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(26aS)-2,3,12,13,26,26a-Hexahydro-19-hydroxy-5,6,32-trimethoxy-1-methyl-8,11:22,25-dietheno-10,15-methano-16,20-metheno-1H,20H-pyrido[2,3,4-uv][1,15,8]benzodioxaazacyclotricosin-30-one

(26aS)-2,3,12,13,26,26a-Hexahydro-19-hydroxy-5,6,32-trimethoxy-1-methyl-8,11:22,25-dietheno-10,15-methano-16,20-metheno-1H,20H-pyrido[2,3,4-uv][1,15,8]benzodioxaazacyclotricosin-30-one Struktur
38835-79-9
CAS-Nr.
38835-79-9
Englisch Name:
(26aS)-2,3,12,13,26,26a-Hexahydro-19-hydroxy-5,6,32-trimethoxy-1-methyl-8,11:22,25-dietheno-10,15-methano-16,20-metheno-1H,20H-pyrido[2,3,4-uv][1,15,8]benzodioxaazacyclotricosin-30-one
Synonyma:
Stepinonine;(26aS)-2,3,12,13,26,26a-Hexahydro-19-hydroxy-5,6,32-trimethoxy-1-methyl-8,11:22,25-dietheno-10,15-methano-16,20-metheno-1H,20H-pyrido[2,3,4-uv][1,15,8]benzodioxaazacyclotricosin-30-one
CBNumber:
CB42173089
Summenformel:
C36H34N2O7
Molgewicht:
606.66436
MOL-Datei:
38835-79-9.mol

(26aS)-2,3,12,13,26,26a-Hexahydro-19-hydroxy-5,6,32-trimethoxy-1-methyl-8,11:22,25-dietheno-10,15-methano-16,20-metheno-1H,20H-pyrido[2,3,4-uv][1,15,8]benzodioxaazacyclotricosin-30-one Eigenschaften

Schmelzpunkt:
244-5°C

Sicherheit

(26aS)-2,3,12,13,26,26a-Hexahydro-19-hydroxy-5,6,32-trimethoxy-1-methyl-8,11:22,25-dietheno-10,15-methano-16,20-metheno-1H,20H-pyrido[2,3,4-uv][1,15,8]benzodioxaazacyclotricosin-30-one Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

A bisbenzylisoquinoline alkaloid present in Stephania japonica, the base forms pale yellow prisms from EtOH and has the double melting point given above. It is laevorotatory with [α]30D - 28° (c 1.0, pyridine). The acetyl derivative has m.p. 157°C. The structure given above has been established on the basis of the NMR and mass spectra.

Einzelnachweise

Tomita, Ibuka., J. Pharm. Soc., Japan, 83, 996 (1963)
Ibuka, Konoshima, Inubushi., Tetrahedron Lett., 4001 (1972)

(26aS)-2,3,12,13,26,26a-Hexahydro-19-hydroxy-5,6,32-trimethoxy-1-methyl-8,11:22,25-dietheno-10,15-methano-16,20-metheno-1H,20H-pyrido[2,3,4-uv][1,15,8]benzodioxaazacyclotricosin-30-one Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


(26aS)-2,3,12,13,26,26a-Hexahydro-19-hydroxy-5,6,32-trimethoxy-1-methyl-8,11:22,25-dietheno-10,15-methano-16,20-metheno-1H,20H-pyrido[2,3,4-uv][1,15,8]benzodioxaazacyclotricosin-30-one Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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  • (26aS)-2,3,12,13,26,26a-Hexahydro-19-hydroxy-5,6,32-trimethoxy-1-methyl-8,11:22,25-dietheno-10,15-methano-16,20-metheno-1H,20H-pyrido[2,3,4-uv][1,15,8]benzodioxaazacyclotricosin-30-one
  • Stepinonine
  • 38835-79-9
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