Identification | Back Directory | [Name]
TRIBUTYL(1-ETHOXYVINYL)TIN | [CAS]
97674-02-7 | [Synonyms]
TRIBUTYL(1-ETHOXYVINYL)TIN (1-ethoxyvinyl)tributyltin 1-ETHOXYVINYL-TRI-N-BUTYLTIN Tri-n-butyl(1-ethoxyvinyl)tin Tributyl(1-ethoxyvinyl)tin(IV) Tributyl(1-ethoxyvinyl)tin,95% (1-Ethoxyvinyl)tributyltin(IV) Tributyl(1-ethoxyvinyl)tin 97% 1-Ethoxyethenyltributylstannane Tributyl(1-ethoxyvinyl)stannane (1-ETHOXYVINYL)TRIBUTYLSTANNANE Tributyl(1-ethoxyvinyl)tin ,97% 1-Ethoxy-1-(tributylstannyl)ethene (1-Ethoxyvinyl)tributylstannane 95% Stannane,tributyl(1-ethoxyethenyl)- (1-ETHOXYVINYL)-TRIBUTYLSTANNAN 97% [1-(Tributylstannyl)vinyl]ethyl ether 1-Ethoxy-1-(tributylstannyl)ethylene 95% Tributyl(1-ethoxyvinyl)tin1-Ethoxyvinyl-tri-n-butyltin (1-Ethoxyethenyl)tributylstannane, (1-Ethoxyvinyl)tributylstannane Tributyl(1-ethoxyvinyl)tin, (1-Ethoxyethenyl)tributylstannane, (1-Ethoxyvinyl)tributylstannane | [Molecular Formula]
C16H34OSn | [MDL Number]
MFCD00010240 | [MOL File]
97674-02-7.mol | [Molecular Weight]
361.15 |
Chemical Properties | Back Directory | [Appearance]
Clear colorless liquid | [Melting point ]
<0°C | [Boiling point ]
85-86 °C0.1 mm Hg(lit.)
| [density ]
1.069 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.476(lit.)
| [Fp ]
>230 °F
| [storage temp. ]
Sealed in dry,2-8°C | [form ]
liquid | [color ]
colorless | [Specific Gravity]
1.069 | [Sensitive ]
Moisture Sensitive | [InChIKey]
HGXJOXHYPGNVNK-UHFFFAOYSA-N |
Hazard Information | Back Directory | [Chemical Properties]
Clear colorless liquid | [Uses]
Electrophilic methyl ketone equivalent used in a recent synthesis of a 13-oxophorbine (chlorophyll) from the corresponding 13-bromochlorin. | [General Description]
This vinylstannane undergoes Stille coupling with a vinyl triflate, giving, after hydrolysis, an α,β?unsaturated ketone, thus acting as an acetyl anion equivalent. |
Questions And Answer | Back Directory | [Reaction]
Versatile tin reagent used for the introduction of a 1-ethoxyvinyl group via a Stille cross-coupling reaction, (palladium-catalyzed coupling of an organohalide (or pseudohalide) with an organotin compound).
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