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Aldoxycarb

ALDICARB-SULFONE Struktur
1646-88-4
CAS-Nr.
1646-88-4
Bezeichnung:
Aldoxycarb
Englisch Name:
ALDICARB-SULFONE
Synonyma:
ALDOXYCARB;UCES;ent4.9;Standak;STANDOK;UC21865;Sulfocarb;STANDAK(R);aldoxycarbe;YangdiMiewei
CBNumber:
CB7710151
Summenformel:
C7H14N2O4S
Molgewicht:
222.26
MOL-Datei:
1646-88-4.mol

Aldoxycarb Eigenschaften

Schmelzpunkt:
132-135 °C
Dichte
1.3816 (rough estimate)
Dampfdruck
1.2×10-2 Pa (25 °C)
Brechungsindex
1.5690 (estimate)
storage temp. 
0-6°C
L?slichkeit
DMSO (Slightly), Methanol (Slightly)
Wasserl?slichkeit
10 g l-1 (25 °C)
pka
13.44±0.46(Predicted)
Aggregatzustand
Solid
Farbe
White to Off-White
BRN 
2215242
EPA chemische Informationen
Aldicarb sulfone (1646-88-4)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher T+
R-S?tze: 24-26/28
S-S?tze: 28-36/37-45
RIDADR  2757
WGK Germany  3
RTECS-Nr. UE2080000
HazardClass  6.1(a)
PackingGroup  I
Toxizit?t duck,LD50,oral,33500ug/kg (33.5mg/kg),Pesticide Manual. Vol. 9, Pg. 18, 1991.
Bildanzeige (GHS) GHS hazard pictogramsGHS hazard pictograms
Alarmwort Achtung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H400 Sehr giftig für Wasserorganismen. Kurzfristig (akut) gew?ssergef?hrdend Kategorie 1 Warnung GHS hazard pictogramssrc="/GHS09.jpg" width="20" height="20" /> P273, P391, P501
Sicherheit
P260 Dampf/Aerosol/Nebel nicht einatmen.
P262 Nicht in die Augen, auf die Haut oder auf die Kleidung gelangen lassen.
P273 Freisetzung in die Umwelt vermeiden.
P280 Schutzhandschuhe/Schutzkleidung/Augenschutz tragen.

Aldoxycarb Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R24:Giftig bei Berührung mit der Haut.
R26/28:Sehr giftig beim Einatmen und Verschlucken.

S-S?tze Betriebsanweisung:

S28:Bei Berührung mit der Haut sofort abwaschen mit viel . . . (vom Hersteller anzugeben).
S36/37:Bei der Arbeit geeignete Schutzhandschuhe und Schutzkleidung tragen.
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).

Beschreibung

Aldoxycarb, is also called 2-mesyl-2-methylpropionaldehyde O-methylcarbamoyloxime (IUPAC), the sulfone analog of aldicarb, is also a systemic insecticide effective for control of insects (mainly sucking insect pests such as aphids, leafhoppers, etc.).

Chemische Eigenschaften

Aldoxycarb is a carbamate pesticide used mainly as an insecticide and acaricide. It is a white crystalline powder with a slightly sulfurous odor. Aldoxycarb is extremely toxic to wildlife. Aldoxycarb (Aldicarb sulfone) is a breakdown product of aldicarb. Aldoxycarb is a degradate/metabolite of aldicarb produced by the oxidation of the thio-moiety.

Verwenden

Aldicarb Sulfone is an analog of Aldicarb (A514650) detected in agricultural products as pesticide residue.

Allgemeine Beschreibung

White crystalline solid. Insecticide.

Reaktivit?t anzeigen

ALDICARB-SULFONE is a carbamate ester. Carbamates are chemically similar to, but more reactive than amides. Like amides they form polymers such as polyurethane resins. Carbamates are incompatible with strong acids and bases, and especially incompatible with strong reducing agents such as hydrides. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidizing acids, peroxides, and hydroperoxides are incompatible with carbamates.

Health Hazard

Exposures to high levels of aldoxycarb cause adverse health effects and damages the nervous system of humans and laboratory animals. Chemicals that cause adverse health effects in humans and laboratory animals after high levels of exposure may pose a risk of adverse health effects in humans exposed to lower levels over long periods of time. Ingestion and other exposures to the chemical cause various health disorders. The type and severity of symptoms varies depending on the amount of chemical involved and the nature of the exposure. The symptoms include, but are not limited to, eye irritation, skin irritation, dizziness, sweating, malaise, CNS depression, abdominal pain, diarrhea, nausea, vomiting, salivation, headache, ataxia, muscle twitching, muscle weakness, runny nose, tearing eyes, pinpoint pupils or dark vision, wheezing, increased or decreased heart rate, seizures, convulsions, and death. It has not caused any delayed neurotoxicity in animals. The onset of these symptoms is rapid and the severity of symptoms depends on the dose. The immediate cause of death is usually respiratory failure.

Landwirtschaftliche Anwendung

Insecticide, Acaricide, Nematicide: Used to control honey locust, gall midge and other insects and mites on cotton, potatoes, sugar beets and ornamentals. Applied to the soil by soluble mixture or spikes. Not listed for use in EU countries.

Handelsname

ALDICARB SULFONE®; TEMIK SULFONE®; SULFOCARB®; STANDAK®; UC-21865®

Stoffwechselwegen

Aldoxycarb is the sulfone analogue of aldicarb. It has now been superseded but, because of its close relationship with aldicarb, it is included here. The degradation and metabolic pathway of these two structurally related compounds are consistent with each other. Information on the metabolism of aldoxycarb discussed in this summary is based on results obtained from studies where aldoxycarb was the test substance. Additional information can be obtained from the aldicarb summary. The metabolism of aldoxycarb in soils, plants and animals follow common metabolic pathways which include the hydrolysis and elimination of the oxime carbamate to yield the corresponding oximes and nitriles. These primary metabolites are further degraded via hydrolysis to the corresponding amides and acids. Other reactions also include the hydrolysis/ oxidation of the oxime to the corresponding alcohol, aldehyde and acid. Further degradation to methane sulfonic acid was observed in plants and animals. The metabolic pathways of aldoxycarb are presented in Scheme 1.

Aldoxycarb Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Aldoxycarb Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 94)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hubei Jusheng Technology Co.,Ltd.
18871490254
linda@hubeijusheng.com CHINA 28172 58
Alchem Pharmtech,Inc.
8485655694
sales@alchempharmtech.com United States 63687 58
career henan chemical co
+86-0371-86658258 +8613203830695
factory@coreychem.com China 29811 58
TargetMol Chemicals Inc.
+1-781-999-5354 +1-00000000000
marketing@targetmol.com United States 32161 58
HANGZHOU CLAP TECHNOLOGY CO.,LTD
86-571-88216897,88216896 13588875226
sales@hzclap.com CHINA 6312 58
AFINE CHEMICALS LIMITED
+86-0571-85134551
sales@afinechem.com China 15352 58
Shaanxi Didu New Materials Co. Ltd
+86-89586680 +86-13289823923
1026@dideu.com China 8670 58
TargetMol Chemicals Inc.

support@targetmol.com United States 38631 58
SUZHOU SENFEIDA CHEMICAL CO.,LTD
+86-0512-83500002 +8615195660023
sales@senfeida.com China 23046 58
Shanghai Acmec Biochemical Technology Co., Ltd.
+undefined18621343501
product@acmec-e.com China 33338 58

1646-88-4(Aldoxycarb)Verwandte Suche:


  • ALDICARB-SULFONE PESTANAL
  • ENDOSULFAN LACTONE PESTANAL, 100 MG
  • (1E)-2-Methyl-1-(([(methylamino)carbonyl]oxy)imino)-2-(methylsulfonyl)propane
  • 2-mesyl-2-methylpropionaldehydeo-methylcarbamoyloxime
  • ALDOXYCARB, 10MG, NEAT
  • Aldicarb sulfone 10mg [1646-88-4]
  • Aldoxycarb 10mg [1646-88-4]
  • UCES
  • YangdiMiewei
  • Propanal,2-methyl-w-(methyl-sulfonyl)-O-[(methylamino)carbonyl]oxime
  • AldicarbSulrone
  • 2-methyl-2-(methylsulfonyl)-propionaldehydo-(methylcarbamoyl)oxime
  • aldoxycarbe
  • Carbamic acid, methyl-, O-[[2-methyl-2-(methylsulfonyl)propylidene]amino] deriv.
  • ent4.9
  • entai3-29261
  • Propanal, 2-methyl-2-(methylsulfonyl)-, O-[(methylamino)carbonyl]oxime
  • Propionaldehyde, 2-methyl-2-(methylsulfonyl)-, O-(methylcarbamoyl)oxime
  • Standak
  • Sulfocarb
  • Temik sulfone
  • 2-METHYL-2-(METHYLSULFONYL)PROPANAL-O-[(METHYLAMINO)CARBONYL]OXIME
  • 2-METHYL-2-(METHYLSULFONYL)-PROPIONALDEHYDE O-(METHYLCARBAMOYL)-OXIME
  • ALDICARB-SULFONE
  • ALDICARB SULPHONE
  • STANDOK
  • STANDAK(R)
  • UC21865
  • 2-methyl-2-(methylsulphonyl)propionaldehyde O-(methylcarbamoyl)oxime
  • ALDICARB SULFONE(TEMIK SULFONE)
  • AldicarbSulfoneSolution,2000mg/L,1ml
  • AldicarbSulfoneSolution,10mg/L,1ml
  • AldicarbSulfoneSolution,100mg/L,1ml
  • Aldicarb sulfone Solution in Acetonitrile, 1000μg/mL
  • Aldicarb sulfone Solution in Methanol, 100μg/mL
  • Aldicarb sulfone Solution in Methanol, 1000μg/mL
  • ALDOXYCARB
  • Aldicarb sulfone,Cholinesterase (ChE),inhibit,Inhibitor
  • Aldicarb-sulfone in Acetone
  • Aldicarb-sulfone in Methanol
  • C10080000 Aldicarb-sulfone
  • 1646-88-4
  • A
  • AA to ALPesticides
  • A-BAlphabetic
  • Alpha sort
  • CarbamatesEnvironmental Standards
  • Insecticides
  • MetabolitesPesticides&Metabolites
  • Nematicides
  • Pesticides
  • Pesticides&Metabolites
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