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(Triphenylphosphoranylidene)ketene

(Triphenylphosphoranylidene)ketene ??? ???
?? ??:
15596-07-3
???:
(Triphenylphosphoranylidene)ketene
???(??):
Bestmann Ylide;Ketenylidene(triphenyl)phosphorane;(Triphenylphosphoranylidene)ketene;(Triphenylphosphoranylidene)ethenone;2-triphenylphosphoranylideneethenone;Ethenone, 2-(triphenylphosphoranylidene)-;2-(triphenyl-$l^{5}-phosphanylidene)ethenone;2-(Triphenyl-lambda5-phosphanylidene)ethen-1-one;Ketenylidene(triphenyl)phosphorane Bestmann Ylide;(Triphenylphosphoranylidene)ethenone, Bestmann ylide, Ketenylidene(triphenyl)phosphorane
CBNumber:
CB41570302
???:
C20H15OP
??? ??:
302.31
MOL ??:
15596-07-3.mol
MSDS ??:
SDS

(Triphenylphosphoranylidene)ketene ??

???
167-173 °C
?? ?
455.4±38.0 °C(Predicted)
??
1.12±0.1 g/cm3(Predicted)
??? ??
solid
??
  • ?? ? ?? ??
WGK ?? 3
HS ?? 2931.90.6000
????(GHS):
?? ?:
??·?? ??:
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??????:
NFPA 704
0
1 0

(Triphenylphosphoranylidene)ketene C??? ??, ??, ??

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A nucleophilic two-carbon building block that participates in a variety of reactions including cycloaddition, multi-component, and domino reactions.

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(Triphenylphosphoranylidene)ketene (Ketenylidenetriphenylphosphorane) is prepared most conveniently by a β-elimination from (Methoxycarbonylmethylene)triphenylphosphorane using Sodium Hexamethyldisilazide or Sodium Amide as a base (eq 1). 
(Triphenylphosphoranylidene)ketene synthesis

(Triphenylphosphoranylidene)ketene ?? ?? ? ???

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(Triphenylphosphoranylidene)ketene ?? ??

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(Triphenylphosphoranylidene)ketene ?? ??:

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