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(R)-Ph-Quinox

(R)-Ph-Quinox ??? ???
?? ??:
220108-54-3
???:
(R)-Ph-Quinox
???(??):
(R)-Ph-Quinox;(R)-4-phenyl-2-(quinolin-2-yl)-4,5-dihydrooxazole;2-[(4R)-4,5-dihydro-4-phenyl-2- oxazolyl]-Quinoline;Quinoline, 2-[(4R)-4,5-dihydro-4-phenyl-2-oxazolyl]-
CBNumber:
CB13150899
???:
C18H14N2O
??? ??:
274.32
MOL ??:
220108-54-3.mol

(R)-Ph-Quinox ??

?? ?
476.8±38.0 °C(Predicted)
??
1.22±0.1 g/cm3(Predicted)
?? ??
under inert gas (nitrogen or Argon) at 2-8°C
??? ??
??
?? ?? (pKa)
3.27±0.61(Predicted)
??
  • ?? ? ?? ??
  • ?? ? ???? ?? (GHS)
????(GHS): GHS hazard pictograms
?? ?: Warning
??·?? ??:
?? ??·?? ?? ?? ?? ?? ?? ? ?? ?? P- ??
H315 ??? ??? ??? ????? ?? ????? ?? 2 ?? GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 ?? ?? ??? ??? ?? ? ?? ?? ??? ?? ?? 2A ?? GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H335 ?? ???? ??? ? ?? ?? ???? ?? - 1? ??;???? ?? ?? 3 ?? GHS hazard pictograms
??????:
P305+P351+P338 ?? ??? ? ?? ?? ???? ????. ???? ?????? ?????. ?? ????.

(R)-Ph-Quinox C??? ??, ??, ??

??

This ligand has been proven effective in the enantioselective diamination of alkenes.

?? ??

(R)-Ph-Quinox-Pd-alkyl complex contains (R)-Ph-quinox (2-[(4R)-4,5-dihydro-4-phenyl-2-oxazolyl]quinolone) as a chiral ligand.

(R)-Ph-Quinox ?? ?? ? ???

???

?? ??


(R)-Ph-Quinox ?? ??

???( 25)?? ??
??? ?? ??? ?? ?? ? ??
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(R)-Ph-Quinox ?? ??:

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