| Identification | More | [Name]
2-Allylcyclohexanone | [CAS]
94-66-6 | [Synonyms]
2-(2-PROPENYL)CYCLOHEXANONE
2-ALLYLCYCLOHEXANONE
O-ALLYLCYCLOHEXANONE
TIMTEC-BB SBB006544
2-(2-propenyl)-cyclohexanon
Cyclohexanone, 2-allyl-
2-allylcyclohexan-1-one
2-Allylcyclohexanone, 97 % | [EINECS(EC#)]
202-352-2 | [Molecular Formula]
C9H14O | [MDL Number]
MFCD00043548 | [Molecular Weight]
138.21 | [MOL File]
94-66-6.mol |
| Safety Data | Back Directory | [Hazard Codes ]
Xn,Xi | [Risk Statements ]
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed .
R36/37/38:Irritating to eyes, respiratory system and skin . | [Safety Statements ]
S22:Do not breathe dust .
S26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice .
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection .
S45:In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) .
S37/39:Wear suitable gloves and eye/face protection . | [RIDADR ]
UN 3077 | [WGK Germany ]
3
| [HS Code ]
29142990 |
| Hazard Information | Back Directory | [Chemical Properties]
clear light yellow liquid | [Uses]
2-Allylcyclohexanone may be used in the synthesis of the following:
- bicyclo[3.3.1]non-2-en-9-one
- R-(-)-epilachnene, an antipode of the defensive droplets from the Mexican bean beetle, Epilachna varivestis
| [Synthesis Reference(s)]
Chemistry Letters, 13, p. 1721, 1984
Journal of the American Chemical Society, 85, p. 207, 1963 DOI: 10.1021/ja00885a021
The Journal of Organic Chemistry, 51, p. 421, 1986 DOI: 10.1021/jo00354a001 | [General Description]
2-Allylcyclohexanone is a β,γ-unsaturated ketone. Selective oxidation of 2-allylcyclohexanone by benzonitrile-hydrogen peroxide has been reported. Asymmetric synthesis of 2-alkylcyclohexanones by alkylation of cyclohexanone enamines (III) of L-proline ester derivatives has been described. Oxidation of 2-allylcyclohexanone by 90% hydrogen peroxide catalyzed by arsonated polystyrene has been studied. |
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| Company Name: |
Energy Chemical
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021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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