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Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate

Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate ??? ???
?? ??:
105228-46-4
???:
Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate
???(??):
6-oxo-2;Benzyl (2S;3-diphenyl-;4-Morpholinecarboxylicacid;(2S,3R)-N-CBZ-6-OXO-2,3- DIPHENYLMORPHOLINE;(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylMorpholine;(2S,3R)-benzyl 6-oxo-2,3- diphenylmorpholine-4-carboxylate;(5S,6R)-(+)-4-Benzyloxycarbonyl-5,6-diphenyl-2-Morpholinone;(2S,3R)-(+)-N-Benzyloxycarbonyl-6-oxo-2,3-diphenylMorpholine;BENZYL (2S,3R)-(+)-6-OXO-2,3-DIPHENYL-4-MORPHOLINECARBOXYLATE
CBNumber:
CB8215941
???:
C24H21NO4
??? ??:
387.43
MOL ??:
105228-46-4.mol

Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate ??

???
205-207 °C(lit.)
??
66 º (c=5.5 in methylene chloride)
?? ?
583.5±50.0 °C(Predicted)
??
1.242±0.06 g/cm3(Predicted)
?? ??
2-8°C
?? ?? (pKa)
-3.33±0.60(Predicted)
optical activity
[α]25/D +66°, c = 5.5 in methylene chloride
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-37/39
WGK ?? 3
HS ?? 29349990
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate C??? ??, ??, ??

??

(2S,3R)-(+)-N-Z-6-oxo-2,3-diphenylmorpholine can be used as a starting material for the synthesis of:

Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate ?? ?? ? ???

???

?? ??


Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate ?? ??

???( 79)?? ??
??? ?? ??? ?? ?? ? ??
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Benzyl (2S,3R)-(+)-6-oxo-2,3-diphenyl-4-morpholinecarboxylate ?? ??:

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