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2-?????-4-???????

2-?????-4-???????
2-?????-4-??????? ??? ???
?? ??:
3098-18-8
???:
2-?????-4-???????
???(??):
2-?????-4-???????
???:
2-HYDROXY-4-METHYLBENZOPHENONE
???(??):
2-HYDROXY-4-METHYLBENZOPHENONE;4'-Methyl-2-hydroxybenzophenone;Benzophenone, 2-Hydroxy-4-methyl-;Methanone, (2-hydroxy-4-methylphenyl)phenyl-
CBNumber:
CB2430599
???:
C14H12O2
??? ??:
212.24
MOL ??:
3098-18-8.mol

2-?????-4-??????? ??

???
62-65°C
?? ?
234°C/15mmHg(lit.)
??
1.164±0.06 g/cm3(Predicted)
???
???? ???
??? ??
powder to crystal
?? ?? (pKa)
8.05±0.35(Predicted)
??
White to Yellow to Green
?? ??(λmax)
375nm(MeOH (pH 11))(lit.)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
?? ???? ?? 36/37/38
????? 26-36/37/39
WGK ?? 3
HS ?? 2914.50.3000
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
??????:
P264 ?? ??? ?? ??? ????.
P264 ?? ??? ?? ??? ????.
P280 ????/???/???/?????? ?????.
P302+P352 ??? ??? ??? ?? ????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P332+P313 ?? ??? ??? ???? ??· ??? ????.
P337+P313 ?? ?? ??? ???? ???? ??· ??? ????.
NFPA 704
0
2 0

2-?????-4-??????? C??? ??, ??, ??

?? ??

Preparation by Friedel–Crafts acylation of m-cresol,
? with benzoic acid in the presence of boron trifluoride at 160° for 2 h (94%) or in the presence of Amberlyst-15 in refluxing chlorobenzene for 65 h (37%) ;
? with benzoyl chloride in the presence of aluminium chloride at 75°, in nitrobenzene at 60° for 18 h (8%) or with titanium tetrachloride in the same conditions (17%).

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