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USHINSUNINE

USHINSUNINE Struktur
3175-89-1
CAS-Nr.
3175-89-1
Englisch Name:
USHINSUNINE
Synonyma:
USHINSUNINE;Oliveroline;Micheline A;(7aS)-6,7,7a,8-Tetrahydro-7-methyl-5H-benzo[g]-1,3-benzodioxolo[6,5,4-de]quinolin-8α-ol;5H-Benzo[g]-1,3-benzodioxolo[6,5,4-de]quinolin-8-ol, 6,7,7a,8-tetrahydro-7-methyl-, (7aS,8R)-
CBNumber:
CB21448043
Summenformel:
C18H17NO3
Molgewicht:
295.33
MOL-Datei:
3175-89-1.mol

USHINSUNINE Eigenschaften

Schmelzpunkt:
178-180 °C
Siedepunkt:
478.0±45.0 °C(Predicted)
Dichte
1.361±0.06 g/cm3(Predicted)
pka
13.46±0.20(Predicted)

Sicherheit

USHINSUNINE Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

An aporphine alkaloid isolated from Michelia alba, M. champaca and M. compressa, this base forms colourless crystals from MeOH or EtOH. It is laevorotatory having [α]18D - 117° (CHCI3 ). A methylenedioxy group, a non-phenolic hydroxyl group and a methylimino group are present.

Occurrence

Polyalthia oliveri yields this aporphine alkaloid. The base yields colourless needles when crystallized from MeOH and is laevorotatory with a specific rotation of [α]D -64° (c 0.5, CHCI3). It gives an ultraviolet spectrum in EtOH with absorption maxima at 236, 275 and 315 nm.

Einzelnachweise

Tomita, Furukawa., J. Pharm. Soc., Japan, 82, 925 (1962)
Yang et al., ibid, 82, 794, 798, 804, 811 (1962)
Yang et al., ibid, 83,216 (1963)
Absolute configuration: Kunimotoetal., Chem. Pharm. Bull., 19,1502 (1971)

USHINSUNINE Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


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3175-89-1()Verwandte Suche:


  • USHINSUNINE
  • (7aS)-6,7,7a,8-Tetrahydro-7-methyl-5H-benzo[g]-1,3-benzodioxolo[6,5,4-de]quinolin-8α-ol
  • Micheline A
  • Oliveroline
  • 5H-Benzo[g]-1,3-benzodioxolo[6,5,4-de]quinolin-8-ol, 6,7,7a,8-tetrahydro-7-methyl-, (7aS,8R)-
  • 3175-89-1
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