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4-(9-ADENYL)-D-ERYTHRO-2,3-DIHYDROXYBUTYRIC ACID

4-(9-ADENYL)-D-ERYTHRO-2,3-DIHYDROXYBUTYRIC ACID Struktur
23918-98-1
CAS-Nr.
23918-98-1
Englisch Name:
4-(9-ADENYL)-D-ERYTHRO-2,3-DIHYDROXYBUTYRIC ACID
Synonyma:
AA-307;Lentysine;lentinacin;eritadenine;D-ERITADENINE;d-erythronicaci;4-(6-AMinopurin-9-yl)-4-deoxy-D-erythronic Acid;4-(9-ADENYL)-D-ERYTHRO-2,3-DIHYDROXYBUTYRIC ACID;d-4-(6-amino-9h-purin-9-yl)-4-deoxyerythronicacid;4-(6-AMino-9H-purin-9-yl)-4-deoxy-D-erythronic Acid
CBNumber:
CB0759223
Summenformel:
C9H11N5O4
Molgewicht:
253.22
MOL-Datei:
23918-98-1.mol

4-(9-ADENYL)-D-ERYTHRO-2,3-DIHYDROXYBUTYRIC ACID Eigenschaften

Schmelzpunkt:
>270°C (dec.)
Siedepunkt:
721℃
alpha 
D +51.4° (c = 1.6 in 0.1N NaOH)
Dichte
1.92
Brechungsindex
1.7610 (estimate)
Flammpunkt:
390℃
storage temp. 
Refrigerator
L?slichkeit
Aqueous Acid (Slightly, Heated), DMSO (Slightly)
Aggregatzustand
Solid
pka
3.37±0.17(Predicted)
Farbe
White to Light Beige

Sicherheit

4-(9-ADENYL)-D-ERYTHRO-2,3-DIHYDROXYBUTYRIC ACID Chemische Eigenschaften,Einsatz,Produktion Methoden

Beschreibung

The empirical formula of this alkaloid should read C9H II N 504' The natural compound is the D-Erythro-form of the base. Melting points recorded for this alkaloid are 279°C (dec.) by Kamiya et al and 26l-3°C (dec.) by Chibata and his colleagues. The alkaloid has specific rotations of [α]D+ 16° (N-HC1) and [α] D + 50° (0.1 N-NaOH). It gives an ultraviolet spectrum in H20 with a single absorption maximum at 26l.5 nm which is shifted to 259.5 nm inN-HCl and is at 262 nm in N-NaOH. Eritadenine forms a methyl ester, m.p. 231°C (dec.) and a diacetate, m.p. 225°C (dec.).

Chemische Eigenschaften

Pale Yellow Solid

Verwenden

Hypocholesterolemic isolated from shiitake mushrooms, effecting phospholipid and linoleic acid metabolisms. Specifically, Eritadenine is a potent inhibitor of S-adenosyl-L-homocysteine hydrolase (SAHH), decreasing total cholesterol levels in plasma.

Einzelnachweise

Chibata et al., Experientia, 25,1237 (1969)
Kamiya et al., Tetrahedron Lett., 4729 (1969)

4-(9-ADENYL)-D-ERYTHRO-2,3-DIHYDROXYBUTYRIC ACID Upstream-Materialien And Downstream Produkte

Upstream-Materialien

Downstream Produkte


4-(9-ADENYL)-D-ERYTHRO-2,3-DIHYDROXYBUTYRIC ACID Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.

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  • 4-(9-ADENYL)-D-ERYTHRO-2,3-DIHYDROXYBUTYRIC ACID
  • 6-amino-alpha,beta-dihydroxy-,(r-(r*,r*))-9h-purine-9-butanoicaci
  • d-4-(6-amino-9h-purin-9-yl)-4-deoxyerythronicacid
  • d-erythronicaci
  • eritadenine
  • lentinacin
  • (αR,βR)-6-Amino-α,β-dihydroxy-9H-purine-9-butanoic acid
  • AA-307
  • Lentysine
  • Lentysine 4-(9-Adenyl)-D-erythro-2,3-dihydroxybutyric acid
  • [R-(R*,R*)]-6-Amino-alpha,beta-dihydroxy-9H-furine-9-butanoic acid
  • 4-(6-AMino-9H-purin-9-yl)-4-deoxy-D-erythronic Acid
  • 4-(6-AMinopurin-9-yl)-4-deoxy-D-erythronic Acid
  • D-ERITADENINE
  • 9H-Purine-9-butanoic acid, 6-amino-α,β-dihydroxy-, (αR,βR)-
  • 23918-98-1
  • Inhibitors
  • Intermediates & Fine Chemicals
  • Pharmaceuticals
  • A potent inhibitor of S-adenosyl-L-homocysteine hydrolase.
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