tert-Butyldimethylsilane
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tert-Butyldimethylsilane ??
- ???
- 13°C
- ?? ?
- 81-83 °C (lit.)
- ??
- 0.701 g/mL at 25 °C (lit.)
- ???
- n
20/D 1.4(lit.)
- ???
- −9 °F
- ?? ??
- under inert gas (nitrogen or Argon) at 2-8°C
- ??? ??
- ??? ??
- ??
- ?? ?? ?? ??
- Specific Gravity
- 0.701
- Hydrolytic Sensitivity
- 3: reacts with aqueous base
- BRN
- 2231162
- InChI
- InChI=1S/C6H16Si/c1-6(2,3)7(4)5/h7H,1-5H3
- InChIKey
- QCIWZIYBBNEPKB-UHFFFAOYSA-N
- SMILES
- [SiH](C(C)(C)C)(C)C
- CAS ??????
- 29681-57-0
??
- ?? ? ?? ??
- ?? ? ???? ?? (GHS)
| ??? ?? | F,Xi | ||
|---|---|---|---|
| ?? ???? ?? | 11-36/37/38 | ||
| ????? | 16-26-36-16/26/36 | ||
| ????(UN No.) | UN 1993 3/PG 2 | ||
| WGK ?? | 3 | ||
| F ?????? | 10-21 | ||
| TSCA | Yes | ||
| ?? ?? | 3.1 | ||
| ???? | I | ||
| HS ?? | 29319090 |
tert-Butyldimethylsilane C??? ??, ??, ??
??
Tert-Butyldimethylsilane (t-BuMe2SiH) is widely used for the protection of hydroxy groups in sugars. Its oxidation product, tert-butyldimethylsilyl hydroperoxide (t-BuMe2SiOOH), is used for preparing luminiscent sources and prostanoids, specifically clavulons[1].?? ??
The iridium complex [Ir(COD)(PPh3)2]+SbF6- reacts with tert-butyldimethylsilane in DMA to form [IrH2(Sol)2(PPh3)2]+SbF6-, which is an active catalyst for the regioselective di- and trisilylation of a series of representative methyl hexopyranosides, β-1,6-anhydrohexopyranosides and 1,3,5-O-methylidene inositol.The silylcarbobicyclization of 4,4-disubstituted 1,6-heptadiynes with tert-butyldimethylsilane catalyzed by Rh(acac)(CO)2, Co2Rh2(CO)12, or (t-BuNC)4RhCo(CO)4 under 50 atm of carbon monoxide gives the corresponding novel 7,7-disubstituted 2-silylbicyclo[3.3.0]octa-1,5-dien-3-ones in good yields[2-3].
tert-Butyldimethylsilane ?? ?? ? ???
???
?? ??
tert-Butyldimethylsilane ?? ??
???( 158)?? ??
| ??? | ?? | ??? | ?? | ?? ? | ?? |
|---|---|---|---|---|---|
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factory@coreychem.com | China | 29809 | 58 |
tert-Butyldimethylsilane ?? ??:
??-??????????? 4-(???-??????????)-3-??-2-one (3R(1'R,4R))-(+)-4-????-3-(1-(T-??????????)ETH)-2- ????? ?????????? ??????????
TERT-BUTYLDIMETHYLSILANOL
t-Butyl methyl fumarate
ALLYLOXY-T-BUTYLDIMETHYLSILANE
t-butyldimethylIsopropoxylsilane
tert-butyl-methoxy-dimethylsilane
TERT-BUTYLDIMETHYLSILYL (R)-(-)-GLYCIDY&
Tert-butyl-dimethyl-(tributylstannylmethoxy)silane
tert-butyldimethyl(4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenoxy)silane
3-BROMOPROPOXY-T-BUTYLDIMETHYLSILANE,(3-BROMOPROPOXY)-TERT-BUTYLDIMETHYLSILANE
N-BUTYLDIMETHYLSILANE
N-(tert-Butyldimethylsilyl)-N-methyl-trifluoroacetamide
AMINOXY-TERT-BUTYLDIMETHYLSILANE
DIMETHYLTHEXYLSILYL CHLORIDE