ChemicalBook >> CAS DataBase List >>((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
![((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Structure](CAS/GIF/192139-92-7.gif)
- CAS No.
- 192139-92-7
- Chemical Name:
- ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
- Synonyms
- RuCL;TsDPEN;RuCl[(R,R)-Tsdpen](p-cymene);RuCl(p-cymene)[(R,R)-Ts-DPEN];Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II);(R,R)-N-;R)-2-AMINO-1;[(R,R)-Tsdpen](p-cymene);RuCl (cymene)[(R,R)-TsDPEN];CHLORO{[(1R,2R)-(-)-2AMINO-1,2DIPHENY
- CBNumber:
- CB81564668
- Molecular Formula:
- C21H21ClN2O2RuS.C10H14
- Molecular Weight:
- 636.219
- MDL Number:
- MFCD10567385
- MOL File:
- 192139-92-7.mol
Last updated:2023-06-28 13:45:06
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Properties
| Melting point | 215 °C |
|---|---|
| storage temp. | 2-8°C |
| solubility | Deuterated Chloroform, DMF |
| form | solid |
| color | yellow to dark brown |
| optical activity | [α]20/D 116°, c = 0.1 in chloroform |
| Sensitive | air sensitive |
| InChIKey | AZFNGPAYDKGCRB-MNPNNRAMNA-M |
| SMILES | C1=C(S(=O)(=O)N([C@H](C2=CC=CC=C2)[C@H](N)C2=CC=CC=C2)[Ru]Cl)C=CC(C)=C1.C1=CC(C)=CC=C1C(C)C |&1:6,13,r| |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280-P301+P312-P302+P352-P305+P351+P338 | |||||||||
| WGK Germany | 3 | |||||||||
| HS Code | 28439000 | |||||||||
| NFPA 704 |
|
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE price More Price(25)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 930008 | RuCl(p-cymene)[(R,R)-Ts-DPEN] | 192139-92-7 | 250MG | $67.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 930008 | RuCl(p-cymene)[(R,R)-Ts-DPEN] | 192139-92-7 | 1G | $172 | 2024-03-01 | Buy |
| Sigma-Aldrich | 703907 | RuCl(p-cymene)[(R,R)-Ts-DPEN] | 192139-92-7 | 100mg | $28.2 | 2024-03-01 | Buy |
| Sigma-Aldrich | 703907 | RuCl(p-cymene)[(R,R)-Ts-DPEN] | 192139-92-7 | 500mg | $102 | 2024-03-01 | Buy |
| TCI Chemical | R0125 | RuCl[(R,R)-Tsdpen](p-cymene) >90%(HPLC) | 192139-92-7 | 200mg | $49 | 2024-03-01 | Buy |
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Chemical Properties,Uses,Production
Reaction
This catalyst has shown to effect highly enantioselective hydrogenation of functionalized ketones where the substituents are dialkylamino, hydoxy, siloxy, carbonyl, ester, amide or thioester.
Chemical Properties
Orange to brown powder
Uses
Phosphine cationic ruthenium catalysts used for enantioselective hydrogenation of:
- Quinolines
- N-Alkyl ketimines
- Antitumor and antiproliferative derivatives of natural products isolated from bacteria
- Hydroxy arylaldehydes via Rap-Stoermer-enantioselective transfer hydrogenation
Catalyst with improved performance modified via microenvironment engineering of nanocages
General Description
RuCl(p-cymene)[(R,R)-Ts-DPEN] is a chiral diamine ligand complexed with ruthenium.
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 172)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hangzhou ICH Biofarm Co., Ltd | +86-0571-28186870; +undefined8613073685410 | sales@ichemie.com | China | 1001 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29791 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18751 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21634 | 55 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32957 | 60 |
| career henan chemical co | +86-0371-86658258 +8613203830695 | sales@coreychem.com | China | 29880 | 58 |
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10311 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
| Accela ChemBio Inc. | +1-858-6993322 | info@accelachem.com | United States | 17777 | 58 |
| Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22963 | 58 |
View Lastest Price from ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE manufacturers
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|---|---|---|---|---|---|---|---|---|
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2023-11-01 | RuCl[(R,R)-Tsdpen](p-cymene)
192139-92-7
|
US $0.00-0.00 / kg | 1kg | 99.0%min | 800kg | Hangzhou ICH Biofarm Co., Ltd | |
![((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE pictures](/ProductImageEN/2023-06/Small/875fb46a-f8e9-40d4-a70c-5f8ec8ba8139.png) |
2023-11-01 | ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
192139-92-7
|
US $0.00 / kg | 1kg | 98.00% | 200kg | Hangzhou ICH Biofarm Co., Ltd | |
![((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE pictures](https://img.chemicalbook.com/ProductImageEN/2019-7/Small/de366415-65fb-4814-9a6b-dfa9c1eb161c.png) |
2019-07-06 | ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
192139-92-7
|
US $1.00 / KG | 1KG | 99% | 5kg | Career Henan Chemical Co |
-
- RuCl[(R,R)-Tsdpen](p-cymene)
192139-92-7
- US $0.00-0.00 / kg
- 99.0%min
- Hangzhou ICH Biofarm Co., Ltd
-
- ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
192139-92-7
- US $0.00 / kg
- 98.00%
- Hangzhou ICH Biofarm Co., Ltd
-
- ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
192139-92-7
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
192139-92-7(((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE)Related Search:
Dichloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II)
RuCl[(S,S)-FsDPEN](p-cymene)
Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(mesitylene)ruthenium(II), min. 90% RuCl[(S,S)-Tsdpen](mesitylene)
tBuXPhos Pd G1
(S,S)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro)(p-cymene)ruthenium(II)
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHALENECHLORO(P-CYMENE)RUTHENIUM CHLORIDE
((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
(1R,2R)-(-)-N-p-Tosyl-1,2-diphenylethylenediamine
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((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene)
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II), min. 95%
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-
cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene) Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(R,R)-Tsdpen](p-cyMene) ((R,R)-2-aMino-1,2-diphenylethyl0[(4-tolyl)sulfonyl]aMino](p-cyMene)RutheniuM(II)chloride Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II), Min. 95% C31H35ClN2O2RuS Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(R,R)-Tsdpen](p-cyMene) RutheniuM,[N-[(1R,2R)-2-(aMino-kN)-1,2-diphenylethyl]-4-MethylbenzenesulfonaMidato-kN]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-Methylethyl)benzene]- [((R,R)-2-AMino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]aMido](chloro)(η6-p-cyMene)rutheniuM (R,R)-N- ((R,r)-2-amino-1,2-diphenylethy)[(4-tolyl)sulfonyl]amido](pcymene)ruthenium(II)chloride (R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro [(1R,2R)-2-amino-1,2-diphenyl-ethyl]-(p-tolylsulfonyl)azanide ((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p... R)-2-AMINO-1 2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE (1R,2R)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide [N-[(1R,2R)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl- [RuCl(η6-p-cymene)(N-tosyl-1,2-diphenylethylenediamine)] RuCl(p-cymene)[(R,R)-Ts-DPEN] Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) Ruthenium,[N-[(1R,2R)-2-(amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-,98% [(R,R)-Tsdpen](p-cymene) Ruthenium, [N-[(1R,2R)-2-(amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]- [(R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(p-cymene)ruthenium(II) Chloro(p-cymene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II) ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE ISO 9001：2015 REACH RuCl (cymene)[(R,R)-TsDPEN] RuCl(p-cymene)[(R,R)-Ts-DPEN] Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) TsDPEN RuCl[(R,R)-Tsdpen](p-cymene) RuCL [((R,R)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)( p -cymene)ruthenium(II) 192139-92-7 [(1R,2R)-2-amiNA-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide RuCl[(R,R)-Tsdpen](p-cymene)/Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) CHLORO{[(1R,2R)-(-)-2AMINO-1,2DIPHENY 192139-92-7 C31H35ClN2O2RuS Ru organometallic complex
cymene)ruthenium(II), min. 95% RuCl[(R,R)-Tsdpen](p-cymene) Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),95% RuCl[(R,R)-Tsdpen](p-cyMene) ((R,R)-2-aMino-1,2-diphenylethyl0[(4-tolyl)sulfonyl]aMino](p-cyMene)RutheniuM(II)chloride Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II), Min. 95% C31H35ClN2O2RuS Chloro{[(1R,2R)-(-)-2-aMino-1,2-diphenylethyl](4-toluenesulfonyl)aMido}(p-cyMene)rutheniuM(II),RuCl[(R,R)-Tsdpen](p-cyMene) RutheniuM,[N-[(1R,2R)-2-(aMino-kN)-1,2-diphenylethyl]-4-MethylbenzenesulfonaMidato-kN]chloro[(1,2,3,4,5,6-h)-1-Methyl-4-(1-Methylethyl)benzene]- [((R,R)-2-AMino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]aMido](chloro)(η6-p-cyMene)rutheniuM (R,R)-N- ((R,r)-2-amino-1,2-diphenylethy)[(4-tolyl)sulfonyl]amido](pcymene)ruthenium(II)chloride (R,R)-N-(p-Toluenesulfonyl)-1,2-diphenylethanediamine(chloro [(1R,2R)-2-amino-1,2-diphenyl-ethyl]-(p-tolylsulfonyl)azanide ((R,R)-2-amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](p... R)-2-AMINO-1 2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE (1R,2R)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide [N-[(1R,2R)-2-(Amino-KN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-KN]chloro[(1,2,3,4,5,6-η:)-1-methyl- [RuCl(η6-p-cymene)(N-tosyl-1,2-diphenylethylenediamine)] RuCl(p-cymene)[(R,R)-Ts-DPEN] Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) Ruthenium,[N-[(1R,2R)-2-(amino-kN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-kN]chloro[(1,2,3,4,5,6-h)-1-methyl-4-(1-methylethyl)benzene]-,98% [(R,R)-Tsdpen](p-cymene) Ruthenium, [N-[(1R,2R)-2-(amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]- [(R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(p-cymene)ruthenium(II) Chloro(p-cymene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II) ((R,R)-2-AMINO-1,2-DIPHENYLETHYL)[(4-TOLYL)SULFONYL]AMIDO](P-CYMENE)RUTHENIUM(II)CHLORIDE ISO 9001：2015 REACH RuCl (cymene)[(R,R)-TsDPEN] RuCl(p-cymene)[(R,R)-Ts-DPEN] Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) TsDPEN RuCl[(R,R)-Tsdpen](p-cymene) RuCL [((R,R)-2-Amino-1,2-diphenylethyl)[(4-tolyl)sulfonyl]amido](chloro)( p -cymene)ruthenium(II) 192139-92-7 [(1R,2R)-2-amiNA-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide RuCl[(R,R)-Tsdpen](p-cymene)/Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II) CHLORO{[(1R,2R)-(-)-2AMINO-1,2DIPHENY 192139-92-7 C31H35ClN2O2RuS Ru organometallic complex