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9-(4-tert-????)-3,6-??(??????)-9H-????

9-(4-tert-????)-3,6-??(??????)-9H-????
9-(4-tert-????)-3,6-??(??????)-9H-???? ??? ???
?? ??:
898546-82-2
???:
9-(4-tert-????)-3,6-??(??????)-9H-????
???(??):
9-(4-tert-????)-3,6-??(??????)-9H-????
???:
CzSi
???(??):
CZSI;9-(4-tert-Butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole;CzSi , 9-(4-tert-butylphenyl)-3,6-bis(triphenylsilyl)-9H-carba;9H-Carbazole, 9-[4-(1,1-dimethylethyl)phenyl]-3,6-bis(triphenylsilyl)-;[9-(4-tert-butylphenyl)-6-triphenylsilylcarbazol-3-yl]-triphenylsilane;9-(4-tert-Butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole ISO 9001:2015 REACH
CBNumber:
CB72484739
???:
C58H49NSi2
??? ??:
816.19
MOL ??:
898546-82-2.mol

9-(4-tert-????)-3,6-??(??????)-9H-???? ??

???
354 °C(Solv: chloroform (67-66-3); hexane (110-54-3))
??
1.05
??? ??
powder/crystals
??
???
InChIKey
WIHKEPSYODOQJR-UHFFFAOYSA-N
SMILES
N1(C2=CC=C(C(C)(C)C)C=C2)C2=C(C=C([Si](C3=CC=CC=C3)(C3=CC=CC=C3)C3=CC=CC=C3)C=C2)C2=C1C=CC([Si](C1=CC=CC=C1)(C1=CC=CC=C1)C1=CC=CC=C1)=C2
Fluorescene
λem?354 nm in CH2Cl2
Absorption
λmax?275 nm in?CH2Cl2

??

9-(4-tert-????)-3,6-??(??????)-9H-???? C??? ??, ??, ??

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CzSi is known for its high triplet energy, wide band-gap, and high glass-transition temperature (Tg >131 °C). It is one of the most widely-used TADF host materials for blue electrophosphorescence.

??

Carbazole-based host materials for blue electrophosphorescence.

?? ??

[1] Yunlong Jiang. “Efficient single light-emitting layer pure blue phosphorescent organic light-emitting devices with wide gap host and matched interlayer.” Journal of Luminescence 168 (2015): Pages 38-42.
[2] Ming-Han Tsai. “Triphenylsilyl- and Trityl-Substituted Carbazole-Based Host Materials for Blue Electrophosphorescence.” ACS Applied Materials & Interfaces 1 3 (2009): 567–574.
[3] Qi Zhu, Jinglin Xu. “High efficiency double light-emitting layer sky blue phosphor organic light-emitting diode with slow emission efficiency attenuation.” Heliyon 9 11 (2023): e22428.

9-(4-tert-????)-3,6-??(??????)-9H-???? ?? ?? ? ???

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9-(4-tert-????)-3,6-??(??????)-9H-???? ?? ??

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