1,1,1,2,2,3,3,4,4-Nonafluor-4-iodbutan
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- CAS-Nr.
- 423-39-2
- Bezeichnung:
- 1,1,1,2,2,3,3,4,4-Nonafluor-4-iodbutan
- Englisch Name:
- Perfluorobutyl iodide
- Synonyma:
- NONAFLUOROBUTYL IODIDE;NONAFLUORO-1-IODOBUTANE;1,1,1,2,2,3,3,4,4-NONAFLUORO-4-IODOBUTANE;C1014NH3;uorobutyL;Perfluoroiodobutane;PERFLUOROBUTYL IODODE;PERFLUOROBUTYL IODIDE;1-Iodoperfluorobutane;1-IODONONAFLUOROBUTANE
- CBNumber:
- CB9474482
- Summenformel:
- C4F9I
- Molgewicht:
- 345.93
- MOL-Datei:
- 423-39-2.mol
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1,1,1,2,2,3,3,4,4-Nonafluor-4-iodbutan Eigenschaften
- Schmelzpunkt:
- -88 °C
- Siedepunkt:
- 66-67 °C
- Dichte
- 2.01 g/mL at 25 °C(lit.)
- Brechungsindex
- n20/D 1.3285(lit.)
- Flammpunkt:
- None
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- Aggregatzustand
- Liquid
- Wichte
- 2.010
- Farbe
- Clear purple
- Wasserl?slichkeit
- immiscible
- Sensitive
- Light Sensitive
- BRN
- 1777546
- Expositionsgrenzwerte
- ACGIH: TWA 0.01 ppm
- Stabilit?t:
- Stable. Incompatible with bases.
- InChIKey
- PGRFXXCKHGIFSV-UHFFFAOYSA-N
- CAS Datenbank
- 423-39-2(CAS DataBase Reference)
- NIST chemische Informationen
- 1-Iodononafluorobutane(423-39-2)
- EPA chemische Informationen
- Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo- (423-39-2)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher |
Xi |
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R-S?tze: |
36/37/38 |
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S-S?tze: |
26-36-37/39 |
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RIDADR |
2810 |
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WGK Germany |
3 |
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RTECS-Nr. |
EK5360000 |
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F |
8 |
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Hazard Note |
Irritant/Light Sensitive |
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TSCA |
T |
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HazardClass |
6.1(b) |
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PackingGroup |
III |
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HS Code |
29034700 |
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Bildanzeige (GHS) |
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Alarmwort |
Warnung |
Gefahrenhinweise |
Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
H411 |
Giftig für Wasserorganismen, mit langfristiger Wirkung. |
Langfristig (chronisch) gew?ssergef?hrdend |
Kategorie 2 |
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Sicherheit |
P273 |
Freisetzung in die Umwelt vermeiden. |
P391 |
Verschüttete Mengen aufnehmen. |
P501 |
Inhalt/Beh?lter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen. |
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1,1,1,2,2,3,3,4,4-Nonafluor-4-iodbutan Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
Beschreibung
Perfluorobutyl iodide (PFBI) is a promising alternative to chlorofluorocarbon solvents used in aircraft ground maintenance operations and other military and commercial operations because it cleans well, has zero ozone depletion potential, and has extremely low global warming properties. Perfluorobutyl iodides also could used as gain media for a solar-pumped laser amplifier. This compound is usually utilized as perfluoroalkyl radical precursors[1–3].
Chemische Eigenschaften
clear colourless liquid with pungent odour
Verwenden
Perfluorobutyl Iodide is used as an organocatalyst in some polymerization reactions.
Synthese
Add 10 mol of triphenylphosphine chloride and 50 mol of N-methylimidazole hydrochloride to methanol and stir to dissolve. Heat to 50°C, add 65 moles of aluminum chloride, stir and dissolve, continue the reaction for 2 hours, raise the temperature to 80°C, evaporate the solvent, and filter to remove the insoluble matter to obtain quaternary ammonium salt and N-alkyl imidazole salt composite aluminum acid. Salt ionic liquid. Add 2 kg of the aluminate ionic liquid prepared in step S1 to the reaction kettle equipped with a reflux device, then add 264 g of perfluoropentanoic acid and raise the temperature to 80°C. Slowly add 2.5 mol of iodine ethanol solution dropwise within 5 hours. After the dropwise addition is completed, heat to 100°C for 8 hours. The reaction solution was allowed to stand and separated into layers to separate the aluminate ionic liquid and product layers. The product layer was purified by distillation to obtain 336g of Perfluorobutyl iodide.
1,1,1,2,2,3,3,4,4-Nonafluor-4-iodbutan Upstream-Materialien And Downstream Produkte
Upstream-Materialien
1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluor-6-iodhexan
Heptadecafluor-1-iodoctan
Pentafluoriodethan
Downstream Produkte
1,1,1,2,2,3,3,4,4-Nonafluor-4-iodbutan Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 267)Lieferanten
423-39-2(1,1,1,2,2,3,3,4,4-Nonafluor-4-iodbutan)Verwandte Suche:
Kaliumiodid
2-Chlor-2-methylpropan
1,1,1,2,3,3,3-Heptafluor-2-iodpropan
1-Chlorbutan
Trifluoromethyl iodide
1-Chlor-2-methylpropan
2-Brom-2-methylpropan
3,8-Diamino-5-(3-(diethylmethylam-monio)-propyl)-6-phenylphenanthri-diniumdiiodid
1-Brombutan
1,1,1-Trifluoriodethan
1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluor-6-iodhexan
3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluordec-1-en
1,1,1,2,2,3,3,4,4-Nonafluor-6-iodhexan
3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoroctylacrylat
1,1,1,2,2,3,3,4,4,5,5,6,6-Tridecafluor-8-iodoctan
3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluoroctansulfonsure
3,3,4,4,5,5,6,6,6-Nonafluorhexen
Heptadecafluor-1-iodoctan
- PERFLUOROBUTYL IODODE
- Nonafluoro-1-iodobutane,1-Iodoperfluorobutane, Perfluorobutyl iodide
- 1-Iodoperfluorobutane, 1,1,1,2,2,3,3,4,4-Nonafluoro-4-iodobutane
- 1-Iodoperfluorobutane, Perfluorobutyl iodide
- Perfluorobutyl iodide,99%
- PERFLUOROBUTYL IODIDE (STABILISED WITH S
- Nonafluoro-1-iodobutane 98%
- Perfluorobutyl iodide (stabilised with silver platelets) for synthesis
- 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo-butan
- Butane, 1,1,1,2,2,3,3,4,4-nonafluoro-4-iodo-
- m-Nonafluorobutyl iodide
- 1-IODONONAFLUOROBUTANE
- PERFLUOROBUTYL IODIDE
- PERFLUORO-N-BUTYL IODIDE
- N-NONAFLUOROBUTYLIODIDE
- NONAFLUORO-N-BUTYL IODIDE
- 1,1,2,2,3,3,4,4,4-Nonafluoro-1-iodobutane
- NONAFLUORO-1-IODOBUTANE, STAB.
- PERFLUOROBUTYL IODIDE 95%
- 1-Iodoperfluorobutane
- 1-Iodononafluorobutane,97%
- n-Nonafluorobutyliodide,98%
- 1-Iodononafluorobutane 98%
- 1-Iodononafluorobutane98%
- C1014NH3
- uorobutyL
- Nonafluorobutyl Iodide >
- Nonafluoro-1-iodobutane, 99%, for synthesis
- Perfluoroiodobutane
- 1,1,1,2,2,3,3,4,4-NONAFLUORO-4-IODOBUTANE
- NONAFLUOROBUTYL IODIDE
- NONAFLUORO-1-IODOBUTANE
- 423-39-2
- CF3CF23I
- C4F9I
- Organic Building Blocks
- Halogenated Hydrocarbons
- Fluorous Compounds
- Fluorous Chemistry
- Alkyl
- Building Blocks
- Alkyl
- Building Blocks
- Chemical Synthesis
- Fluorinated Building Blocks
- F-Tagged
- Halogenated Hydrocarbons
- Organic Building Blocks
- Organic Fluorinated Building Blocks
- Organic Fluorides
- Fluorous Chemistry
- Fluorous Compounds
- Synthetic Organic Chemistry