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- ?? ?
- 105 °C (lit.)
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- 1.153 g/mL at 25 °C (lit.)
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- n
20/D 1.498(lit.)
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- 63 °F
- ?? ??
- 2-8°C
- ??? ??
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- Colorless to Light orange to Yellow
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- ??????, ??? ? ??????? ?????. ?? ???.
- ??
- Moisture Sensitive
- BRN
- 1730851
- CAS ??????
- 2373-51-5(CAS DataBase Reference)
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- ?? ? ???? ?? (GHS)
| ??? ?? | F,Xi | ||
|---|---|---|---|
| ?? ???? ?? | 11-37 | ||
| ????? | 9-16-33 | ||
| ????(UN No.) | UN 1993 3/PG 2 | ||
| WGK ?? | 3 | ||
| RTECS ?? | WQ3700000 | ||
| F ?????? | 13 | ||
| ?? ?? | 3 | ||
| ???? | II | ||
| HS ?? | 2930909899 | ||
| ???? ?? | KE-05742 |
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CLEAR YELLOW TO BROWN LIQUID??
Chloromethyl methyl sulfide is used as a methylene transfer reagent for iron(II) mediated cyclopropanation and for carbonyl and aromatic compounds. It protects alcohols as their methylthiomethyl (MTM) ethers by reaction, e.g. with NaH/NaI in DME. It is also used for the preparation of MTM esters of carboxylic acids, e.g. by treatment of the K salt of the acid in the presence of NaI and 18-crown-6 and for reaction with cyclopentadienyl iron dicarbonyl dimer in the formation of an iron-containing methylene transfer agent.Synthesis Reference(s)
Tetrahedron Letters, 35, p. 6127, 1994 DOI: 10.1016/0040-4039(94)88094-8??????????? ?? ?? ? ???
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Disiloxane, 1,1,1,3-tetraethoxy-3,3-dimethyl- (9CI)
2-(?????)?????
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1,5-DICHLOROHEXAMETHYLTRISILOXANE
1,3-DICHLORO-1,3-DIMETHYL-1,3-DIPHENYLDISILOXANE
1,3-DICHLOROTETRAMETHYLDISILOXANE
S-Methyl methanethiolsulfonate
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Stannous chloride dihydrate
CHLOROMETHYL PHENYL SULFIDE
CHLOROMETHYL PHENYL SULFONE
PHENYL CHLOROTHIOFORMATE
CHLOROMETHYL 4-CHLOROPHENYL SULFIDE
CHLOROMETHYL PHENYL SULFOXIDE
CHLOROMETHYL THIOCYANATE
CHLOROMETHYL TRIFLUOROMETHYL SULFIDE
P-TOLUENESULFONYLMETHYL CHLORIDE
N-PROPYL CHLOROTHIOFORMATE
1-chloro-4-[(chloromethyl)sulphonyl]benzene
BIS(CHLOROMETHYL) SULFIDE
PHENYL CHLORODITHIOFORMATE
P-CHLOROPHENYL TRICHLOROMETHYL SULFIDE