8932AL RuCl2[(R)-xylbinap][(R,R)-dpen] 200mg $147 2021-12-16 Buy
American Custom Chemicals Corporation ING0013141 DICHLORO-[(R)-(+)-2,2'-BIS-[DI-(3,5-XYLYL)PHOSPHINO]-1,1'-BINAPHTHYL]-[(1R,2R)-(+)-1,2-DIPHENYLETHYLENEDIAMINE]RUTHENIUM-(II) 95.00% 5MG $501.07 2021-12-16 Buy
Arctom AS626980 RuCl2[(R)-xylbinap][(R,R)-dpen] 98% 250mg $92 2021-12-16 Buy
Arctom AS626980 RuCl2[(R)-xylbinap][(R,R)-dpen] 98% 1g $229 2021-12-16 Buy
Chemenu CM102989 Dichloro{(R)-(+)-2,2''-bis[di(3,5-xylyl)phosphino]-1,1''-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) 98% 1g $320 2021-12-16 Buy
Chem-Impex 40798 RuCl2[(R)-xylbinap][(R,R)-dpen] 200MG $74.55 2021-12-16 Buy
Sigma-Aldrich 692301 RuCl2[(R)?DM?BINAP][(R,R)?DPEN] 50mg $33.8 2024-03-01 Buy
Sigma-Aldrich 692301 RuCl2[(R)?DM?BINAP][(R,R)?DPEN] 100mg $48.6 2023-06-20 Buy
Strem Chemicals 44-0226 Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen] 250mg $64 2024-03-01 Buy
Strem Chemicals 44-0226 Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen] 1g $190 2024-03-01 Buy
Strem Chemicals 44-0226 Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-xylbinap][(R,R)-dpen] 5g $474 2024-03-01 Buy
TCI Chemical R0135 RuCl2[(R)-xylbinap][(R,R)-dpen] 200mg $75 2024-03-01 Buy
TCI Chemical R0135 RuCl2[(R)-xylbinap][(R,R)-dpen] 1g $253 2024-03-01 Buy

Properties

storage temp. :2-8°C
form :Powder
color :yellow
Sensitive :air sensitive

Safety Information

Symbol(GHS): GHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning GHS hazard pictograms
Precautionary statements:
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352 IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P321 Specific treatment (see … on this label).
P332+P313 IF SKIN irritation occurs: Get medical advice/attention.
P362 Take off contaminated clothing and wash before reuse.

Description

RuCl2[(R)-DM-BINAP][(R,R)-DPEN] can catalyze the enantioselective asymmetric reduction of benzils to form the corresponding chiral 1,2-diols.

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