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13478-93-8
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NICKEL DIMETHYLGLYOXIME
???(??):
Nsc159141;NICKEL DIMETHYLGLYOXIME;Nickel dimethylglyoximate;Bis(dimethylglyoxime)nickel;NICKEL(II) DIMETHYLGLYOXIME;Bis(dimethylglyoximato)nickel;Nickel(II)dimethylglyoxime,99%;bis(butanedione dioximato)nickel;Bis(dimethylglyoximato)nickel (II);Bis(2,3-butanedione dioximato)nickel
CBNumber:
CB2203836
???:
C8H14N4NiO4
??? ??:
288.91
MOL ??:
13478-93-8.mol

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250°C (subl.)
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NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3
CAS ??????
13478-93-8
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  • ?? ? ???? ?? (GHS)
????(GHS): GHS hazard pictogramsGHS hazard pictograms
?? ?: Danger
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?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H317 ????? ?? ??? ??? ? ?? ?? ??? ?? ?? 1 ?? GHS hazard pictograms P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
H351 ?? ??? ??? ??? (????? ?? ???? ???? ???? ??? ?? ????? ??? ???? ??) ??? ?? ?? 2 ?? P201, P202, P281, P308+P313, P405,P501
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P201 ?? ? ?? ???? ?????.
P261 ??·?·??·???·??·...·????? ??? ????.
P280 ????/???/???/?????? ?????.
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.
P405 ???? ?????.
NFPA 704
0
2 0

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Nickel(II) Dimethylglyoximate [13478-93-8] bis(dimethylglyoximato) nickel(II), Ni(C4H7N2 O2)2, Mr 288.94, is obtained quantitatively as a bright-red precipitate when an alcoholic solution of dimethylglyoxime is added to a neutral or slightly alkaline solution of a nickel(II) salt. This reaction is used in the gravimetric estimation of nickel and is also useful as a spot test for the presence of nickel ions. The structure of this diamagnetic solid shows the nickel(II) ion to be in a squareplanar environment; the dotted lines represent strong intramolecular hydrogen bonds.

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Bright-red powder. Insoluble in water; soluble in mineral acids.

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As sun-fast pigment in paints, lacquers, cellulose compounds and cosmetics.

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