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3,4,5-Trimethoxybenzoic acid [(2S,7aα,14aβ)-dodecahydro-11-oxo-7α,14α-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-2β-yl] ester

3,4,5-Trimethoxybenzoic acid [(2S,7aα,14aβ)-dodecahydro-11-oxo-7α,14α-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-2β-yl] ester Struktur
30430-48-9
CAS-Nr.
30430-48-9
Englisch Name:
3,4,5-Trimethoxybenzoic acid [(2S,7aα,14aβ)-dodecahydro-11-oxo-7α,14α-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-2β-yl] ester
Synonyma:
Sarodesmine;1',2'-e][1,5]diazocin-2-yl ester;3,4,5-dimethoxy-benzoic acid 11-oxo-dodecahydro-7,14-methano-dipyrido[1,2-a;3,4,5-Trimethoxybenzoic acid [(2S,7aα,14aβ)-dodecahydro-11-oxo-7α,14α-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-2β-yl] ester;Benzoic acid, 3,4,5-trimethoxy-, (2S,7S,7aR,14S,14aS)-dodecahydro-11-oxo-7,14-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-2-yl ester (9CI)
CBNumber:
CB42424598
Summenformel:
C25H34N2O6
Molgewicht:
458.55
MOL-Datei:
30430-48-9.mol

3,4,5-Trimethoxybenzoic acid [(2S,7aα,14aβ)-dodecahydro-11-oxo-7α,14α-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-2β-yl] ester Eigenschaften

Schmelzpunkt:
174°C

Sicherheit

3,4,5-Trimethoxybenzoic acid [(2S,7aα,14aβ)-dodecahydro-11-oxo-7α,14α-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-2β-yl] ester Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

Obtained from the dried branches of Sarothamnus catalaunicus Webb, this alkaloid is dextrorotatory with [α]20D + 73.6° (c 1.0, MeOH). It forms clusters of colourless needles from either MeOH or Et20. On acid hydrolysis it forms lupanine and trimethoxybenzoic acid, thereby confirming the above structure.

Einzelnachweise

Faugeras, Paris., Compt. Rend., 271D, 611 (1970)

3,4,5-Trimethoxybenzoic acid [(2S,7aα,14aβ)-dodecahydro-11-oxo-7α,14α-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-2β-yl] ester Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


3,4,5-Trimethoxybenzoic acid [(2S,7aα,14aβ)-dodecahydro-11-oxo-7α,14α-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-2β-yl] ester Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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  • 3,4,5-Trimethoxybenzoic acid [(2S,7aα,14aβ)-dodecahydro-11-oxo-7α,14α-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-2β-yl] ester
  • Sarodesmine
  • 1',2'-e][1,5]diazocin-2-yl ester
  • 3,4,5-dimethoxy-benzoic acid 11-oxo-dodecahydro-7,14-methano-dipyrido[1,2-a
  • Benzoic acid, 3,4,5-trimethoxy-, (2S,7S,7aR,14S,14aS)-dodecahydro-11-oxo-7,14-methano-2H,6H-dipyrido[1,2-a:1',2'-e][1,5]diazocin-2-yl ester (9CI)
  • 30430-48-9
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