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ChemicalBook >> CAS DataBase List >>2,4-DINITROBENZENESULFENYL CHLORIDE

2,4-DINITROBENZENESULFENYL CHLORIDE

CAS No.
528-76-7
Chemical Name:
2,4-DINITROBENZENESULFENYL CHLORIDE
Synonyms
KHARASCH REAGENT;DNP-SULFENYL CHLORIDE;LABOTEST-BB LT00453936;2,4-Dinitrophenylthio chloride;(2,4-Dinitrophenylthio) chloride;2,4-dinitro-benzenesulfenylchlorid;2,4-DINITROPHENYLSULFENYL CHLORIDE;2,4-DINITROBENZENESULFENYL CHLORIDE;2,4-dinitrophenyl hypochlorothioite;2,4-Dinitrobenzenesulphenyl chloride
CBNumber:
CB8349604
Molecular Formula:
C6H3ClN2O4S
Molecular Weight:
234.62
MDL Number:
MFCD00007129
MOL File:
528-76-7.mol
Last updated:2024-12-18 14:15:30

2,4-DINITROBENZENESULFENYL CHLORIDE Properties

Melting point 94-97 °C(lit.)
Boiling point 430.1±35.0 °C(Predicted)
Density 1.700 (estimate)
refractive index 1.6000 (estimate)
storage temp. 2-8°C
solubility benzene: soluble
form solid
color Light orange to Yellow to Green
Merck 14,3274
BRN 405600
CAS DataBase Reference 528-76-7(CAS DataBase Reference)
FDA UNII 6XLF60A5YM
EPA Substance Registry System Benzenesulfenyl chloride, 2,4-dinitro- (528-76-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07
Signal word  Danger
Hazard statements  H314-H228-H302+H312+H332
Precautionary statements  P280-P305+P351+P338-P310-P210-P240-P241-P260-P264-P270-P271-P301+P330+P331+P310-P303+P361+P353+P310+P363-P304+P340+P310-P305+P351+P338+P310-P370+P378-P405-P501
Hazard Codes  C
Risk Statements  34-37
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
F  8-9-19-21
HS Code  2930.90.2900
HazardClass  8
PackingGroup  III

2,4-DINITROBENZENESULFENYL CHLORIDE price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical D1463 2,4-Dinitrophenylsulfenyl Chloride >96.0%(T) 528-76-7 5g $44 2024-03-01 Buy
TRC D479836 2,4-Dinitrobenzenesulfenyl chloride 528-76-7 500mg $55 2021-12-16 Buy
Biosynth Carbosynth FD61093 2,4-Dinitrophenylsulfenyl Chloride 528-76-7 2g $60 2021-12-16 Buy
Biosynth Carbosynth FD61093 2,4-Dinitrophenylsulfenyl Chloride 528-76-7 5G $100 2021-12-16 Buy
Biosynth Carbosynth FD61093 2,4-Dinitrophenylsulfenyl Chloride 528-76-7 10g $150 2021-12-16 Buy
Product number Packaging Price Buy
D1463 5g $44 Buy
D479836 500mg $55 Buy
FD61093 2g $60 Buy
FD61093 5G $100 Buy
FD61093 10g $150 Buy

2,4-DINITROBENZENESULFENYL CHLORIDE Chemical Properties,Uses,Production

Uses

2,4-Dinitrobenzenesulfenyl chloride was used in preparation of chlorine and bromine biphenyls.

Preparation

CAUTION: This reaction should be carried out in a hood behind a safety shield. The product decomposes explosively if heated above 90-100°C .
To a 500-ml, three-necked flask equipped with a mechanical stirrer, distillation column, and distillation head is added 100 gm (0.25 mole) of dry 2,4-dinitrophenyl disulfide and 250 ml of ethylene chloride. The contents are heated with an oil bath at 125°C until 30-40 ml of the solvent is collected by distillation. The contents are cooled and the distillation head replaced by a gas inlet and exit tube connected to an alkali trap. Then 0.15 gm (0.002 mole) of Merck "Iron by Hydrogen" powder is added as a catalyst [51a-c], and dry chlorine gas is slowly bubbled into the reaction. In a few minutes, the reaction warms up, and the flask is surrounded with a 20°C water bath. The chlorine gas is bubbled in at such a rate that 18 gm (0.25 mole) is added over a 1-1½-hr period. After this time, the suspended disulfide should gradually disappear, and a clear, amber-red solution results. The flow of chlorine gas is stopped, the solution stirred for 1 hr, filtered through diatomaceous earth, the filtrate aspirated to remove excess chlorine, and then 400 ml of anhydrous ether is added. Within ½ hr, most of the product crystallizes by cooling the flask in an ice-salt-water bath for 3-4 hr. The product is filtered, washed with 100 ml of cold ether, and then dried to afford 70 gm (60%) of brilliant yellow needles, m.p. 95-95.5°C.
Preparation of 2,4-Dinitrobenzenesulfenyl Chloride by the Chlorinolysis of 2,4-Dinitrophenyl Disulfide

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 1796, 1950 DOI: 10.1021/ja01160a108

General Description

2,4-Dinitrobenzenesulfenyl chloride undergoes addition reactions with transannularly substituted cycloalkenes and norbornenes. 2,4-Dinitrobenzenesulfenyl chloride can convert allylic alcohols to dienes by 1,4-elimination.

Purification Methods

Crystallise the sulfenyl chloride from CCl4. [Beilstein 6 II 316.]

2,4-DINITROBENZENESULFENYL CHLORIDE Preparation Products And Raw materials

Raw materials

Preparation Products

2,4-DINITROBENZENESULFENYL CHLORIDE Suppliers

Global( 64)Suppliers
Supplier Tel Email Country ProdList Advantage
Nanjing jinheyou Trading Co., Ltd. 		15705188088 admin@jheyou.com CHINA 1268 58
career henan chemical co 		+86-0371-86658258 +8613203830695 factory@coreychem.com China 29810 58
Shaanxi Dideu Medichem Co. Ltd 		+86-29-87569262 +86-15003564040 1087@dideu.com China 3199 58
Dayang Chem (Hangzhou) Co.,Ltd. 		571-88938639 +8617705817739 info@dycnchem.com China 52849 58
GIHI CHEMICALS CO.,LIMITED 		+8618058761490 info@gihichemicals.com China 49978 58
Aladdin Scientific 		+1-+1(833)-552-7181 sales@aladdinsci.com United States 57505 58
Mainchem Co., Ltd. +86-0592-6210733 sale@mainchem.com China 32343 55
Suzhou Highfine Biotech Co., Ltd 0512-68417696 18306209966 linda@highfine.com China 1407 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 021-61259108 18621169109 market03@meryer.com China 40228 62

View Lastest Price from 2,4-DINITROBENZENESULFENYL CHLORIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,4-Dinitrophenylsulfenyl Chloride pictures 2025-01-03 2,4-Dinitrophenylsulfenyl Chloride
528-76-7
 US $0.00-0.00 / KG 10mg 99%HPLC 2000tons Shaanxi Dideu Medichem Co. Ltd
2,4-DINITROBENZENESULFENYL CHLORIDE pictures 2020-01-10 2,4-DINITROBENZENESULFENYL CHLORIDE
528-76-7
 US $9.80 / KG 1g ≥99% 100kg Career Henan Chemical Co
2,4-DINITROBENZENESULFENYL CHLORIDE pictures 2019-11-08 2,4-DINITROBENZENESULFENYL CHLORIDE
528-76-7
 US $0.00 / g 1g 99.5%min 20kg/week Nanjing jinheyou Trading Co., Ltd.
2,4-dinitro-benzenesulfenylchlorid KHARASCH REAGENT LABOTEST-BB LT00453936 DNP-SULFENYL CHLORIDE 2,4-Dinitrobenzenesulphenyl chloride Benzenesulfenyl chloride,2,4-dinitro- 2 4-DINITROPHENYL SULFENYL CHLORIDE 96% 2,4-DINITROBENZENESULFENYL CHLORIDE 2,4-DINITROPHENYLSULFENYL CHLORIDE 2,4-Dinitrophenylsulfenyl chloride, Kharasch reagent (2,4-Dinitrophenylthio) chloride 2,4-Dinitrophenylthio chloride 2,4-dinitrophenyl hypochlorothioite (2,4-dinitrophenyl) thiohypochlorite 2,4-Dinitrophenylsulfenyl Chloride > 528-76-7 C6H3ClN2O4S O2N2C6H3SCl Peptide Synthesis Protective Reagents (Peptide Synthesis) Protection & Derivatization Reagents (for Synthesis) Protein Modification Proteomics and Protein Expression Proteomics Reagents for tryptophan modification Specific Amino Acid Modification BioChemical Biochemistry Peptide Synthesis Protection & Derivatization Reagents (for Synthesis) Protective Reagents (Peptide Synthesis) Synthetic Organic Chemistry