| Identification | Back Directory | [Name]
Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3] | [CAS]
944451-14-3 | [Synonyms]
(S)-[(RuCl(DM-SEGPHOS))2(μ-Cl)3][NH2Me2]
[NH2Me2][(RuCl((S)-dm-segphos[R]))2(μ-Cl)3]
[NH2Me2][(RuCl((S)-dm-segphos(regR)))2(mu-Cl)3]
Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II)[NH2Me2][{RuCl((S)-dm-segphos)}2(μ-Cl)3]
DiMethylaMMoniuM dichlorotri(Mu-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((S)-dM-segphos)}2(μ-Cl)3]
Dimethylammonium dichlorotri(μ-chloro)bis{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((S)-dm-segphos(R))}2(μ-Cl)3] | [Molecular Formula]
C94H95Cl5NO8P4Ru2 | [MDL Number]
MFCD09753038 | [MOL File]
944451-14-3.mol | [Molecular Weight]
1875.12 |
| Chemical Properties | Back Directory | [Melting point ]
>100°C | [storage temp. ]
2-8°C | [Water Solubility ]
Insoluble in water | [form ]
Powder | [color ]
light brown | [Sensitive ]
air sensitive |
| Safety Data | Back Directory | [Hazard Codes ]
F | [Risk Statements ]
11 | [RIDADR ]
UN1325 class 4.1 PG 3 Flammable solids, organic, n.o.s., HI: all | [WGK Germany ]
3 | [HS Code ]
2843.90.0000 |
| Questions And Answer | Back Directory | [Reaction]
- Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
- Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
- Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone.
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Energy Chemical
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021-021-58432009 400-005-6266 |
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http://www.energy-chemical.com |
| Company Name: |
TCI Europe
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320-37350700 |
| Website: |
https://www.tcichemicals.com/de/de/index.html |
| Company Name: |
TCI AMERICA
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800-4238616 |
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https://www.tcichemicals.com/en/us/index.html |
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