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Palladacycle Gen. 3

Palladacycle Gen. 3 Struktur
1447963-73-6
CAS-Nr.
1447963-73-6
Englisch Name:
Palladacycle Gen. 3
Synonyma:
Palladacycle Gen. 3;CPHOS PALLADACYCLE GEN. 3;{2-amino-[1,1-biphenyl]-2-yl}palladio;Palladacycle Gen. 3 ISO 9001：2015 REACH;Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), 98%;Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),CPhos Pd G3;CPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II);Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / CPhos Pd G3;Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),CPhos Palladacycle Gen. 3
CBNumber:
CB43175619
Summenformel:
C41H54N3O3PPdS
Molgewicht:
806.35
MOL-Datei:
1447963-73-6.mol

Palladacycle Gen. 3 Eigenschaften

Schmelzpunkt:
176-178 °C (decomposition)
Aggregatzustand
Powder
Farbe
white to off-white
InChIKey
BYZMMBLECCTRMT-UHFFFAOYSA-N
SMILES
P(C1CCCCC1)(C1CCCCC1)(C1C=CC=CC=1C1C(=CC=CC=1N(C)C)N(C)C)[Pd+2]1(NC2=CC=CC=C2C2=CC=CC=[C-]12)[O-]S(=O)(=O)C

Sicherheit

Palladacycle Gen. 3 Chemische Eigenschaften,Einsatz,Produktion Methoden

Reaktionen

  1. Catalyst for the highly selective cross-coupling of secondary alkylzinc reagents with heteroaryl halides
  2. Catalyst for the completely linear-selective Negishi cross-coupling of allylzinc halides with aryl and vinyl electrophiles
Reactions of 1447963-73-6

Allgemeine Beschreibung

CPhos Pd G3 is a modified G3 precatalyst (G3′). It has been synthesized by Buchwald and coworkers from second generation (G2) precatalyst by methylation of the amino group present on biphenyl backbone. It is a useful catalyst for various cross-coupling reactions. They are versatile catalysts. They have long life in solution and are readily soluble in various organic solvents. G3- precatalysts have been employed in various C-N bond forming reactions.

Palladacycle Gen. 3 Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte

Palladacycle Gen. 3 Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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  • CPHOS PALLADACYCLE GEN. 3
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), 98%
  • METHANESULFONATO(2-DICYCLOHEXYLPHOSPHINO-2',6'-BIS(DIMETHYLAMINO)-1,1'-BIPHENYL)(2'-AMINO-1,1'-BIPHENYL-2-YL)PALLADIUM(II),98%[CPHOSPALLADACYCLEGEN.3]
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),CPhos Palladacycle Gen. 3
  • Palladacycle Gen. 3
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II) / CPhos Pd G3
  • Palladacycle Gen. 3 ISO 9001：2015 REACH
  • CPhos Pd G3 / Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • {2-amino-[1,1-biphenyl]-2-yl}palladio
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II)
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II),CPhos Pd G3
  • Methanesulfonato(2-dicyclohexylphosphino-2',6'-bis(dimethylamino)-1,1'-biphenyl)(2'-amino-1,1'-biphenyl-2-yl)palladium(II), 98% [CPhos Palladacycle Gen. 3
  • 1447963-73-6
  • C41H54N3O3PPdS
  • Buchwald Ligands&Precatalysts
  • Buchwald Precatalysts Series
  • Pd
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