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ChemicalBook >> CAS DataBase List >>N,N,N',N'-Tetramethyl-1,4-phenylenediamine

N,N,N',N'-Tetramethyl-1,4-phenylenediamine

CAS No.
100-22-1
Chemical Name:
N,N,N',N'-Tetramethyl-1,4-phenylenediamine
Synonyms
tl85;TL 85;TMPPD;WursterBlue];wurster’sblue;Wurster's blue;Wurster's blue;p-Bis(dimethylamino)benzene;Tetramethyl-p-phenyldiamine;1,4-bis(dimethylamino)-benzen
CBNumber:
CB2300445
Molecular Formula:
C10H16N2
Molecular Weight:
164.25
MDL Number:
MFCD00008309
MOL File:
100-22-1.mol
MSDS File:
SDS
Last updated:2024-12-18 14:07:02

N,N,N',N'-Tetramethyl-1,4-phenylenediamine Properties

Melting point 49-51 °C(lit.)
Boiling point 260 °C(lit.)
Density 0.9743 (rough estimate)
refractive index 1.5700 (estimate)
Flash point >230 °F
storage temp. Store below +30°C.
form powder
pka 5.92±0.12(Predicted)
color off-white to gray
Water Solubility slightly in cold, more in hot water
Sensitive Air & Light Sensitive
Merck 14,9228
BRN 1564025
Stability Stable, but may be air or light sensitive. Combustible. Incompatible with acids, acid chlorides, acid anhydrides, oxidizing agents.
CAS DataBase Reference 100-22-1(CAS DataBase Reference)
FDA UNII P4P3AC32ZB
NIST Chemistry Reference 1,4-Benzenediamine, N,N,N',N'-tetramethyl-(100-22-1)
EPA Substance Registry System

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Signal word  Warning
Hazard statements  H302+H312+H332
Hazard statements  H302+H312+H332
Precautionary statements  P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
Precautionary statements  P280-P301+P312+P330-P302+P352+P312-P304+P340+P312
Hazard Codes  Xn
Risk Statements  20/21/22-40-36/37/38
Safety Statements  28-28A-36-26-22
RIDADR  UN 2811 6.1/PG 3
WGK Germany  1
RTECS  ST4200000
F  10
TSCA  Yes
HazardClass  6.1(a)
PackingGroup  II
HS Code  29215190
Toxicity LD50 oral in bird - wild: 23700ug/kg
NFPA 704
0
2 0

N,N,N',N'-Tetramethyl-1,4-phenylenediamine price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich T7394 N,N,N′,N′-Tetramethyl-p-phenylenediamine 99%, powder 100-22-1 5g $112 2024-03-01 Buy
Sigma-Aldrich T7394 N,N,N′,N′-Tetramethyl-p-phenylenediamine 99%, powder 100-22-1 25g $285 2024-03-01 Buy
Sigma-Aldrich 8.21101 N,N,N′,N′-Tetramethyl-1,4-phenylenediamine for synthesis 100-22-1 5G $76.7 2024-03-01 Buy
Sigma-Aldrich 8.21101 N,N,N′,N′-Tetramethyl-1,4-phenylenediamine for synthesis 100-22-1 25g $254 2024-03-01 Buy
Alfa Aesar L00559 N,N,N',N'-Tetramethyl-p-phenylenediamine, 98+% 100-22-1 10g $61.5 2024-03-01 Buy
Product number Packaging Price Buy
T7394 5g $112 Buy
T7394 25g $285 Buy
8.21101 5G $76.7 Buy
8.21101 25g $254 Buy
L00559 10g $61.5 Buy

N,N,N',N'-Tetramethyl-1,4-phenylenediamine Chemical Properties,Uses,Production

Chemical Properties

purple to brown crystalline powder

Uses

N,N,N',N'-Tetramethyl-p-phenylenediamine is a reducing co-substrate for heme peroxidases. It is used for detection of peroxidases on polyacrylamide gels.

Uses

In the form of the hydrochloride as a reagent in analytical chemistry.

Synthesis Reference(s)

The Journal of Organic Chemistry, 29, p. 488, 1964 DOI: 10.1021/jo01025a506

General Description

Leaflets or a drab green solid.

Air & Water Reactions

N,N,N',N'-Tetramethyl-1,4-phenylenediamine may be sensitive to air and heat. . Insoluble in water.

Reactivity Profile

N,N,N',N'-Tetramethyl-1,4-phenylenediamine can burn in air to give toxic NOx gases . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition N,N,N',N'-Tetramethyl-1,4-phenylenediamine emits toxic fumes. It is an irritant.

Fire Hazard

N,N,N',N'-Tetramethyl-1,4-phenylenediamine is probably combustible.

Safety Profile

Poison by ingestion. Moderatelytoxic by inhalation. Mutation data reported. When heatedto decomposition it emits toxic fumes of NOx.

Purification Methods

Crystallise the amine from pet ether or water. It can be sublimed or dried carefully in a vacuum line, and stored in the dark under nitrogen. It has been recrystallised from its melt. [Beilstein 13 H 74, 13 I 22, 13 II 40, 13 III 111, IV 107.]

N,N,N',N'-Tetramethyl-1,4-phenylenediamine Preparation Products And Raw materials

Global( 146)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21634 55
career henan chemical co 		+86-0371-86658258 +8613203830695 sales@coreychem.com China 29880 58
SHANDONG ZHI SHANG CHEMICAL CO.LTD 		+86 18953170293 sales@sdzschem.com China 2930 58
Chongqing Chemdad Co., Ltd 		+86-023-6139-8061 +86-86-13650506873 sales@chemdad.com China 39894 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 49374 58
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418671 +8618949823763 sales@tnjchem.com China 34563 58
Shanghai UCHEM Inc. 		+862156762820 +86-13564624040 sales@myuchem.com China 7629 58
Baoji Guokang Bio-Technology Co., Ltd. 		0917-3909592 13892490616 gksales1@gk-bio.com China 9312 58
Hefei Hirisun Pharmatech Co., Ltd 		+8615056975894 shawn@hirisunpharm.com CHINA 9911 58
Dayang Chem (Hangzhou) Co.,Ltd. 		571-88938639 +8617705817739 info@dycnchem.com China 52849 58

View Lastest Price from N,N,N',N'-Tetramethyl-1,4-phenylenediamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
N,N,N 2021-07-13 N,N,N",N"-Tetramethyl-1,4-phenylenediamine
100-22-1
 US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
N,N,N 2021-07-09 N,N,N",N"-Tetramethyl-1,4-phenylenediamine
100-22-1
 US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
N,N,N',N'-Tetramethyl-1,4-phenylenediamine pictures 2019-07-06 N,N,N',N'-Tetramethyl-1,4-phenylenediamine
100-22-1
 US $8.80 / KG 1KG 97%-99% 100kg Career Henan Chemical Co
N,N,N',N'-TETRAMETHYL-1,4-PHENYLENEDIAMINE N,N,N',N'-TETRAMETHYL-P-PHENYLENEDIAMINE 1,4-BIS(DIMETHYLAMINO)BENZENE 1,4-bis(dimethylamino)-benzen 4-Benzenediamine,N,N,N’,N’-tetramethyl-1 Benzene, 1,4-bis(dimethylamino)- N,N,N',N'-Tetramethyl-1,4-Benzenediamine N,N,N',N'-Tetramethyl-p-fenylendiamin n,n,n’,n’-tetramethyl-4-benzenediamine N,N,N’,N’-Tetramethyl-benzene-1,4-diamine n,n,n’,n’-tetramethyl-p-fenylendiamin N,N,N’,N’-Tetramethyl-p-phenyl n,n,n’,n’-tetramethyl-p-phenylenediamin p-Bis(dimethylamino)benzene p-Phenylenediamine, N,N,N',N'-tetramethyl- Tetramethyl-p-phenyldiamine Tetramethyl-p-phenylenediamine TL 85 tl85 wurster’sblue Wurster's blue 1,4-Bis(dimethylamino)benzene~Wursters Blue N,N,N,N-tetramethyl-P-*phenylenediamine free ba N,N,N',N'-TETRAMETHYL-P-*PHENYLENEDIAMIN E FREE BASE N,N,N',N'-Tetramethyl-p-phenylenediamine, 98+% 1,4-Benzenediamine, N,N,N,N-tetramethyl- N,N,N?N?Tetramethyl-p-phenylene- diamine, [1,4-Bis(dimethylamino)benzene TETRAMETHYLPARA-PHENYLENEDIAMINE 1,4-BenzenediaMine, N1,N1,N4,N4-tetraMethyl- N,N,N',N'-TetraMethyl-p-phenylenediaMine 99%, powder TMPPD WursterBlue] N,N,N',N'Tetramethyl-p-phenylenediamine≥ 99%(Titration) N,N,N',N'-Tetramethyl-1,4-phenylenediamine for synthesis N,N,N',N'-4METH-P-PHENDIA 2HCL 1-N,1-N,4-N,4-N-tetramethylbenzene-1,4-diamine N1,N1,N4,N4-Tetramethylbenzene-1,4-diamine N,N,N',N'-TETRAMETHYL-1,4-PHENYLENEDIAMI 4-(Dimethylamino)-N,N-dimethylaniline 100-22-1 C10H16N2 N,N,N',N'-Tetramethyl-1,4-phenylenediamine -Amino-2-methyl-123H-tetrazole N,N,N',N'-Tetramethyl-1,4-phenylenediamine N,N,N,N-Tetramethyl-1,4-phenylenediamine , N,N,N′,N′-Tetramethyl-p-phenylenediamine Wurster's blue 100-22-1 22488-01-9 C6H4NCH322 Building Blocks Organic Building Blocks Nitrogen Compounds Polyamines