| Identification | More | [Name]
EUGENOL ACETATE | [CAS]
93-28-7 | [Synonyms]
1,3,4-EUGENOL ACETATE
1-ACETOXY-2-METHOXY-4-ALLYLBENZENE
4-ALLYL-2-METHOXYPHENOL ACETATE
4-ALLYL-2-METHOXYPHENYL ACETATE
ACETOEUGENOL
ACETYL EUGENOL
EUGENOL ACETATE
EUGENYL ACETATE
FEMA 2469
PHENOL, 4-ALLYL-2-METHOXY:ACETATE
1-acetoxy-4-allyl-2-methoxy-benzene
2-methoxy-4-(2-propenyl)-phenoacetate
2-methoxy-4-(2-propenyl)-phenol,acetate
4-allyl-2-methoxy-phenoacetate
Aceteugenol
aceticacid4-allyl-2-methoxy-phenylester
eugenyl
Phenol,2-methoxy-4-(2-propenyl)-,acetate
EUGENYL ACETATE 98+% FCC
EUGENOL ACETATE 98+% | [EINECS(EC#)]
202-235-6 | [Molecular Formula]
C12H14O3 | [MDL Number]
MFCD00026191 | [Molecular Weight]
206.24 | [MOL File]
93-28-7.mol |
| Chemical Properties | Back Directory | [Appearance]
liquid | [Melting point ]
26°C | [Boiling point ]
281-286 °C(lit.) | [density ]
1.079 g/mL at 25 °C(lit.)
| [vapor pressure ]
0.041Pa at 20℃ | [FEMA ]
2469 | [refractive index ]
n20/D 1.518(lit.)
| [Fp ]
230 °F
| [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [solubility ]
Chloroform (Sparingly), Ethyl Acetate (Slightly), Methanol (Slightly) | [form ]
Colourless to Light Yellow Oil to Semi-Solid | [color ]
White or Colorless to Light yellow | [Odor]
at 100.00 %. fresh sweet woody clove floral carnation malt spice | [Stability:]
Stable. Combustible. Incompatible with strong oxidizing agents. | [Odor Type]
spicy | [Water Solubility ]
407mg/L at 20℃ | [JECFA Number]
1531 | [LogP]
2.8 at 25℃ | [CAS DataBase Reference]
93-28-7(CAS DataBase Reference) | [NIST Chemistry Reference]
Phenol, 2-methoxy-4-(2-propenyl)-, acetate(93-28-7) | [EPA Substance Registry System]
Phenol, 2-methoxy-4-(2-propenyl)-, acetate (93-28-7) |
| Safety Data | Back Directory | [Hazard Codes ]
Xn | [Risk Statements ]
R22:Harmful if swallowed.
R38:Irritating to the skin. | [Safety Statements ]
S36:Wear suitable protective clothing . | [WGK Germany ]
2
| [RTECS ]
SJ4550000
| [HS Code ]
29147000 | [Safety Profile]
Moderately toxic by
ingestion. A skin irritant. Combustible
liquid. When heated to decomposition it
emits acrid smoke and irritating fumes. See
also EUGENOL, ALLYL COMPOUNDS,
and ESTERS. | [Toxicity]
The acute oral LD50 value in rats was reported as 1.67 g/kg (Jenner, Hagan, Taylor, Cook & Fitzhugh, 1964) and as 2.6 g/kg (2.3-2.9 g/kg) (Moreno, 1972b). The acute dermal LD50 value in rabbits exceeded 5 g/kg (Moreno, 1972a). |
| Hazard Information | Back Directory | [Chemical Properties]
Eugenol Acetate occurs in clove
oil, together with eugenol. It is a crystalline solid (mp 29°C) or yellowish liquid
with a slightly fruity, clove odor. Eugenol acetate is prepared by acetylation of
eugenol with acetic anhydride and is used in floral compositions to accentuate
floral, spicy characters. | [Chemical Properties]
Eugenyl acetate has a characteristic odor reminiscent of clove oil, with a burning, aromatic favor. | [Chemical Properties]
liquid | [Occurrence]
Reported found in the essential oils of Laurus nobilis, clove buds and leaves, cassia leaf and cinnamon leaf, root and bark | [Uses]
Eugenol Acetate is a constituent of Clove oil, an essential oil from the clove plant, Syzygium aromaticum. Clove oil is a natural analgaesic and antiseptic used primarily in dentistry for its main ingredient Eugenol. Clove oil can also be purchased in pharmacies over the counter, as a home remedy for dental pain relief, mainly toothache; it is also often found in the aromatherapy section of health food stores. | [Application]
Mild and sweet-spicy, balsamic-fruity odour, reminiscent of carnation. Earthy-fresh notes or leafy-floral notes are not uncommon. Used in perfumes to emphasize floralness in carnation, along with iso-eugenol, Amyl oxy-iso-eugenol, etc. Fresher than these, but also milder. Not stable in white soap or alkali. It is in flavors for berry, fruit, mint, spice, and vanilla types.
| [Definition]
ChEBI: Acetyleugenol is a member of phenols and a benzoate ester. | [Preparation]
By direct acetylation of eugenol using acetic anhydride. | [Flammability and Explosibility]
Notclassified |
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