[S-(R*,S*)]-α-[2-(Dimethylamino)-1-methylethyl]-α-phenylphenethylalkohol
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- CAS-Nr.
- 38345-66-3
- Bezeichnung:
- [S-(R*,S*)]-α-[2-(Dimethylamino)-1-methylethyl]-α-phenylphenethylalkohol
- Englisch Name:
- (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
- Synonyma:
- chirald;Oxiphene;D-OXYPHENE;chirald tm;CHIRALD(R);DEXTROOXYPHENE;α-(+)-Oxyphene;Darvon alcohol;Einecs 253-893-6;Mosher'S reagent
- CBNumber:
- CB0251222
- Summenformel:
- C19H25NO
- Molgewicht:
- 283.41
- MOL-Datei:
- 38345-66-3.mol
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[S-(R*,S*)]-α-[2-(Dimethylamino)-1-methylethyl]-α-phenylphenethylalkohol Eigenschaften
Sicherheit
- Risiko- und Sicherheitserkl?rung
- Gefahreninformationscode (GHS)
Bildanzeige (GHS) |
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Alarmwort |
Warnung |
Gefahrenhinweise |
Code |
Gefahrenhinweise |
Gefahrenklasse |
Abteilung |
Alarmwort |
Symbol |
P-Code |
H302 |
Gesundheitssch?dlich bei Verschlucken. |
Akute Toxizit?t oral |
Kategorie 4 |
Warnung |
src="/GHS07.jpg" width="20" height="20" /> |
P264, P270, P301+P312, P330, P501 |
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Sicherheit |
P264 |
Nach Gebrauch gründlich waschen. |
P264 |
Nach Gebrauch gründlich waschen. |
P270 |
Bei Gebrauch nicht essen, trinken oder rauchen. |
P301+P312 |
BEI VERSCHLUCKEN: Bei Unwohlsein GIFTINFORMATIONSZENTRUM/Arzt/... (geeignete Stelle für medizinische Notfallversorgung vom Hersteller/Lieferanten anzugeben) anrufen. |
P330 |
Mund ausspülen. |
P501 |
Inhalt/Beh?lter ... (Entsorgungsvorschriften vom Hersteller anzugeben) zuführen. |
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[S-(R*,S*)]-α-[2-(Dimethylamino)-1-methylethyl]-α-phenylphenethylalkohol Chemische Eigenschaften,Einsatz,Produktion Methoden
Verwenden
Reducing reagent in organic synthesis.
l?uterung methode
Purify the hydrochloride by dissolving 1.5g in 13.5 mL of 5N HCl, heat to boiling and evaporate in a vacuum. Recrystallise the hydrochloride three times from MeOH/EtOAc giving m 189-190o, []D -33.7o (c 1, H2O) {enantiomer has +34.2o}. The hydrochloride in the minimum volume of water is basified with aqueous 5N NaOH and extracted with Et2O. The extract is dried (K2CO3) and evaporated, leaving a residue which is stored in a desiccator over solid KOH as a low melting solid. It can be recovered using these procedures from asymmetric reductions with LAH, and re-used. [Pohland & Sullivan J Am Chem Soc 77 3400 1955, Sullivan et al. J Org Chem 28 2483 1963, Beilstein 13 IV 2221.]
[S-(R*,S*)]-α-[2-(Dimethylamino)-1-methylethyl]-α-phenylphenethylalkohol Upstream-Materialien And Downstream Produkte
Upstream-Materialien
Downstream Produkte
[S-(R*,S*)]-α-[2-(Dimethylamino)-1-methylethyl]-α-phenylphenethylalkohol Anbieter Lieferant Produzent Hersteller Vertrieb H?ndler.
Global( 31)Lieferanten
38345-66-3([S-(R*,S*)]-α-[2-(Dimethylamino)-1-methylethyl]-α-phenylphenethylalkohol)Verwandte Suche:
- 2-S-3-R-plus-4-dimethylamino-1-2-*diphenyl-3-meth
- chirald
- [S-(R*,S*)]-alpha-[2-(dimethylamino)-1-methylethyl]-alpha-phenylphenethyl alcohol
- DEXTROOXYPHENE
- chirald tm
- D-OXYPHENE
- (2S,3R)-4-(DIMETHYLAMINO)-3-METHYL-1,2-DIPHENYLBUTAN-2-OL, TOLUENE SOLUTION
- Dextrocarbinol base, (2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol, (2S,3R)-(+)-4-Dimethylamino-3-methyl-1,2-diphenyl-2-butanol
- Dextrocarbinol base, (2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol
- (2S,3R)-1,2-Diphenyl-3-methyl-4-(dimethylamino)-2-butanol
- (αS)-α-[(1R)-2-(Dimethylamino)-1-methylethyl]-α-phenylbenzeneethanol
- (αS)-α-Phenyl-α-[(R)-1-(dimethylaminomethyl)ethyl]benzeneethanol
- α-(+)-Oxyphene
- Darvon alcohol
- Einecs 253-893-6
- Mosher'S reagent
- Oxiphene
- (2S,3R)-(+)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
- (2S,3R)-4-DIMETHYLAMINO-1,2-DIPHENYL-3-METHYL-2-BUTANOL
- (+)-(2S,3R)-4-DIMETHYLAMINO-3-METHYL-1,2-DIPHENYL-2-BUTANOL
- DEXTROCARBINOL BASE
- CHIRALD(R)
- (2S,3R)-4-(dimethylamino)-3-methyl-1,2-diphenylbutan-2-ol
- (2S,3R)-(+)-4-Dimethylamino-1,2-diphenyl-3-methyl-2-butanol, (2S,3R)-(+)-4-Dimethylamino-3-methyl-1,2-diphenyl-2-butanol, Dextrocarbinol base
- (2S,3R)-4-(Dimethylamino)-1,2-diphe
- Benzeneethanol, α-[(1R)-2-(dimethylamino)-1-methylethyl]-α-phenyl-, (αS)-
- Dextropropoxyphene EP Impurity A
- Propoxyphene USP Related Compound A
- (2S,3R)-4-(dimethylamino)-1,2-diphenyl-3-methyl-butan-2-ol (oxyphene),
- Dextropropoxyphene Hydrochloride EP Impurity A
- Codeine Phosphate Impurity 14
- 38345-66-3
- Organic Building Blocks
- Chiral Building Blocks
- Asymmetric Synthesis
- Amino Alcohols