1-Fluoropyridinium tetrafluoroborate
- CAS No.
- 107264-09-5
- Chemical Name:
- 1-Fluoropyridinium tetrafluoroborate
- Synonyms
- F-PLUS B500 (FP-B500);1-fluoropyridine tetrafluoroborate;N-Fluoropyridinium tetrafluroborate;1-FLUOROPYRIDINIUM TETRAFLUOROBORATE;N-FLUOROPYRIDINIUM TETRAFLUOROBORATE;N-Fluoropyridiniumtetrafluroborate95%;N-Fluoropyridiniumtetrafluroborate97%;1-fluoropyridin-1-iuM tetrafluoroborate;N-Fluoropyridinium tetrafluroborate 97%;1-FLUOROPYRIDINIUM TETRAFLUOROBORATE 97%
- CBNumber:
- CB4696117
- Molecular Formula:
- C5H5BF5N
- Molecular Weight:
- 184.9
- MDL Number:
- MFCD00153176
- MOL File:
- 107264-09-5.mol
- MSDS File:
- SDS
| Melting point | 186-192 °C (lit.) |
|---|---|
| form | Powder |
| color | Off-white |
| Sensitive | Moisture Sensitive |
| BRN | 4281226 |
| CAS DataBase Reference | 107264-09-5(CAS DataBase Reference) |
| UNSPSC Code | 12352100 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|---|---|
| Signal word | Danger |
| Hazard statements | H314 |
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 |
| Hazard Codes | C |
| Risk Statements | 34 |
| Safety Statements | 26-36/37/39-45 |
| RIDADR | UN 3261 8/PG 2 |
| WGK Germany | 3 |
| F | 9-21 |
| Hazard Note | Moisture sensitive/Corrosive |
| HazardClass | 8 |
| PackingGroup | III |
| HS Code | 29333990 |
1-Fluoropyridinium tetrafluoroborate price More Price(11)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 377260 | 1-Fluoropyridinium tetrafluoroborate ≥95% | 107264-09-5 | 1g | $77.3 | 2023-01-07 | Buy |
| TCI Chemical | F0343 | 1-Fluoropyridinium Tetrafluoroborate [Fluorinating Reagent] >95.0%(T) | 107264-09-5 | 5g | $152 | 2021-12-16 | Buy |
| TCI Chemical | F0343 | 1-Fluoropyridinium Tetrafluoroborate [Fluorinating Reagent] >95.0%(T) | 107264-09-5 | 25g | $499 | 2021-12-16 | Buy |
| TRC | F598218 | 1-Fluoropyridinium Tetrafluoroborate [Fluorinating Reagent] | 107264-09-5 | 100mg | $60 | 2021-12-16 | Buy |
| TRC | F598218 | 1-Fluoropyridinium Tetrafluoroborate [Fluorinating Reagent] | 107264-09-5 | 50mg | $45 | 2021-12-16 | Buy |
1-Fluoropyridinium tetrafluoroborate Chemical Properties,Uses,Production
Chemical Properties
off-white powder
Uses
1-Fluoropyridine tetrafluoroborate is a pyridine organic compound, which can be used as an intermediate in pharmaceutical synthesis.
General Description
1-Fluoropyridinium tetrafluoroborate (N-Fluoropyridinium tetrafluoroborate), an N-fluorinated compound, is an electrophilic fluorinating reagent (containing N and F double bond). Controlled potential electrolysis of 1-fluoropyridinium tetrafluoroborate has been reported to afford pyridine, 2-fluoropyridine and 2-acetamidopyridine.
Research
The products from the controlled potential electrolysis of 1-fluoropyridinium tetrafluoroborate were determined to be pyridine, 2-fluoropyridine, and 2-acetamidopyridine in yields. Loss of fluoride ion from the neutral radical in equilibrium with the dimer is believed to be the initial step in a multi-step mechanism, which results in the products observed from the controlled potential coulometry of 1-fluoropyridinium tetrafluoroborate. Catalytic fluorination/chlorination competition experiments of β-keto ester 5 were used to assess the relative fluorinating activity of various electrophilic NF reagents (containing an NF bond). SelectfluorTM ( F-TEDA; TEDA=triethylenediamine) reacts more than 100 times faster than 1-fluoropyridinium tetrafluoroborate[1-2].
References
[1] Edward W Oliver, Dennis H Evans. “Electrochemical studies of six NF electrophilic fluorinating reagents.” Journal of Electroanalytical Chemistry 474 1 (1999): Pages 1-8.
[2] P. Toullec. “Relative Electrophilic Fluorinating Power as Assayed by Competitive Catalytic Halogenation Reactions.” ChemInform 56 1 (2005).
1-Fluoropyridinium tetrafluoroborate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28172 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 49732 | 58 |
| ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23541 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | +86-029-89586680 +86-18192503167 | 1026@dideu.com | China | 7732 | 58 |
| Finetech Industry Limited | +86-27-87465837 +8618971612321 | info@finetechnology-ind.com | China | 9641 | 58 |
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52849 | 58 |
| PT CHEM GROUP LIMITED | +86-85511178; +86-85511178; | peter68@ptchemgroup.com | China | 35425 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49984 | 58 |
| Gansu Lizhong New Material Technology Co.,LTD | 13088788637 19993134645 | 1984863666@qq.com | China | 10 | 58 |
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43340 | 58 |
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View Lastest Price from 1-Fluoropyridinium tetrafluoroborate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-17 | 1-FLUOROPYRIDINIUM TETRAFLUOROBORATE
107264-09-5
|
US $1.10 / g | 1g | 99.0% min | 100 tons min | Shaanxi Dideu Medichem Co. Ltd |
-
- 1-FLUOROPYRIDINIUM TETRAFLUOROBORATE
107264-09-5
- US $1.10 / g
- 99.0% min
- Shaanxi Dideu Medichem Co. Ltd
1-Fluoropyridinium tetrafluoroborate Spectrum
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