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15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine

15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Struktur
21040-66-4
CAS-Nr.
21040-66-4
Englisch Name:
15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine
Synonyma:
Spiradine G;15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine;12aH,14H-3,14a-Ethano-14,4b,8-ethanylylidene-1H,5H-[2]benzopyrano[4,3-g]oxazolo[3,2-a]azocin-17-ol, decahydro-8-methyl-2-methylene-, (3S,4aR,4bR,8R,8aR,12aS,14S,14aR,17S,18R)- (9CI)
CBNumber:
CB22428956
Summenformel:
C22H31NO3
Molgewicht:
357.49
MOL-Datei:
21040-66-4.mol

15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Eigenschaften

Schmelzpunkt:
168-l700 C

Sicherheit

15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

A sixth alkaloid found in Spiraea japonica L. fil., the base is laevorotatory with [α]D - 137° (c 1.16, MeOH). Reduction with NaBH4 gives a triol while oxida_x0002_tion with chromic acid in pyridine forms a monoketone, m.p. IS8-l60°C. The presence of an exocyclic methylene group is confirmed by catalytic reduction and subsequent oxidation with KMn04 to give a ketone.

Einzelnachweise

Toda, Hirata., Tetrahedron Lett., 5565 (1968)

15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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  • 15,23-Dideoxy-19,23-epoxy-6β-hydroxyajaconine
  • Spiradine G
  • 12aH,14H-3,14a-Ethano-14,4b,8-ethanylylidene-1H,5H-[2]benzopyrano[4,3-g]oxazolo[3,2-a]azocin-17-ol, decahydro-8-methyl-2-methylene-, (3S,4aR,4bR,8R,8aR,12aS,14S,14aR,17S,18R)- (9CI)
  • 21040-66-4
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