2-Methyl-4-oxo-3-(prop-2-inyl)cy-clopent-2-en-1-yl-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropan-carboxylat
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- CAS-Nr.
- 23031-36-9
- Bezeichnung:
- 2-Methyl-4-oxo-3-(prop-2-inyl)cy-clopent-2-en-1-yl-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropan-carboxylat
- Englisch Name:
- Prallethrin
- Synonyma:
- ETOC;s4068;Pralle;ETOC(R);s-4068sf;NYLAR(R);ai3-29750;PRALLETHRIN;S-4068 forte;Prallethrin 0
- CBNumber:
- CB4471390
- Summenformel:
- C19H24O3
- Molgewicht:
- 300.39
- MOL-Datei:
- 23031-36-9.mol
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2-Methyl-4-oxo-3-(prop-2-inyl)cy-clopent-2-en-1-yl-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropan-carboxylat Eigenschaften
- Schmelzpunkt:
- 25°C
- Siedepunkt:
- 381.62°C (rough estimate)
- Dichte
- d420 1.03
- Dampfdruck
- ﹤4.3×10-5 Pa (23.1 °C)
- Brechungsindex
- 1.4200 (estimate)
- Flammpunkt:
- 139 °C
- storage temp.
- 2-8°C
- L?slichkeit
- Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Sparingly)
- Wasserl?slichkeit
- 8 mg l-1 (25 °C)
- Stabilit?t:
- Stable. Incompatible with strong oxidizing agents.
- CAS Datenbank
- 23031-36-9(CAS DataBase Reference)
- EPA chemische Informationen
- Prallethrin (23031-36-9)
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
| Kennzeichnung gef?hrlicher |
T,N |
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| R-S?tze: |
22-23-50/53 |
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| S-S?tze: |
45-60-61 |
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| RIDADR |
UN2811 6.1/PG 2 |
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| WGK Germany |
3 |
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| HS Code |
29162090 |
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| Giftige Stoffe Daten |
23031-36-9(Hazardous Substances Data) |
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| Toxizit?t |
mouse,LD50,oral,190mg/kg (190mg/kg),Iyakuhin Kenkyu. Study of Medical Supplies. Vol. 20, Pg. 228, 1989. |
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| Bildanzeige (GHS) |
 
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| Alarmwort |
Achtung |
| Gefahrenhinweise |
| Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
| H302 |
Gesundheitssch?dlich bei Verschlucken. |
Akute Toxizit?t oral |
Kategorie 4 |
Warnung |
![GHS hazard pictograms]() src="/GHS07.jpg" width="20" height="20" /> |
P264, P270, P301+P312, P330, P501 |
| H331 |
Giftig bei Einatmen. |
Akute Toxizit?t inhalativ |
Kategorie 3 |
Achtung |
![GHS hazard pictograms]() src="/GHS06.jpg" width="20" height="20" /> |
P261, P271, P304+P340, P311, P321,P403+P233, P405, P501 |
| H410 |
Sehr giftig für Wasserorganismen mit langfristiger Wirkung. |
Langfristig (chronisch) gew?ssergef?hrdend |
Kategorie 1 |
Warnung |
![GHS hazard pictograms]() src="/GHS09.jpg" width="20" height="20" /> |
P273, P391, P501 |
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| Sicherheit |
| P261 |
Einatmen von Staub vermeiden. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P264 |
Nach Gebrauch gründlich waschen. |
| P270 |
Bei Gebrauch nicht essen, trinken oder rauchen. |
| P273 |
Freisetzung in die Umwelt vermeiden. |
| P301+P312 |
BEI VERSCHLUCKEN: Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen. |
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2-Methyl-4-oxo-3-(prop-2-inyl)cy-clopent-2-en-1-yl-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropan-carboxylat Chemische Eigenschaften,Einsatz,Produktion Methoden
R-S?tze Betriebsanweisung:
R22:Gesundheitssch?dlich beim Verschlucken.
R23:Giftig beim Einatmen.
R50/53:Sehr giftig für Wasserorganismen, kann in Gew?ssern l?ngerfristig sch?dliche Wirkungen haben.
S-S?tze Betriebsanweisung:
S45:Bei Unfall oder Unwohlsein sofort Arzt zuziehen (wenn m?glich, dieses Etikett vorzeigen).
S60:Dieses Produkt und sein Beh?lter sind als gef?hrlicher Abfall zu entsorgen.
S61:Freisetzung in die Umwelt vermeiden. Besondere Anweisungen einholen/Sicherheitsdatenblatt zu Rate ziehen.
Chemische Eigenschaften
solid
Verwenden
Prallethrin ia a synthetic pyrethroid; propynyl analog of allethrin. Prallethrin is used as an insecticide.
Hazard
A poison by ingestion and inhalation. Low
toxicity by skin contact.
Pharmakologie
Prallethrin is a propynyl analog of allethrin, with
2-methyl-4-oxo-3-(prop-2-ynyl)-cyclopent-2-enyl as the
secondary alcohol moiety that has been introduced against
public health pests (113–115). The ester of the (S)-alcohol
with (1R)-trans,cis-chrysanthemic acid resolved partially
is commercialized on the strength of the assessment of
insecticidal action of individual stereoisomers (116). Compared
with d-allethrin, it is approximately four, six, and
five times more effective on Musca domestica (for killing),
Blattella germanica (for killing), and Culex pipiens pallens
(for knockdown), respectively (43). A lower level of resistance
to prallethrin than to phenoxybenzyl pyrethroids
was demonstrated in a kdr-resistant housefly strain (116).
Sicherheitsprofil
A poison by ingestion
and inhalation. Low toxicity by skin contact.
When heated to decomposition it emits
acrid smoke and irritating vapors.
Stoffwechselwegen
Prallethrin is stable under normal room temperature storage conditions
for up to 36 months. It is labile to alkali at the ester linkage, forming 2
and 3 (Scheme 1). Analogy with the allethrins (from which it differs
only in the degree of unsaturation in the side chain - propyne rather
than propene) would suggest that the compound is very photolabile.
2-Methyl-4-oxo-3-(prop-2-inyl)cy-clopent-2-en-1-yl-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropan-carboxylat Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
2-Methyl-4-oxo-3-(prop-2-inyl)cy-clopent-2-en-1-yl-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropan-carboxylat Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 140)Lieferanten
23031-36-9(2-Methyl-4-oxo-3-(prop-2-inyl)cy-clopent-2-en-1-yl-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropan-carboxylat)Verwandte Suche:
- D-Trans-Prallethrin
- 2-Methyl-4-oxo-3-(2-propynyl)-2-cyclopenten-1-yl 2,2-dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylate
- Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propenyl)-, 2-methyl-4-oxo-3-(2-propynyl)-2-cyclopenten-1-yl ester
- prallethrin (bsi,draft e-iso9, prallethrine (draft f-iso)etoc
- PRALLETHRIN,RICH-D-TRANS
- 2,2-Dimethyl-3-(2-methylprop-1-enyl)-cyclopropanecarboxylate
- 2-Methyl-4-oxo-3-(prop-2-ynyl)cyclopent-2-en-1-yl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate
- ETOC(R)
- ETOC
- CYCLOPROPANECARBOXYLIC ACID, 2,2-DIMETHYL-3-(2-METHYL-1-PROPENYL)-(1S)-2-METHYL-4-OXO-3-(2-PROPENYL)-2-CYCLOPENTEN-1-YL ESTER, (1R)
- prallethrin ETOC 2-methyl-4-oxo-3-(prop-2-ynyl)cyclopent-2-en-1-yl 2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate
- 2,2-dimethyl-3-(2-methylpropenyl)-,esterwith4-hydroxy-3-methyl-2-(2-propynyl)-2-cyclopenten-1-oCyclopropanecarboxylicacid
- 2-dimethyl-3-(2-methylpropenyl)-esterwith4-hydroxy-3-methyl-2-(2-propynyl)-2-cyclopenten-1-onecyclopropanecarboxylicaci
- 2-Methyl-4-oxo-3-(2-propynyl)cyclopent-2-enyl(1R)-cis,trans-chrysanthemate
- ai3-29750
- d,d-t80-prallethrin
- s4068
- s-4068sf
- trans-(+-)-ydroxy-3-methyl-2-(2-propynyl)-2-cyclopenten-1-on
- (RS)-2-Methyl-4-oxo-3-prop-2-ynylcyclopent-2-enyl (1RS,3RS:1RS,3SR)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropanecarboxylate
- 2-methyl-4-oxo-3-prop-2-ynylcyclopent-2-enyl-2,2-dimethyl-3-(2-methylprop-1-enyl) cyclopropanecarboxylate
- Pralle
- 2,2-Dimethyl-3-(2-methyl-1-propen-1-yl)-1-cyclopropanecarboxylic acid 2-methyl-4-oxo-3-(2-propynyl)-2-cyclopenten-1-yl ester
- 2,2-Dimethyl-3-(2-methyl-1-propenyl)cyclopropanecarboxylic acid 2-methyl-4-oxo-3-(2-propynyl)-2-cyclopenten-1-yl ester
- Rethrinpropargyl
- S-4068 forte
- 2,2-DiMethyl-3-(2-Methyl-1-propen-1-yl)cyclopropanecarboxylic Acid 2-Methyl-4-oxo-3-(2-propyn-1-yl)-2-cyclopenten-1-yl Ester
- Acetylene C PerMethrin
- trans-(±)-4-Hydroxy-
3-Methyl-2-(2-propynyl)-2-cyclopenten-1-one 2,2-DiMethyl-3-(2-Methylpropenyl)
cyclopropanecarboxylate, (8CI)
- Prallethrin 10mg [23031-36-9]
- 2-Methyl-4-oxo-3-(prop-2-yn-1-yl)cyclopent-2-en-1-yl 2,2-diMethyl-3-(2-Methylprop-1-en-1-yl)cyclopropanecarboxylate
- Prallethrin
(Mixture of diastereoMers)
- (S)-2-METHYL-4-OXO-3-(2-PROPYNYL)-CYCLOPENT-1-YL (1R)-CIS-TRANS-CHRYSANTHEMATE
- (S)-2-METHYL-4-OXO-3-PROP-2-YNYLCYCLOPENT-1-YL(1R)-CIS,TRANS-2,2-DIMETHYL-3-(2-METHYLPROP-1-ENYL)-CYCLOPROPANECARBOXYLATE
- PRALLETHRIN
- NYLAR(R)
- (RS)-2-methyl-4-oxo-3-(2-propynyl)cyclopent-2-enyl(1RS)-cis,trans-chrysanthemate
- Prallethrin 0
- Prallethrin @100 μg/mL in Methanol
- Cyclopropanecarboxylic acid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-, 2-methyl-4-oxo-3-(2-propyn-1-yl)-2-cyclopenten-1-yl ester
- (1S,3S)-2,2-dimethyl-3-(2-methylprop-1-enyl)-1-cyclopropanecarboxylic acid [(1R)-2-methyl-4-oxo-3-prop-2-ynyl-1-cyclopent-2-enyl] ester
- Prallethrin(Mixture of diastereom)
- Prallethrin 10.0 μg/ml Acetonitrile
- 23031-36-9
- Agro-Products
- INSECTICIDE
