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2,4-?????

2,4-?????
2,4-????? ??? ???
?? ??:
142-83-6
???:
2,4-?????
???(??):
2,4-?????;????????;2,4-??????
???:
(E,E)-2,4-Hexadienal
???(??):
2,4-HEXADIENAL;(2E,4E)-Hexa-2,4-dienal;SORBALDEHYDE;SORBIC ALDEHYDE;FEMA 3429;JACS-142-83-6;Hexa-2,4-dienal;n-Hex-2,4-dienal;T2 T4 HEXADIENAL;2,4-HEXADIEN-1-AL
CBNumber:
CB9143146
???:
C6H8O
??? ??:
96.13
MOL ??:
142-83-6.mol
MSDS ??:
SDS

2,4-????? ??

???
-16.5°C
?? ?
69 °C/20 mmHg (lit.)
??
0.895 g/mL at 20 °C 0.871 g/mL at 25 °C (lit.)
?? ??
>1 (vs air)
???
n20/D 1.541(lit.)
FEMA
3429 | TRANS,TRANS-2,4-HEXADIENAL
???
154 °F
?? ??
2-8°C
???
Almost insoluble in water, soluble in alcohol and oils.
??? ??
liquid
??
Colorless
Specific Gravity
0.871
??
????? ??? ? 10.00%. ??? ?? ?? ? ???
?? ??
??
???? ??
synthetic
???
??? ?? ??? ????? ???.
??
Air Sensitive
JECFA Number
1175
BRN
1698401
???
????. ?? ??. ?? ???, ???, ?? ???? ???? ????.
LogP
1.06
CAS ??????
142-83-6(CAS DataBase Reference)
IARC
2B (Vol. 101) 2013
NIST
2,4-Hexadienal, (E,E)-(142-83-6)
EPA
2,4-Hexadienal, (2E,4E)- (142-83-6)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? T,Xi,Xn
?? ???? ?? 22-24-34-43-36/37/38-20/21/22
????? 26-36/37/39-45-36
????(UN No.) UN 2922 8/PG 3
WGK ?? 3
RTECS ?? WG1925000
F ?????? 1-10
?? ?? ?? Irritant
TSCA Yes
?? ?? 6.1
???? III
HS ?? 29121900
?? ?? ??? 142-83-6(Hazardous Substances Data)
????(GHS): GHS hazard pictogramsGHS hazard pictograms
?? ?: Danger
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H314 ??? ?? ??? ?? ??? ??? ????? ?? ????? ?? 1A, B, C ?? GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P270 ? ??? ??? ??? ???, ???? ???? ???.
P280 ????/???/???/?????? ?????.
P303+P361+P353 ??(?? ????)? ??? ??? ?? ??? ??? ????? ??? ?? ????/?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
2
2 0

2,4-????? C??? ??, ??, ??

??

trans, frans-2,4-Hexadienal has a fresh, green, floral citrus odor. May be synthesized by slowly heating croton-aldehyde with acetaldehyde in the presence of pyridine at 85 - 90°C.

??? ??

liquid

??

Reported found in olive, roasted peanuts, tomato, caviar, fish, auto-oxidized salmon oil, tea, apricot, strawberry, wheaten bread, Russian cheeses, cooked chicken and beef, boiled mutton, hop oil, raw and roasted peanuts, soybean, olive, rice, buckwheat, malt, kiwifruit and scallops.

??

2,4-Hexadienal, is used in the synthesis of chiral cycloadducts. 2,4-Hexadienal is used as a flavouring agent, as a chemical intermediate in various organic synthetic reactions and as a raw material in the manufacture of sorbic acid. It is also used as in the manufacture of polymethine dyes, as a pharmaceutical intermediate in the manufacture of mitomycins and antihypercholesteraemics, as an inhibitor of corrosion for steel used in oil field operations, as a monomer in reactions with silane comonomers for the manufacture of polyalkenyloxysilane polymer and as a fumigant against larvae of the Caribbean fruit fly.

?? ??

Can be obtained by slowly heating crotonaldehyde with acetaldehyde in the presence of pyridine at 85 to 90°C.

?? ??

trans,trans-2,4-Hexadienal is a volatile is a flavor compound that is reported to occur in different types of tea.

2,4-????? ?? ?? ? ???

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2,4-????? ?? ??

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