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????? ??? ???
?? ??:
40487-42-1
???:
?????
???(??):
??????;PEN?METHALIN;?????;PEN?METHALIN(PENDIMETHALIN)
???:
Pendimethalin
???(??):
pendimethaline;penoxaline;PROWL;Prowl(R) (Pendimethaline);3,4-Dimethyl-2,6-dinitro-N-(1-ethylpropyl)-benzenamine;FRAMP;Stomp;waxup;wayup;AcuMen
CBNumber:
CB7245266
???:
C13H19N3O4
??? ??:
281.31
MOL ??:
40487-42-1.mol

????? ??

???
56-57°C
?? ?
330°C
??
1.17
???
1.5700 (estimate)
???
11 °C
?? ??
APPROX 4°C
???
DMSO: 100 mg/mL (355.48 mM)
?? ?? (pKa)
-2.24±0.33(Predicted)
??? ??
??
??? ??
??? ??
??
???-??? ??
???
<0.5mg/L
Merck
14,7084
BRN
2157711
InChIKey
CHIFOSRWCNZCFN-UHFFFAOYSA-N
LogP
5.180
NIST
Penoxaline(40487-42-1)
EPA
Pendimethalin (40487-42-1)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi;N,N,Xi,T,F
?? ???? ?? 43-50/53-39/23/24/25-23/24/25-11
????? 2-24-29-37-60-61-45-16-7-36/37
????(UN No.) UN3077 9/PG 3
WGK ?? 2
RTECS ?? BX5470000
?? ?? 9
???? III
HS ?? 29214990
?? ?? ??? 40487-42-1(Hazardous Substances Data)
?? LC50 (96-hour) for rainbow trout 138 μg/L and bluegill sunfish 199 μg/L; acute oral LD50 of the technical product for male and female rats 1,250 and 1,050 mg/kg, respectively (Ashton and Monaco, 1991)
???? ?? KE-14053
????(GHS): GHS hazard pictogramsGHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H302 ??? ??? ?? ?? ?? - ?? ?? 4 ?? GHS hazard pictograms P264, P270, P301+P312, P330, P501
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H410 ??? ??? ?? ????? ?? ??? ?? ????? ?? - ?? ?? 1 ?? GHS hazard pictograms P273, P391, P501
??????:
P273 ???? ???? ???.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
NFPA 704
0
1 0

????? MSDS


Herbadox

????? C??? ??, ??, ??

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Brown Solid

??

Herbicide used to control the spread of weedgrass.

??

ChEBI: A member of the class of substituted anilines that is N-(pentan-3-yl)aniline bearing two additional nitro substituents at positions 2 and 6 as well as two methyl substituents at positions 3 and 4. A herbicide used to control most annual rasses and many annual broad-leaved weeds.

?? ??

Orange-yellow crystals. Non corrosive. Used as an herbicide.

??? ?? ??

Insoluble in water.

?? ???

A dinitroaniline derivative.

???

Herbicide: Pendimethalin is a selective pre-emergence and post-emergence herbicide used on various agricultural and non-agricultural sites to control broadleaf weeds and grassy weeds in crops such as apricot, carrot, cherry, corn, cotton, fig, garbanzos, garlic, olive, onion, nectarine, peach, pear, pecan, plum, rice and prune, and noncrop areas. It is applied to soil preplant, pre-emergence, and post-emergence with ground and aerial equipment.

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AC 92553®; ACCOTAB®; BULLET® (pendimethalin + cyanazine); GO-GO-SAN®; HERBADOX®; PAY-OFF®; PENOXALIN®; PENOXALINE®; PROWL®; SIPAXOL®; SQUADRON® (with imazaquin); STOMP®; TATA PANIDA®; VALOR®; WAY-UP®

??? ??

Pendimethalin is a selective preemergence and postemergence 2,6-dinitroaniline herbicide used on various agricultural and non-agricultural sites to control broadleaf weeds and grassy weeds in crops such as apricot, carrot, cherry, corn, cotton, fig, garbanzos, garlic, olive, onion, nectarine, peach, pear, pecan, plum, rice and prune, and noncrop areas. It is applied to soil preplant, pre-emergence, and postemergence with ground and aerial equipment.

?? ?? ??

Irradiation of pendimethalin in methanol yields, in addition to the minor dealkylated product, the major products 2-amino-6-nitro-N-(1-ethylpropyl)-3,4-xylidine and 2-nitroso-6-nitro-3,4-xylidine. Pendimethalin degrades rapidly through reductive cyclization of the amino group and adjacent N-ethylpropyl to give a cyclized benzimidazole product. The photodecomposition of pendimethalin involves oxidative dealkylation, nitro reduction, and cyclization. By soil bacteria, pendimethalin degrades through different pathways from the photodegradation reaction, resulting in benzimidazole and hydroxylated products of the N-alkyl and xylyl methyl groups. The major metabolic routes of pendimethalin by rats involves hydroxylation of the 4-methyl and the N-ethyl group, oxidation of these alkyl groups to carboxylic acids, nitro reduction, cyclization, and conjugation in the urine and the tissues. Products of cyclization reactions giving methylbenzimidazole-carboxylic acids are unique metabolites to the liver and kidney.

?? ??

UN3077 Environmentally hazardous substances, solid, n.o.s., Hazard class: 9; Labels: 9-Miscellaneous hazardous material, Technical Name Required.

? ???

Reacts with oxidizers, acids and alkaline materials. Contact with strong oxidizers may cause fire and explosions.

??? ??

It is the responsibility of chemical waste generators to determine if a discarded chemical is classified as a hazardous waste. See 40 CFR Parts 261.3 for United States Environmental Protection Agency guidelines for the classification determination. Additionally, in order to ensure complete and accurate classification, waste generators must consult state and local hazardous waste regulations. Organic pesticides, whether of botanical or synthetic origin, can be destroyed by incineration equipped with scrubbers to remove acid wastes.

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???( 356)?? ??
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