Triethyl 2-fluoro-2-phosphonoacetate
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- CAS-Nr.
- 2356-16-3
- Englisch Name:
- Triethyl 2-fluoro-2-phosphonoacetate
- Synonyma:
- ethyl 2-(diethoxyphosphoryl)-2-fluoroacetate;czj;uoro-2-phosphonoacetate;Triethyl-2-Fluoro-2-Phosphono;triethylphosphonofluoroacetate;Triethyl2-Fluoro-2-phosphoacetate;RIETHYL2-FLUORO-2-PHOSPHONOACETATE;Triethyl-2-fluoro-phosphonoacetate;Triethyl α-fluoro(phosphono)acetate;Ethyl diethylphosphonofluoroacetate
- CBNumber:
- CB9119497
- Summenformel:
- C8H16FO5P
- Molgewicht:
- 242.18
- MOL-Datei:
- 2356-16-3.mol
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Triethyl 2-fluoro-2-phosphonoacetate Eigenschaften
- Siedepunkt:
- 75 °C0.01 mm Hg(lit.)
- Dichte
- 1.194 g/mL at 25 °C(lit.)
- Brechungsindex
- n20/D 1.425(lit.)
- Flammpunkt:
- 165 °F
- storage temp.
- Keep in dark place,Inert atmosphere,Room temperature
- Aggregatzustand
- clear liquid
- Farbe
- Colorless to Almost colorless
- Wichte
- 1.194
- BRN
- 1912161
- CAS Datenbank
- 2356-16-3(CAS DataBase Reference)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Kennzeichnung gef?hrlicher |
Xi,F |
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| R-S?tze: |
36/37/38 |
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| S-S?tze: |
26-36-37/39 |
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| WGK Germany |
3 |
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| F |
10-21 |
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| Hazard Note |
Irritant |
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| HazardClass |
IRRITANT, FLAMMABLE |
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| HS Code |
29319090 |
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| Bildanzeige (GHS) |
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| Alarmwort |
Warnung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H227 |
Combustible liquid |
Flammable liquids |
Category 4 |
Warnung |
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P210, P280, P370+P378, P403+P235,P501 |
| H315 |
Verursacht Hautreizungen. |
Hautreizung |
Kategorie 2 |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P302+P352, P321,P332+P313, P362 |
| H319 |
Verursacht schwere Augenreizung. |
Schwere Augenreizung |
Kategorie 2 |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
P264, P280, P305+P351+P338,P337+P313P |
| H335 |
Kann die Atemwege reizen. |
Spezifische Zielorgan-Toxizit?t (einmalige Exposition) |
Kategorie 3 (Atemwegsreizung) |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
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| Sicherheit |
| P261 |
Einatmen von Staub vermeiden. |
| P305+P351+P338 |
BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen. |
| P405 |
Unter Verschluss aufbewahren. |
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Triethyl 2-fluoro-2-phosphonoacetate Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.
S-S?tze Betriebsanweisung:
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S37/39:Bei der Arbeit geeignete Schutzhandschuhe und Schutzbrille/Gesichtsschutz tragen.
Chemische Eigenschaften
clear colorless liquid
Verwenden
Reactant for:
- Diels-Alder reactions
- Biosynthesis of terpene
- Stereoselective synthesis of unsaturated esters, fluorides and nitriles from the reactions of aldehydes and ketones using Wadsworth-Emmons phosphonates
- Synthesis of quinolones
- Horner-Wadsworth-Emmons asymmetric hydration
- Addition reactions and the subsequent application to click chemistry
- Asymmetric intermolecular Stetter reactions
Synthesis Reference(s)
The Journal of Organic Chemistry, 60, p. 4730, 1995
DOI: 10.1021/jo00120a014
Triethyl 2-fluoro-2-phosphonoacetate Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
Triethyl 2-fluoro-2-phosphonoacetate Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 231)Lieferanten
2356-16-3()Verwandte Suche:
- 2-FLUORO-2-PHOSPHONOACETIC ACID TRIETHYL ESTER 95+%
- RIETHYL2-FLUORO-2-PHOSPHONOACETATE
- 2-Fluoro-2-(diethoxyphosphinyl)acetic acid ethyl ester
- Fluoro(diethoxyphosphinyl)acetic acid ethyl ester
- Diethyl [(ethoxycarbonyl)fluoromethyl]phosphonate 96%
- Ethyl (diethoxyphosphonyl)(fluoro)acetate, 2-Fluoro-2-phosphonoacetic acid triethyl ester
- (Diethoxyphosphinyl)fluoroacetic Acid Ethyl Ester
Ethyl (Diethoxyphosphinyl)fluoroacetate
2-Fluoro-2-phosphonoacetic Acid Triethyl Ester
- Triethyl α-fluoro(phosphono)acetate
- Ethyl (diethoxyphosphoryl)(fluoro)acetate, Ethyl (diethylphosphono)(fluoro)acetate
- 2-Fluoro-2-phosphonoacetic acid triethyl ester 96%
- 2-Fluoro-2-phosphonoaceticacidtriethylester97%
- Triethyl-2-fluoro-phosphonoacetate
- 2-Phosphono-2-fluoroacetic acid triethyl ester
- ETHYL (DIETHOXYPHOSPHORYL)(FLUORO)ACETATE
- Diethyl [(ethoxycarbonyl)fluoromethyl]phosphonate
- Ethyl diethylphosphonofluoroacetate
- Triethyl 2-fluoro-2-phosphonoacetate 96%
- (R,S)-(Diethoxy-phosphoryl)-fluoro-aceticacidethylester
- triethylphosphonofluoroacetate
- TRIETHYL 2-FLUORO-2-PHOSPHONOACETATE
- 2-FLUORO-2-PHOSPHONOACETIC ACID TRIETHYL ESTER
- ETHYL (DIETHOXYPHOSPHINYL)FLUOROACETATE
- (DIETHOXYPHOSPHINYL)FLUOROACETIC ACID ETHYL ESTER
- TRIETHYL 2-FLUORO-2-PHOSPHONOACETATE, 96 %
- 2-Fluoro-2-phosphonoaceticacidtriethylester(FluorinatedHornerreagent)
- Triethyl2-Fluoro-2-phosphoacetate
- Triethyl-2-Fluoro-2-Phosphono
- 2-diethoxyphosphoryl-2-fluorobutanoate
- Triethyl2-Fluoro-2-phosphonoacetate>
- uoro-2-phosphonoacetate
- czj
- Acetic acid, 2-(diethoxyphosphinyl)-2-fluoro-, ethyl ester
- ethyl 2-(diethoxyphosphoryl)-2-fluoroacetate
- 2-(diethoxyphosphinyl)-2-fluoro-Acetic acid ethyl ester
- 2356-16-3
- 236-16-3
- C2H5O2POCHFCO2C2H5
- C2H5O2POCHFCO2
- C8H16FO5P
- Horner-Wadsworth-Emmons Reagents
- Synthetic Reagents
- Olefination
- C-C Bond Formation
- Fluorinated Building Blocks
- Wittig & Horner-Emmons Reaction
- Horner-Emmons Reaction
- Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds
- Phosphorus compounds
- Fluorinated Building Blocks
- Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds
- Horner-Emmons Reaction
- Synthetic Organic Chemistry
- Wittig & Horner-Emmons Reaction
- C-C Bond Formation
- Horner-Wadsworth-Emmons Reagents
- Olefination
