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ChemicalBook--->CAS DataBase List--->935449-46-0

935449-46-0

935449-46-0 Structure

935449-46-0 Structure
IdentificationBack Directory
[Name]

Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3]
[CAS]

935449-46-0
[Synonyms]

(R)[(RuCl(DMSEGPHOS)2(μCl)3][NH2Me2]
[NH2Me2][(RuCl((R)-dm-segphos[R]))2(μ-Cl)3]
[NH2Me2][(RuCl((R)-dm-segphos(regR)))2(mu-Cl)3]
Dimethylammonium dichlorotri(chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos)}2(Cl)3]
DiMethylaMMoniuM dichlorotri(Mu-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dM-segphos)}2(μ-Cl)3]
Dimethylammonium dichlorotri(μ-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos(R))}2(μ-Cl)3]
[Molecular Formula]

C94H95Cl5NO8P4Ru2
[MDL Number]

MFCD09753038
[MOL File]

935449-46-0.mol
[Molecular Weight]

1875.12
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

2-8°C
[Water Solubility ]

Insoluble in water
[form ]

Powder
[color ]

light brown
[Sensitive ]

air sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H335-H319
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
[WGK Germany ]

3
[HS Code ]

2843.90.0000
Questions And AnswerBack Directory
[Reaction]

  1. Biaryl bisphosphine ligand with narrow dihedral angle. The DM-SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity in the asymmetric hydrogenation of α-substituted-β-ketoesters.
  2. Ruthenium catalyzed enantioselective synthesis of β amino acids by hydrogenation.
  3. Ruthenium catalyzed asymmetric hydrogenation of 3-quinuclidinone.
Reactions of 935449-46-0
Hazard InformationBack Directory
[Uses]

(R)-[(RuCl(DM-SEGPHOS?)2(μ-Cl)3][NH2Me2] can be used as a catalyst for the asymmetric hydrogenation of ketones to chiral alcohols. It can also be utilized to prepare (R)-methyl-3-hydroxybutanoate from methyl acetoacetate via stereoselective hydrogenation reaction.
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