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PARAFORMALDEHYDE

PARAFORMALDEHYDE Struktur
25231-38-3
CAS-Nr.
25231-38-3
Englisch Name:
PARAFORMALDEHYDE
Synonyma:
PARAFORM;POLYACETAL;ACETAL RESIN;POLY(TRIOXANE);POLYOXMETHYLENE;POLYFORMALDEHYDE;POLYACETAL RESIN;FORMALDEHYDE RESIN;Polyoxymethylenediacetate;oxymethylene homopolymer diacetate
CBNumber:
CB2233204
Summenformel:
C3H6O3X2
Molgewicht:
90.08
MOL-Datei:
25231-38-3.mol

PARAFORMALDEHYDE Eigenschaften

Schmelzpunkt:
175 °C
Dichte
1.42 g/mL at 25 °C
Dampfdichte
1.03 (vs air)
Dampfdruck
<1.45 mm Hg ( 25 °C)
Flammpunkt:
158 °F
L?slichkeit
chlorophenol above 70°C: soluble
Aggregatzustand
prilled
Farbe
White
Dielectric constant
3.6(Ambient)
EPA chemische Informationen
Poly(oxymethylene), .alpha.-acetyl-.omega.-(acetyloxy)- (25231-38-3)

Sicherheit

Kennzeichnung gef?hrlicher Xn
R-S?tze: 31
S-S?tze: 36
RIDADR  UN 2213 4.1/PG 3
WGK Germany  3
RTECS-Nr. RV0540000

PARAFORMALDEHYDE Chemische Eigenschaften,Einsatz,Produktion Methoden

R-S?tze Betriebsanweisung:

R31:Entwickelt bei Berührung mit S?ure giftige Gase.

S-S?tze Betriebsanweisung:

S36:DE: Bei der Arbeit geeignete Schutzkleidung tragen.

Chemische Eigenschaften

The homopolymers and copolymers of formaldehyde, prepared as described above, are rigid materials with broadly similar properties. They are particularly noted for their stiffness, fatigue resistance and creep resistance and are counted as one of the 'engineering plastics'. They find application principally in injection moulded mechanical parts such as gears, cams and plumbing components. The copolymers are somewhat less crystalline and therefore have lower density, melting point, hardness, tensile strength and flexural modulus. The main advantage claimed for the copolymers is improved processability, with less degradation at processing temperatures.
As is characteristic of crystalline polymers which do not interact with any liquids, there are no effective solvents at room temperature for the commercial formaldehyde polymers. At temperatures above 70°C, solution occurs in a few solvents such as the chlorophenols. The resistance of the polymers to inorganic reagents is not, however, outstanding. Strong acids, strong alkalis and oxidizing agents cause a deterioration in mechanical properties. (The copolymers are significantly superior to the homopolymers in alkali resistance.)
Oxidation of polyformaldehyde occurs in air on prolonged exposure to ultraviolet light and/or elevated temperature. Antioxidants are therefore commonly added to the polymers.

synthetische

(a) Homopolymers In the preparation of high molecular weight polyformaldehyde the initial operation consists of the production of pure formaldehyde, free from low molecular weight polymers and other hydroxy compounds which cause chain transfer. In a typical process potassium hydroxide-precipitated paraformaldehyde (degree of polymerization approximately 200) is carefully washed with water and dried for several hours in vacuo at 80??C. The dried polymer is then decomposed in nitrogen at 150-160??C; the product is passed through several traps at -15??C to remove water, glycols, and other impurities. The resulting formaldehyde has a water content (free and combined) of less than 0.1 %.
The formaldehyde is then introduced into a reactor where it passes over the surface of a rapidly stirred solution of initiator (either a Lewis acid or base; triphenylphosphine appears to be favoured) in a carefully dried inert medium such as heptane at about 40??C. The process is designed to give a very low concentration of formaldehyde to minimize transfer from polymer to monomer. To the initiator solution may be added a polymer stabilizer (e.g. diphenylamine) and transfer agents (e.g. traces of water or methanol). Polymerization is continued until the concentration of polymer in the slurry is about 20% and then the polymer is collected by filtration.
In the final stage the polymer is subjected to an esterification reaction to improve its thermal stability. The esterification may be effected with a number of anhydrides, but acetic anhydride is generally preferred. Typically, the polyformaldehyde is heated under slight pressure to about 160??C with acetic anhydride and a small amount of sodium acetate (catalyst). The polymer is soluble in acetic anhydride at this temperature but is precipitated when the solution is cooled. The acetylated polymer is collected by filtration, washed with water (to remove the anhydride and catalyst) and then acetone (containing di-fi-naphthyl-p-phenylenediamine as antioxidant), and dried in vacuo at 70??C. The product is then extruded and chopped into granules. The average molecular weight (Mn) of the polyformaldehyde produced by these methods is generally in the range 30000-100000.
The polymerization of formaldehyde by Lewis bases such as triaryl amines (R3N), arsines, and phosphines proceeds by the following anionic mechanism:

25231-38-3 synthesis_1


The polymerization of formaldehyde by Lewis acids such as boron trifluoride proceeds according to following cationic mechanism:

25231-38-3 synthesis_2


The hydroxy-terminated polymers have poor thermal stability. Loss of a proton, possibly to an initiator residue, from a chain end gives an anion capable of decomposing to formaldehyde by the reverse of the propagation process. The stability of the polymer is therefore improved if the hydroxy endgroups are removed by esterification:

25231-38-3 synthesis_3


It may be noted here that the polymerization of formaldehyde cannot be effected with free radical initiators.
(b) Copolymers
Details of the procedures used in the preparation of commercial formaldehyde copolymers have not been fully disclosed. The principal monomer is trioxan and the second monomer is a cyclic ether such as ethylene oxide, 1,3- dioxolane or an oxetane; ethylene oxide appears to be the preferred comonomer and is used at a level of about 2%. Boron trifluoride (or its etherate) is apparently the most satisfactory initiator, although many cationic initiators are effective; anionic and free radical initiators are not effective. The reaction is carried out in bulk. The rapid solidification of the polymer

PARAFORMALDEHYDE Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


PARAFORMALDEHYDE Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

Global( 12)Lieferanten
Firmenname Telefon E-Mail Land Produktkatalog Edge Rate
CONIER CHEM AND PHARMA LIMITED
+8618523575427
sales@conier.com China 49374 58
Alfa Chemistry

Info@alfa-chemistry.com United States 24072 58
Guangdong wengjiang Chemical Reagent Co., Ltd. 0751-2815987 13927875076
3007432263@qq.com China 9969 58
Shaanxi DIDU pharmaceutical and Chemical Co., Ltd 15229059051
1027@dideu.com China 10003 58
Shanghai Saikerui Biotechnology Co. , Ltd. 021-58000709 15900491054
info@scrbio.com China 10329 58
Shanghai Beiwanta Biotechnology Co., Ltd. 021-67187366 19901745723
info@bwtlab.com China 9284 58
SHANGHAI ZZBIO CO., LTD. 15102117276 19921389125
tech@zzbioco.com China 12065 58

25231-38-3()Verwandte Suche:


  • PARAFORM
  • POLYACETAL
  • POLYACETAL RESIN
  • POLYFORMALDEHYDE
  • POLY(OXYMETHYLENE), ACETATE END-CAPPED
  • POLYOXMETHYLENE
  • POLY(TRIOXANE)
  • FORMALDEHYDE RESIN
  • .alpha.-acetyl-.omega.-(acetyloxy)-Poly(oxymethylene)
  • alpha-acetyl-omega-(acetyloxy)-poly(oxymethylene
  • Polyoxymethylenediacetate
  • ACETAL RESIN
  • POLY(OXYMETHYLENE), ACETATE END-CAPPED, MELT INDEX 6
  • Poly(oxymethylene), .alpha.-acetyl-.omega.-(acetyloxy)-
  • Poly(oxymethylene), α-acetyl-ω-(acetyloxy)-
  • oxymethylene homopolymer diacetate
  • α-Acetyl-ω-(acetyloxy)-Poly(oxymethylene)
  • 25231-38-3
  • CH3CO2CH2OnCOCH3
  • Aldehydes
  • Building Blocks
  • Carbonyl Compounds
  • C1 to C6
  • Organic Building Blocks
  • Polymers
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