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(R)-(+)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE

(R)-(+)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE Struktur
119838-44-7
CAS-Nr.
119838-44-7
Englisch Name:
(R)-(+)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE
Synonyma:
R-BOC-BMI;(R)-(+)-1-(TERT-BUTOXYCARBONYL)-2-T-BUT&;(R)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE;(R)-1-Boc-2-tert-butyl-3-methylimidazolidin-4-one;(R)-(+)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE;(R)-(+)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE 99%;N-(tert-butoxycarbonyl)-2-butyl-3-methyl-4-imidazolidinone;t-Butyl 2-t-Butyl-3-methyl-4-oxo-1-imidazolidinecarboxylate;(R)-1-Boc-2-tert-butyl-3-methyl-4-imidazolidinone≥ 99% (Titration);(R)-(+)-1-(TERT-BUTOXYCARBONYL)-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINE
CBNumber:
CB9166082
Summenformel:
C13H24N2O3
Molgewicht:
256.34
MOL-Datei:
119838-44-7.mol

(R)-(+)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE Eigenschaften

Schmelzpunkt:
68-70 °C(lit.)
Siedepunkt:
399.58°C (rough estimate)
Dichte
1.0600 (rough estimate)
Brechungsindex
1.4365
storage temp. 
Sealed in dry,2-8°C
pka
-0.60±0.40(Predicted)
Aggregatzustand
crystalline solid
Farbe
colorless

Sicherheit

S-S?tze: 22-24/25
WGK Germany  3
F  8-10
HS Code  29332100

(R)-(+)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE Chemische Eigenschaften,Einsatz,Produktion Methoden

S-S?tze Betriebsanweisung:

S22:Staub nicht einatmen.
S24/25:Berührung mit den Augen und der Haut vermeiden.

Chemische Eigenschaften

white crystalline powder

Verwenden

(R)-(+)-1-Boc-2-tert-butyl-3-methyl-4-imidazolidinone is a chiral glycine derivative used for the synthesis of amino acids.

Synthese

The commercial glycine N-methylamide hydrochloride is converted to the racemic imidazolidinone (2) by imine formation with Pivalaldehyde and cyclization under acidic conditions (eq 1). The mandelate salt of like configuration is less soluble and is used for highly efficient resolution; subsequent treatment with Boc anhydride (Di-t-butyl Dicarbonate) gives the enantiomeric Boc-BMI (1) (eq 2).
(R)-( )-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE

(R)-(+)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE Upstream-Materialien And Downstream Produkte

Upstream-Materialien

4-IMidazolidinone, 2-(1,1-diMethylethyl)-3-Methyl- (S)-(-)-1-(TERT-BUTOXYCARBONYL)-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE Di(tert-butyl)carbonat

Downstream Produkte

(R)-(+)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 31)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Alchem Pharmtech,Inc. 		8485655694
sales@alchempharmtech.com United States 63687 58
LEAPCHEM CO., LTD. 		+86-852-30606658
market18@leapchem.com China 43340 58
Suzhou ARTK Medchem Co., Ltd. 		+86-512-68323658 +86-18168183658
 sales1@artkmedchem.com China 39004 58
Amadis Chemical Company Limited 		571-89925085
sales@amadischem.com China 131957 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788
 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 021-61259108 18621169109
 market03@meryer.com China 40228 62
Chemsky（shanghai）International Co.,Ltd. 021-50135380
shchemsky@sina.com China 32321 50
Daicel Chiral Technologies (China)CO.,LTD 021-50460086-9 15921403865
 han_yajun@dctc.daicel.com China 7195 65
Tianjin Derchemist Science & Technology Co., Ltd. 22-58627059 13920586291
 zdcomcon@126.com China 3461 50
Thermo Fisher Scientific 800-810-5118
cnchemical@thermofisher.com China 17770 75
  • (R)-(+)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE
  • (R)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE
  • (R)-(+)-1-(TERT-BUTOXYCARBONYL)-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINE
  • (R)-(+)-1-(TERT-BUTOXYCARBONYL)-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE
  • R-BOC-BMI
  • (R)-(+)-1-(TERT-BUTOXYCARBONYL)-2-T-BUT&
  • (R)-(+)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE 99%
  • (R)-(+)-1-(TERT-BUTOXYCARBONYL)-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE 99%
  • N-(tert-butoxycarbonyl)-2-butyl-3-methyl-4-imidazolidinone
  • (R)-(+)-1-(tert-Butoxycarbonyl)-2-tert-butyl-3-methyl-4-imidazolidinone,99%
  • (R)-1-BOC-2-(TERT-BUTYL)-3-METHYL-4-IMIDAZOLIDINONE;(R)-(+)-1-BOC-2-TERT-BUTYL-3-METHYL-4-IMIDAZOLIDINONE
  • (R)-tert-Butyl 2-(tert-butyl)-3-Methyl-4-oxoiMidazolidine-1-carboxylate
  • t-Butyl 2-t-Butyl-3-methyl-4-oxo-1-imidazolidinecarboxylate
  • (R)-1-Boc-2-tert-butyl-3-methylimidazolidin-4-one
  • (R)-1-Boc-2-tert-butyl-3-methyl-4-imidazolidinone≥ 99% (Titration)
  • (2R)-2-tert-butyl-3-methyl-4-oxo-1-imidazolidinecarboxylic acid tert-butyl ester
  • 1-Imidazolidinecarboxylic acid, 2-(1,1-dimethylethyl)-3-methyl-4-oxo-, 1,1-dimethylethyl ester, (2R)-
  • Tert-butyl (R)-2-(tert-butyl)-3-methyl-4-oxoimidazolidine-1-carboxylate
  • 119838-44-7
  • Precursors for Amino Acid Synthesis
  • Peptide Synthesis
  • Specialty Synthesis
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