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1-Octadecanol

1-Octadecanol Struktur
112-92-5
CAS-Nr.
112-92-5
Englisch Name:
1-Octadecanol
Synonyma:
STEARYL ALCOHOL;Ceteareth-20;OCTADECANOL;Octadecan-1-ol;Stenol;stearyl;STEARYLIC ALCOHOL;Stearol;n-Octadecanol;OCTADECYL ALCOHOL
CBNumber:
CB4852872
Summenformel:
C18H38O
Molgewicht:
270.49
MOL-Datei:
112-92-5.mol

1-Octadecanol Eigenschaften

Schmelzpunkt:
56-59 °C (lit.)
Siedepunkt:
210 °C15 mm Hg
Dichte
0.812 g/mL at 25 °C (lit.)
Dampfdichte
9.3 (vs air)
Dampfdruck
<0.01 mm Hg ( 38 °C)
Brechungsindex
1.4356 (estimate)
Flammpunkt:
185°C
storage temp. 
2-8°C
L?slichkeit
methanol: soluble10mg/mL, clear, colorless
Aggregatzustand
Flakes
pka
15.20±0.10(Predicted)
Wichte
0.812
Farbe
White
Geruch (Odor)
wh. unctuous flakes or gran., faint odor, bland taste
Explosionsgrenze
~8%
Wasserl?slichkeit
insoluble
Merck 
14,8805
BRN 
1362907
Dielectric constant
3.4(58℃)
LogP
7.4
CAS Datenbank
112-92-5(CAS DataBase Reference)
NIST chemische Informationen
1-Octadecanol(112-92-5)
EPA chemische Informationen
1-Octadecanol (112-92-5)
Sicherheit
  • Risiko- und Sicherheitserkl?rung
  • Gefahreninformationscode (GHS)
S-S?tze: 24/25
RIDADR  UN 1986
WGK Germany  -
RTECS-Nr. RG2010000
Selbstentzündungstemperatur 842 °F
TSCA  Yes
HS Code  29051700
Giftige Stoffe Daten 112-92-5(Hazardous Substances Data)
Toxizit?t LD50 orally in Rabbit: > 2000 mg/kg
Bildanzeige (GHS) GHS hazard pictograms
Alarmwort Warnung
Gefahrenhinweise
Code Gefahrenhinweise Gefahrenklasse Abteilung Alarmwort Symbol P-Code
H315 Verursacht Hautreizungen. Hautreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P302+P352, P321,P332+P313, P362
H319 Verursacht schwere Augenreizung. Schwere Augenreizung Kategorie 2 Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" /> P264, P280, P305+P351+P338,P337+P313P
H335 Kann die Atemwege reizen. Spezifische Zielorgan-Toxizit?t (einmalige Exposition) Kategorie 3 (Atemwegsreizung) Warnung GHS hazard pictogramssrc="/GHS07.jpg" width="20" height="20" />
Sicherheit
P261 Einatmen von Staub vermeiden.
P305+P351+P338 BEI KONTAKT MIT DEN AUGEN: Einige Minuten lang behutsam mit Wasser spülen. Eventuell vorhandene Kontaktlinsen nach M?glichkeit entfernen. Weiter spülen.

1-Octadecanol Chemische Eigenschaften,Einsatz,Produktion Methoden

ERSCHEINUNGSBILD

FARBLOSE BIS WEISSE, LEICHT WACHSARTIGE FLOCKEN ODER BL?TTCHEN.

CHEMISCHE GEFAHREN

Reagiert mit starken S?uren und starken Oxidationsmitteln.

ARBEITSPLATZGRENZWERTE

TLV nicht festgelegt (ACGIH 2005).
MAK: IIb (nicht festgelegt, aber Informationen vorhanden); (DFG 2005).

LECKAGE

Verschüttetes Material in Beh?ltern sammeln. Reste sorgf?ltig sammeln. An sicheren Ort bringen.

S-S?tze Betriebsanweisung:

S24/25:Berührung mit den Augen und der Haut vermeiden.

Chemische Eigenschaften

Stearyl alcohol, or 1-octadecanol, is an organic compound classified as a saturated fatty alcohol with the formula CH3(CH2)16CH2OH. It occurs as hard, white, waxy pieces, flakes, or granules, which have a slight characteristic odor and a bland taste. It is soluble in alcohol, acetone, and ether, but insoluble in water. Furthermore, it is combustible.

Verwenden

1-Octadecanol is used as a surfactant in cosmetics. It effectively moisturizes hands and face with pheohydrane, which is a complex derived from the microalgae Chlorella Vulgaris and hydrolyzed algin found in sea water. It is a saturated alcohol of high purity and can substitute for cetyl alcohol in pharmaceutical dispensing, in cosmetic creams, for emulsions, textile oils and finishes, as antifoam agent, lubricant, viscosity agent, builder, and chemical raw material.

synthetische

1-Octadecanol is prepared commercially via Ziegler aluminum alkyl hydrolysis or the catalytic, high-pressure hydrogenation of stearyl acid, followed by filtration and distillation. It may also be derived from natural fats and oils.

Application

1-Octadecanol is a long chain primary alcohol that is used in the production of emulsions, textile oils, antifoam agents, and lubricants. Other large scale applications include the manufacture of alkyl amines, tertiary amines, ethoxylates, halides/mercaptans, and polymerization stabilizers. It generally occurs as a mixture of solid alcohols whose primary constituent is 1-octadecanol. It occurs naturally in sperm whale oil and has been isolated from the hyperthermophilic bacterium Pyrococcus furiosus.
1-Octadecanol has been used to model the plant epicuticular wax layer for an investigation by differential scanning calorimetry and Fourier transform infrared spectroscopy.
The use of 1-octadecanol to prepare microsphere formulations for such compounds as paclitaxel and indomethacin has been described.

Vorbereitung Methode

Historically, stearyl alcohol was prepared from sperm whale oil but is now largely prepared synthetically by reduction of ethyl stearate with lithium aluminum hydride.

Definition

ChEBI: Octadecan-1-ol is a long-chain primary fatty alcohol consisting of a hydroxy function at C-1 of an unbranched saturated chain of 18 carbon atoms. It has a role as a plant metabolite, a human metabolite and an algal metabolite. It is a long-chain primary fatty alcohol, a fatty alcohol 18:0 and a primary alcohol. It derives from a hydride of an octadecane.

Allgemeine Beschreibung

Mixed monolayers of 1-octadecanol and ethylene glycol monooctadecyl ether were studied to investigate their evaporation suppressing performance. The rate dependence of the collapse pressure for an octadecanolmonolayer using axisymmetric drop shape analysis has been investigated.

Health Hazard

Mildly toxic by ingestion. Questionable carcinogen with experimental neoplastigenic data. A skin and eye irritant.

Brandgefahr

Flammable when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

Pharmazeutische Anwendungen

1-Octadecanol is used in cosmetics and topical pharmaceutical creams and ointments as a stiffening agent. By increasing the viscosity of an emulsion, stearyl alcohol increases its stability. 1-Octadecanol also has some emollient and weak emulsifying properties, and is used to increase the water-holding capacity of ointments, e.g. petrolatum. In addition, 1-Octadecanol has been used in controlled-release tablets, suppositories, and microspheres.It has also been investigated for use as a transdermal penetration enhancer.

Sicherheit(Safety)

Stearyl alcohol is generally considered to be an innocuous, nontoxic material. However, adverse reactions to stearyl alcohol present in topical preparations have been reported. These include contact urticaria and hypersensitivity reactions, which are possibly due to impurities contained in stearyl alcohol rather than stearyl alcohol itself.
The probable lethal oral human dose is greater than 15 g/kg.
LD50 (rat, oral): 20 g/kg

Synthese

1-Octadecanol is synthesized from Stearic acid, which may be obtained by saponification of Tallow, or hydrogenation of Cottonseed oil, from Castor oil or from other natural oils.

Lager

Stearyl alcohol is stable to acids and alkalis and does not usually become rancid. It should be stored in a well-closed container in a cool, dry place.

l?uterung methode

Crystallise octadecanol from MeOH, or dry Et2O and *C6H6, then fractionally distil it in vacuo. Also purify it by column chromatography. Free it from cetyl alcohol by zone refining. [Beilstein 1 IV 1888.]

Inkompatibilit?ten

Incompatible with strong oxidizing agents and strong acids.

Einzelnachweise

[1] P. SELVIN THOMAS. Electrical properties of natural rubber nanocomposites: effect of 1-octadecanol functionalization of carbon nanotubes[J]. Journal of Materials Science, 2011. DOI:10.1007/s10853-011-6174-4
[2] DIANA N. H. TRAN. Molecular Interactions behind the Synergistic Effect in Mixed Monolayers of 1-Octadecanol and Ethylene Glycol Monooctadecyl Ether[J]. The Journal of Physical Chemistry B, 2013. DOI:10.1021/jp401027c
[3] Rowe, R.C., Sheskey, P.J., & Quinn, M. (1994). Handbook of Pharmaceutical Excipients.

1-Octadecanol Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


1-Octadecanol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 548)Lieferanten
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Hebei Weibang Biotechnology Co., Ltd
+8615531157085
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112-92-5()Verwandte Suche:


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