13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine Chemische Eigenschaften,Einsatz,Produktion Methoden
Beschreibung
This alkaloid has been obtained by Gadamer and Winterfeld during a systematic
examination of the residues remaining after the isolation of chelidonine from
Chelidonum majus L. The base forms colourless prisms on crystallization from
EtOH and has [α]
D + 115.8°. It furnishes a crystalline hydrochloride and an
aurichloride, m.p. 237-8°C. The O-acetate is amorphous, m.p. 147°C; [α]
D +
55.5°. One methoxyl group, two methylenedioxy groups, one hydroxyl group
and a methylimino group are present in the molecule.
Einzelnachweise
Gadamer, Winterfeld., Arch. Pharm., 257,298 (1919)
Garlamer, Winterfeld., ibid, 258, 148 (1920)
Gadamer, Winterfeld., ibid, 262,249 (1924)
Bruchhausen, Bersch., Ber., 63,2520 (1930)
Bruchhausen, Bersch., ibid, 64,370 (1931)
13,14-Dihydro-6-hydroxy-12-methoxy[1,3]benzodioxolo[5,6-c]-1,3-dioxolo[4,5-i]phenanthridine Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte