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1,2-Dianilinoethane

1,2-Dianilinoethane ??? ???
?? ??:
150-61-8
???:
1,2-Dianilinoethane
???(??):
NODX;NSC 8719;Wanzlicks;Stabilite;wanzlick's reagent;1,2-DIANILINOETHANE;TIMTEC-BB SBB003424;N,N'-ETHYLENEDIANILINE;Stabilite (antioxidant);DIPHENYLETHYLENEDIAMINE
CBNumber:
CB5230224
???:
C14H16N2
??? ??:
212.29
MOL ??:
150-61-8.mol
MSDS ??:
SDS

1,2-Dianilinoethane ??

???
65-67 °C(lit.)
?? ?
228°C 12mm
??
1.0799 (rough estimate)
???
1.6000 (estimate)
???
228°C/12mm
??? ??
powder to crystal
?? ?? (pKa)
4.67±0.50(Predicted)
??
White to Light yellow to Light red
???
?? ??? 0.072 g/L @ 25°C.
Merck
14,2990
BRN
646740
InChI
InChI=1S/C14H16N2/c1-3-7-13(8-4-1)15-11-12-16-14-9-5-2-6-10-14/h1-10,15-16H,11-12H2
InChIKey
NOUUUQMKVOUUNR-UHFFFAOYSA-N
SMILES
C(NC1=CC=CC=C1)CNC1=CC=CC=C1
CAS ??????
150-61-8(CAS DataBase Reference)
EPA
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
??? ?? Xi
?? ???? ?? 36/37/38
????? 26-36
WGK ?? 3
RTECS ?? KV4800000
F ?????? 34
TSCA Yes
HS ?? 29214200
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P261 ??·?·??·???·??·...·????? ??? ????.
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P271 ?? ?? ??? ? ?? ???? ?????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
NFPA 704
0
1 0

1,2-Dianilinoethane C??? ??, ??, ??

??? ??

BEIGE TO LIGHT BROWN CRYSTALLINE POWDER

??

1,2-Dianilinoethane can forms crystalline imidazolidines with aldehydes in the presence of AcOH. N-donating ligand. Can be used as a trapping agent for aldehydes.

?? ??

N,N′-Diphenylethylenediamine can be used:
To prepare nickel(II) chelates to study their chemical reactivities.
To prepare N-heterocyclic carbene (NHC) adducts by reacting with substituted benzaldehydes.
As a starting material to prepare substituted cyclic poly(methyl methacrylate)s.

Purification Methods

Crystallise the reagent from aqueous EtOH or MeOH. [Beilstein 12 H 543, 12 IV 986.]

1,2-Dianilinoethane ?? ?? ? ???

???

?? ??


1,2-Dianilinoethane ?? ??

???( 156)?? ??
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1,2-Dianilinoethane ?? ??:

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