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Diethyl-[S-(R*,R*)]-tartrat

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Struktur
13811-71-7
CAS-Nr.
13811-71-7
Bezeichnung:
Diethyl-[S-(R*,R*)]-tartrat
Englisch Name:
(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
Synonyma:
DET;D-DET;D-tartrate;DIETHYL D-TARTRATE;(-)-Diethyl D-tartrate;D(-)diethyl tartarate;(2R,3R)-diethyl 2,3-dihydroxysuccinate;ETHYL TARTRATE;diethyl (2S,3S)-2,3-dihydroxybutanedioate;(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl
CBNumber:
CB7105982
Summenformel:
C8H14O6
Molgewicht:
206.19
MOL-Datei:
13811-71-7.mol

Diethyl-[S-(R*,R*)]-tartrat Eigenschaften

Schmelzpunkt:
17 °C
Siedepunkt:
162 °C/19 mmHg (lit.)
alpha 
-9 º (neat)
Dichte
1.205 g/mL at 20 °C (lit.)
Brechungsindex
n20/D 1.446(lit.)
Flammpunkt:
200 °F
storage temp. 
Store below +30°C.
L?slichkeit
Chloroform (Slightly), Water (Slightly)
pka
11.61±0.20(Predicted)
Aggregatzustand
Viscous Liquid
Farbe
Clear colorless
Wichte
1.21
Optische Aktivit?t
[α]23/D 8.5°, neat
Wasserl?slichkeit
insoluble
Merck 
14,3855
BRN 
1727143
CAS Datenbank
13811-71-7(CAS DataBase Reference)
NIST chemische Informationen
Butanedioic acid, 2,3-dihydroxy-, diethyl ester, [S-(R*,R*)]-(13811-71-7)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
Kennzeichnung gef?hrlicher Xi
R-S?tze: 36/37/38
S-S?tze: 24/25-36-26
WGK Germany  3
Hazard Note  Irritant
HS Code  29181300
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H227 Combustible liquid Flammable liquids Category 4 Warnung P210, P280, P370+P378, P403+P235,P501
Sicherheit
P403+P235 An einem gut belüfteten Ort aufbewahren. Kühl halten.

Diethyl-[S-(R*,R*)]-tartrat Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R36/37/38:Reizt die Augen, die Atmungsorgane und die Haut.

S-S?tze Betriebsanweisung:

S24/25:Berührung mit den Augen und der Haut vermeiden.
S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.
S26:Bei Berührung mit den Augen sofort gründlich mit Wasser abspülen und Arzt konsultieren.

Chemische Eigenschaften

Colorless to light yellow liqui

Verwenden

Diethyl D(-)-tartrate is mainly used in chiral pharmaceuticals, chiral intermediates and chiral catalysts. It can be used with titanium in enolic asymmetric epoxidization. The compound d-alpha-tocopherol is the principal compound present in natural vitamin E sources. At present, d-alpha-tocopherol and other tocopherol derivatives are used in pharmaceuticals, foods and animal feeds. It is used as a food additive.

l?uterung methode

Distil the esters under high vacuum and store them under vacuum or in an inert atmosphere in a desiccator in round bottomed flasks equiped with a vacuum stopcock. They have also been distilled by Kügelrohr distillation and/or by 'wiped-film' molecular distillation. They are slightly soluble in H2O but miscible with EtOH and Et2O. [Gao et al. J Am Chem Soc 109 5770 (5771) 1987, IR: Pristera Anal Chem 25 844 1953, Beilstein 3 III 1025 for D-(-), 3 IV 1232 for L(+).]

Diethyl-[S-(R*,R*)]-tartrat Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


Diethyl-[S-(R*,R*)]-tartrat Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 574)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
Hebei Weibang Biotechnology Co., Ltd
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Hebei Mojin Biotechnology Co., Ltd
+86 13288715578 +8613288715578
sales@hbmojin.com China 12835 58
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+8617531190177
peter@yan-xi.com China 5857 58
Hebei Chuanghai Biotechnology Co,.LTD
+86-13131129325
sales1@chuanghaibio.com China 5889 58
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+8617732866630
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+86-0533-2185556 +8617865335152
Mandy@hangyubiotech.com China 10986 58
airuikechemical co., ltd.
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sales02@sdzhonghuimaterial.com China 983 58
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+8613343047651
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Capot Chemical Co.,Ltd.
+86-(0)57185586718 +86-13336195806
sales@capot.com China 29791 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512
info@tianfuchem.com China 21634 55

13811-71-7(Diethyl-[S-(R*,R*)]-tartrat)Verwandte Suche:


  • (-)-Diethyl D-tartrate, Made froM unnatural tartaric acid, 99% 25ML
  • (R,R)-(+)-Weinsaeure-diethylester
  • (-)-Diethyl (2S,3S)-2,3-dihydroxybutane-1,4-dioate, (-)-Diethyl (2S,3S)-2,3-dihydroxysuccinate
  • D-(-)-TARTARIC ACID DIETHYL ESTER
  • (2S,3S)-(-)-DIETHYL TARTRATE
  • (2S,3S)(-)-DIHYDROXYBUTANE-1,4-DIOIC ACID DIETHYL ESTER
  • diethyl [S-(R*,R*)]-tartrate
  • MINUS-TARTARIC ACID DIETHYL ESTER
  • DIETHYL D-TARTRATE, 99+%
  • D (-)Diethy tartrate
  • (-)-Diethyl D-tartrate, made from unnatural tartaric acid, 99%
  • Butanedioic acid, 2,3-dihydroxy-, diethyl ester, S-(R*,R*)-
  • Diethyl-L-(+)-Tartarte
  • D-(-)-WEINSURE-DIETHYLESTER
  • (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Diethyl D-
  • tartrate D-Tartaric acid diethyl ester
  • D-ethyl tartrate
  • Diethyl-D(-)-Tartrate99.0%Min
  • (-)-Diethyl d-tartrate, 99%, made from unnatural tartaric acid
  • (2S,3S)-2,3-Dihydroxysuccinic acid diethyl ester
  • Diethyl dextro-tartrate
  • (2S,3S)(-)-Dihydroxy
  • EsoMeprazo interMediate C
  • D- two ethyl acetate
  • Dihydroxybutane-1,4-dioic acid diethyl ester
  • D-Tartaric Acid Diethyl Ester,99%e.e.
  • (2S,3S)-(-)-Diethyl tartrate for synthesis
  • dlethyl-tartrate
  • (-)-DIETHYL-2,3-DIHYDROXYSUCCINATE
  • (-)-DIETHYL-D-TARTRATE
  • DIETHYL D-(-)-TARTRATE
  • [-]-TARTARIC ACID DIETHYL ESTER
  • D(-)-DIETHYL TARTRATE
  • D-(-)-Diethyl L-tartrate
  • (-)-Diethyl D-tartrate >=99%
  • Diethyl Tartrate D(-)
  • (-)-Diethyl (2S,3S)-2,3-dihydroxybutane-1,4-dioate,
  • (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester 13811-71-7
  • 3S)(-)-Dihydroxybutane-1
  • 4-dioic acid diethyl ester
  • diethyl laevo-tartrate
  • DI-ETHYL-D-TARTRATE (Pure) 13811-71-7
  • Diethyl-D-Tartarate (13811-71-7)
  • (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester in stock Factory
  • Butanedioic acid, 2,3-dihydroxy-, 1,4-diethyl ester, (2S,3S)-
  • D-tartrate
  • (2R,3R)-diethyl 2,3-dihydroxysuccinate
  • (-)-Diethyl D-tartrate
  • (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl
  • D(-)diethyl tartarate
  • ETHYL TARTRATE
  • DIETHYL D-TARTRATE
  • DET
  • D-DET
  • diethyl (2S,3S)-2,3-dihydroxybutanedioate
  • (-)-Diethyl tartrate
  • D-(-)-Tartaric Acid Diethyl Ester Diethyl-D-tartrate
  • ( - ) Di Ethyl D Tartrate
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